Palladium β-diketonate complex catalyzed synthesis of monosubstituted arylferrocenes

Tetrahedron Letters

Volumn 49, Issue 36, 2008, Pages 5252-5254

  Purecha, Vishal H ^a   Nandurkar, Nitin S ^a   Bhanage, Bhalchandra M ^a   Nagarkar, Jayashree M ^a  

^a UNIVERSITY OF MUMBAI   (India)

Author keywords

Aryl halide; Bis(ferrocenyl)mercury; Cross coupling; Ferrocene

Indexed keywords

2,2,6,6 TETRAMETHYL 3,5 HEPTANEDIONATE; FERROCENE DERIVATIVE; HEPTANE DERIVATIVE; KETONE DERIVATIVE; MERCURY; PALLADIUM BETA DIKETONATE;

ARTICLE; ARYLATION; CATALYSIS; CROSS COUPLING REACTION; SYNTHESIS;

EID: 47749119523     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2008.06.106     Document Type: Article

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34. 2: Palladium chloride (1.8 g, 10 mmol) and sodium chloride (0.59 g, 10 mmol) were dissolved in methanol (50 mL) and stirred at room temperature overnight. The solution was filtered into a 100 mL volumetric flask and diluted with methanol to give a 0.1 M palladium(II) concentration. A mixture of this solution (100 mL), 2,2,6,6-tetramethyl-3,5-heptanedione (4.6 g, 25 mmol) and sodium carbonate (1.06 g, 10 mmol) was stirred overnight. The resulting yellow precipitate(4.03 g, 85% yield) was filtered and dried. Mp 238-240 °C.
35. 1H NMR.