-
1
-
-
25144457531
-
-
(a) Gillmore, J. G.; Neiser, J. D.; McManus, K. A.; Roh, Y.; Dombrowski, G. W.; Brown, T. G.; Dinnocenzo, J. P.; Fand, S.; Robello, D. R. Macromolecules 2005, 38, 7684.
-
(2005)
Macromolecules
, vol.38
, pp. 7684
-
-
Gillmore, J.G.1
Neiser, J.D.2
McManus, K.A.3
Roh, Y.4
Dombrowski, G.W.5
Brown, T.G.6
Dinnocenzo, J.P.7
Fand, S.8
Robello, D.R.9
-
2
-
-
33847718541
-
-
U.S. Patent 6,569,600
-
(b) Dinnocenzo, J. P.; Fand, S. Y.; Robello, D. R.; Erdogan, T. U.S. Patent 6,569,600, 2003.
-
(2003)
-
-
Dinnocenzo, J.P.1
Fand, S.Y.2
Robello, D.R.3
Erdogan, T.4
-
3
-
-
0001346222
-
-
Renner, C. A.; Katz, T. J.; Pouliquen, J.; Turro, N. J.; Waddell, W. H. J. Am. Chem. Soc. 1975, 97, 2568.
-
(1975)
J. Am. Chem. Soc
, vol.97
, pp. 2568
-
-
Renner, C.A.1
Katz, T.J.2
Pouliquen, J.3
Turro, N.J.4
Waddell, W.H.5
-
4
-
-
0006989344
-
-
Turro, N. J.; Ramamurthy, V.; Katz, T. J. Nouv. J. Chem. 1977, 1, 363.
-
(1977)
Nouv. J. Chem
, vol.1
, pp. 363
-
-
Turro, N.J.1
Ramamurthy, V.2
Katz, T.J.3
-
7
-
-
0000133040
-
-
Okamoto, H.; Arai, T.; Sakuragi, H.; Tokumaru, K. Bull. Chem. Soc. Jpn. 1990, 63, 2881.
-
(1990)
Bull. Chem. Soc. Jpn
, vol.63
, pp. 2881
-
-
Okamoto, H.1
Arai, T.2
Sakuragi, H.3
Tokumaru, K.4
-
8
-
-
0000508577
-
-
Karatsu, T.; Tsuchiya, M.; Arai, T.; Sakuragi, H.; Tokumaru, K. Bull. Chem. Soc. Jpn. 1994, 67, 3030.
-
(1994)
Bull. Chem. Soc. Jpn
, vol.67
, pp. 3030
-
-
Karatsu, T.1
Tsuchiya, M.2
Arai, T.3
Sakuragi, H.4
Tokumaru, K.5
-
9
-
-
0042870273
-
-
Möllerstedt, H.; Wennerström, O. J. Photochem. Photobiol., A 2001, 139, 37.
-
(2001)
J. Photochem. Photobiol., A
, vol.139
, pp. 37
-
-
Möllerstedt, H.1
Wennerström, O.2
-
10
-
-
0015432730
-
-
Whitten, D. G.; Wildes, P. D.; DeRosier, C. A. J. Am. Chem. Soc. 1972, 94, 7811.
-
(1972)
J. Am. Chem. Soc
, vol.94
, pp. 7811
-
-
Whitten, D.G.1
Wildes, P.D.2
DeRosier, C.A.3
-
11
-
-
33845280360
-
-
Yee, W. A.; Hug, S. J.; Kliger, D. S. J. Am. Chem. Soc. 1988, 110, 2164.
-
(1988)
J. Am. Chem. Soc
, vol.110
, pp. 2164
-
-
Yee, W.A.1
Hug, S.J.2
Kliger, D.S.3
-
12
-
-
0001278014
-
-
Saltiel, J.; Wang, S.; Ko, D.-H.; Gormin, D. A. J. Phys. Chem. A 1998, 102, 5383.
-
(1998)
J. Phys. Chem. A
, vol.102
, pp. 5383
-
-
Saltiel, J.1
Wang, S.2
Ko, D.-H.3
Gormin, D.A.4
-
13
-
-
0000806251
-
-
11b,c to the effect of a photoactive impurity. (a) Hyndman, H. L.; Monroe, B. M.; Hammond, G. S. J. Am. Chem. Soc. 1969, 91, 2852.
-
11b,c to the effect of a photoactive impurity. (a) Hyndman, H. L.; Monroe, B. M.; Hammond, G. S. J. Am. Chem. Soc. 1969, 91, 2852.
-
-
-
-
14
-
-
0000457042
-
-
(b) Saltiel, J.; Townsend, D. E.; Sykes, A. J. Am. Chem. Soc. 1973, 95, 5968.
-
(1973)
J. Am. Chem. Soc
, vol.95
, pp. 5968
-
-
Saltiel, J.1
Townsend, D.E.2
Sykes, A.3
-
15
-
-
0005289438
-
-
(c) Saltiel, J.; Metts, L.; Wrighton, M. J. Am. Chem. Soc. 1969, 91, 5684.
-
(1969)
J. Am. Chem. Soc
, vol.91
, pp. 5684
-
-
Saltiel, J.1
Metts, L.2
Wrighton, M.3
-
16
-
-
33847732090
-
-
U.S. Patent Application 2005136357 A1, June 23, 2005
-
Farid, S. Y.; Robello, D. R.; Dinnocenzo, J. P.; Merkel, P. B.; Ferrar, L. S.; Roh, Y.; Mis, M. U.S. Patent Application 2005136357 A1, June 23, 2005.
-
-
-
Farid, S.Y.1
Robello, D.R.2
Dinnocenzo, J.P.3
Merkel, P.B.4
Ferrar, L.S.5
Roh, Y.6
Mis, M.7
-
17
-
-
0011422966
-
-
Turro, N. J.; McVey, J.; Ramamurthy, V.; Lechtken, P. Angew. Chem., Int. Ed. Engl. 1979, 18, 572.
-
(1979)
Angew. Chem., Int. Ed. Engl
, vol.18
, pp. 572
-
-
Turro, N.J.1
McVey, J.2
Ramamurthy, V.3
Lechtken, P.4
-
18
-
-
33847755353
-
-
As discussed in ref 4, more complex schemes may apply for cis/trans isomerizations
-
As discussed in ref 4, more complex schemes may apply for cis/trans isomerizations.
-
-
-
-
19
-
-
0000910861
-
-
See, for example: a, Padwa, A, Ed, Marcel Dekker: New York
-
See, for example: (a) Mattes, S. L.; Farid, S. In Organic Photochemistry; Padwa, A., Ed.; Marcel Dekker: New York, 1983; Vol. 6, p 233.
-
(1983)
Organic Photochemistry
, vol.6
, pp. 233
-
-
Mattes, S.L.1
Farid, S.2
-
20
-
-
0008536559
-
-
Fox, M. A, Chanon, M, Eds, Elsevier: Amsterdam
-
(b) Lewis, F. D. In Photoinduced Electron Transfer, Fox, M. A., Chanon, M., Eds.; Elsevier: Amsterdam, 1988; Vol. C, p 1.
-
(1988)
Photoinduced Electron Transfer
, vol.100
, pp. 1
-
-
Lewis, F.D.1
-
23
-
-
0031573815
-
-
(e) Schmittel, M.; Burghart, A. Angew. Chem., Int. Ed. Engl. 1997, 36, 2550.
-
(1997)
Angew. Chem., Int. Ed. Engl
, vol.36
, pp. 2550
-
-
Schmittel, M.1
Burghart, A.2
-
25
-
-
0038348698
-
-
(b) Kiau, S; Liu, G.; Shukla, D.; Dinnocenzo, J. P.; Young, R. H.; Farid, S. J. Phys. Chem. A 2003, 107, 3625.
-
(2003)
J. Phys. Chem. A
, vol.107
, pp. 3625
-
-
Kiau, S.1
Liu, G.2
Shukla, D.3
Dinnocenzo, J.P.4
Young, R.H.5
Farid, S.6
-
26
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33847758122
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-
Measured vs SCE in methylene chloride by Dr. M. Madaras of Eastman Kodak Co
-
Measured vs SCE in methylene chloride by Dr. M. Madaras of Eastman Kodak Co.
-
-
-
-
28
-
-
0001106707
-
-
Balzani, V.; Bolletta, F.; Scandola, F. J. Am. Chem. Soc. 1980, 102, 2152.
-
(1980)
J. Am. Chem. Soc
, vol.102
, pp. 2152
-
-
Balzani, V.1
Bolletta, F.2
Scandola, F.3
-
30
-
-
33847698823
-
-
S notation here for brevity.
-
S notation here for brevity.
-
-
-
-
32
-
-
0000181757
-
-
While differences in entropy between the triplet and ground states (AS) are expected to be small for the relatively rigid sensitizers used in our experiments, they may not be negligible. For example, ΔS values of approximately -0.6 to -1.2, 0.2, 1.8, and -0.8 kcal/mol may be estimated at room temperature for excitation of benzophenone,23a,b 4-methylbenzophenone,23c biphenyl,23a and 4-methylbiphenyl,23c respectively, on the basis of the effect of temperature on triplet-energy-transfer equilibria, a) Gessner, F, Scaiano, J. C. J. Am. Chem. Soc. 1985, 107, 7206
-
23c respectively, on the basis of the effect of temperature on triplet-energy-transfer equilibria. (a) Gessner, F.; Scaiano, J. C. J. Am. Chem. Soc. 1985, 107, 7206.
-
-
-
-
33
-
-
0031563678
-
-
(b) Yamaji, M.; Okada, K.; Marciniak, B.; Shizuka, H. Chem. Phys. Lett. 1977, 277, 375.
-
(1977)
Chem. Phys. Lett
, vol.277
, pp. 375
-
-
Yamaji, M.1
Okada, K.2
Marciniak, B.3
Shizuka, H.4
-
34
-
-
0037632234
-
-
(c) Zhang, D.; Closs, G. L.; Chung, D. D.; Norris, J. R. J. Am. Chem. Soc. 1993, 115, 3670.
-
(1993)
J. Am. Chem. Soc
, vol.115
, pp. 3670
-
-
Zhang, D.1
Closs, G.L.2
Chung, D.D.3
Norris, J.R.4
-
35
-
-
0034685437
-
-
24a (a) Coenjarts, C.; Scaiano, J. C. J. Am. Chem. Soc. 2000, 122, 3635.
-
24a (a) Coenjarts, C.; Scaiano, J. C. J. Am. Chem. Soc. 2000, 122, 3635.
-
-
-
-
36
-
-
33847708573
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This is the value of kd calculated from the Smoluchowski equation (kd, 4πNrs+RDS+R/1000) with r s+R, 5.5 Å and DS+R, 2.9 × 10-5 cm2 s-1, where the diffusion coefficient DS+R is calculated from the Stokes-Einstein equation (DS+R, DS, DR, RT/6πηrSN, RT/6πηrRN) with η, 0.5 cP and rS, rR, 2.75 Å
-
R = 2.75 Å.
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-
-
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37
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0003924674
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For example, the triplet energy of 2-butene is ∼10 kcal/mol higher than that of dimethyl fumarate, and the triplet energy of β-methylstyrene is ∼5 kcal/mol higher than that of methyl cinnamate.26a a, 2nd ed, Marcel Dekker: New York
-
26a (a) Murov, S. L; Camichael, I.; Hug, G. L. Handbook of Photochemistry, 2nd ed.; Marcel Dekker: New York, 1993.
-
(1993)
Handbook of Photochemistry
-
-
Murov, S.L.1
Camichael, I.2
Hug, G.L.3
-
38
-
-
0037970472
-
-
† is nonzero is arguable. See, for example: Saltiel, J.; Marchand, G. R.; Kirkor-Kaminska, E.; Smothers, W. K.; Mueller, W. B.; Charlton, J. L. J. Am. Chem. Soc. 1984, 106, 3144.
-
† is nonzero is arguable. See, for example: Saltiel, J.; Marchand, G. R.; Kirkor-Kaminska, E.; Smothers, W. K.; Mueller, W. B.; Charlton, J. L. J. Am. Chem. Soc. 1984, 106, 3144.
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-
-
-
39
-
-
0037173856
-
-
(a) Lalevée, J.; Allonas, X.; Louërai, F.; Fouassier, J. P. J. Phys. Chem. A 2002, 106, 6702.
-
(2002)
J. Phys. Chem. A
, vol.106
, pp. 6702
-
-
Lalevée, J.1
Allonas, X.2
Louërai, F.3
Fouassier, J.P.4
-
40
-
-
0038666545
-
-
(b) Allonas, X.; Lalevee, J.; Fouassier, J. P. Chem. Phys. 2003, 290, 257.
-
(2003)
Chem. Phys
, vol.290
, pp. 257
-
-
Allonas, X.1
Lalevee, J.2
Fouassier, J.P.3
-
41
-
-
11144307431
-
-
(c) Lalevee, J.; Allonas, X.; Fouassier, J. P. Chem. Phys. Lett. 2005, 401, 483.
-
(2005)
Chem. Phys. Lett
, vol.401
, pp. 483
-
-
Lalevee, J.1
Allonas, X.2
Fouassier, J.P.3
-
42
-
-
33847752103
-
-
The thermodynamic triplet energy for B2 is less accurately determined due to a small amount of absorption by photoproduct(s) in the region of the sensitizer triplet transient absorption.
-
The thermodynamic triplet energy for B2 is less accurately determined due to a small amount of absorption by photoproduct(s) in the region of the sensitizer triplet transient absorption.
-
-
-
-
43
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-
33645700844
-
-
Quantum mechanical computations of triplet energies of benzene derivatives with bulky substituents are sparse. However, calculations on p-xylene suggest a quinoidal triplet conformation about 4.6 kcal/mol lower in energy than the vertical hexagonal form as well as an antiquinoidal conformation that is about 0.6 kcal/mol more stable than the hexagonal form. Buma, W. J, van der Waals, J. H, van Hemert, M. C. J. Chem. Phys. 1990, 93, 3746
-
Quantum mechanical computations of triplet energies of benzene derivatives with bulky substituents are sparse. However, calculations on p-xylene suggest a quinoidal triplet conformation about 4.6 kcal/mol lower in energy than the vertical hexagonal form as well as an antiquinoidal conformation that is about 0.6 kcal/mol more stable than the hexagonal form. Buma, W. J.; van der Waals, J. H.; van Hemert, M. C. J. Chem. Phys. 1990, 93, 3746.
-
-
-
-
44
-
-
0039237514
-
-
Frank, I.; Grimme, S.; Peyerimhoff, S. D. J. Am. Chem. Soc. 1994, 116, 5949.
-
(1994)
J. Am. Chem. Soc
, vol.116
, pp. 5949
-
-
Frank, I.1
Grimme, S.2
Peyerimhoff, S.D.3
-
47
-
-
84915479136
-
-
S+R = 5.5Å: Eigen, M. Z. Phys. Chem. 1954, 1, 176.
-
S+R = 5.5Å: Eigen, M. Z. Phys. Chem. 1954, 1, 176.
-
-
-
-
48
-
-
33847716155
-
-
Although both kd and k-d decrease with increasing solvent viscosity, it is generally accepted that their ratio, k -d/kd, remains constant. See ref 34 and Pilling, M. J, Seakins, P. W. Reaction Kinetics; Oxford University Press: Oxford, 1995; pp 146-156
-
d, remains constant. See ref 34 and Pilling, M. J.; Seakins, P. W. Reaction Kinetics; Oxford University Press: Oxford, 1995; pp 146-156.
-
-
-
-
49
-
-
33847743290
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The 0-0 phosphorescence band at 77 K for DETX* occurs at about 62 kcal/mol in ethyl acetate and at about 60 kcal/mol in more polarizable chloroform.
-
The 0-0 phosphorescence band at 77 K for DETX* occurs at about 62 kcal/mol in ethyl acetate and at about 60 kcal/mol in more polarizable chloroform.
-
-
-
-
50
-
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33847696410
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-
TCE was chosen as an analogue of DB2 without the complications of chain isomerization. The short lifetime of triplet TCE eliminates reverse energy transfer as is the case for R, and the rate constants for quenching of triplet IMP are similar for TCE and DB2.
-
TCE was chosen as an analogue of DB2 without the complications of chain isomerization. The short lifetime of triplet TCE eliminates reverse energy transfer as is the case for R, and the rate constants for quenching of triplet IMP are similar for TCE and DB2.
-
-
-
-
51
-
-
0000993108
-
-
Scaiano, J. C.; Leigh, W. J.; Meador, M. A.; Wagner, P. J. J. Am. Chem. Soc. 1985, 107, 5086.
-
(1985)
J. Am. Chem. Soc
, vol.107
, pp. 5086
-
-
Scaiano, J.C.1
Leigh, W.J.2
Meador, M.A.3
Wagner, P.J.4
-
52
-
-
25144468217
-
-
Dopper, J. H.; Greijdanus, B.; Oudman, D.; Wynberg, H. Tetrahedron Lett. 1975, 4297.
-
(1975)
Tetrahedron Lett
, pp. 4297
-
-
Dopper, J.H.1
Greijdanus, B.2
Oudman, D.3
Wynberg, H.4
-
54
-
-
0000080876
-
-
Specht, D. P.; Martic, P. A.; Fand, S. Tetrahedron 1982, 38, 1203.
-
(1982)
Tetrahedron
, vol.38
, pp. 1203
-
-
Specht, D.P.1
Martic, P.A.2
Fand, S.3
-
55
-
-
0001416784
-
-
Brown-Wensley, K. A.; Mattes, S. L.; Fand, S. J. Am. Chem. Soc. 1978, 100, 4162.
-
(1978)
J. Am. Chem. Soc
, vol.100
, pp. 4162
-
-
Brown-Wensley, K.A.1
Mattes, S.L.2
Fand, S.3
-
60
-
-
0001761970
-
-
(a) Richards, J. T.; West, G.; Thomas, J. K. J. Phys. Chem. 1970, 74, 4137.
-
(1970)
J. Phys. Chem
, vol.74
, pp. 4137
-
-
Richards, J.T.1
West, G.2
Thomas, J.K.3
-
61
-
-
0039772275
-
-
(b) Scaiano, J. C.; Weldon, D.; Pliva, C. N.; Martinez, L. J. J. Phys. Chem. A 1998, 102, 6898.
-
(1998)
J. Phys. Chem. A
, vol.102
, pp. 6898
-
-
Scaiano, J.C.1
Weldon, D.2
Pliva, C.N.3
Martinez, L.J.4
-
62
-
-
0041732418
-
-
Shukla, D.; Liu, G.; Dinnocenzo, J. P.; Farid, S. Can. J. Chem. 2003, 81, 744.
-
(2003)
Can. J. Chem
, vol.81
, pp. 744
-
-
Shukla, D.1
Liu, G.2
Dinnocenzo, J.P.3
Farid, S.4
-
63
-
-
0030928520
-
-
Dockery, K. P.; Dinnocenzo, J. P.; Farid, S.; Goodman, J. L.; Gould, I. R.; Todd, W. P. J. Am. Chem. Soc. 1997, 119, 1876.
-
(1997)
J. Am. Chem. Soc
, vol.119
, pp. 1876
-
-
Dockery, K.P.1
Dinnocenzo, J.P.2
Farid, S.3
Goodman, J.L.4
Gould, I.R.5
Todd, W.P.6
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