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Volumn , Issue 16, 2004, Pages 2514-2525

Heavier alkali metal complexes of 2-phenylamidopyridine: An X-ray crystallographic and theoretical study of a structurally diverse series of crown ether adducts

Author keywords

[No Author keywords available]

Indexed keywords

ALKALI METALS; CROWN ETHERS; DIMERS; MICROANALYSIS; NEGATIVE IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; X RAY CRYSTALLOGRAPHY;

EID: 4744355182     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b406741j     Document Type: Article
Times cited : (16)

References (110)
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    • note
    • Crystals of 11 were triclinic, space group P̄1, a = 8.637(2) Å, b = 9.803(2) Å, c = 11.480(2) Å, α - 67.337(3)°, β = 89.975(3)°, γ = 73.630(3)°, Z= 1. They were thin needles giving marginal diffraction data (despite repeated recrystallisation and data collection), and the structure could not be satisfactorily refined to a stable convergence, giving a high R above 0.12, badly shaped displacement ellipsoids, and high residual electron density, indicating probable serious disorder problems that could not be resolved due to the poor quality of the data.
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    • note
    • Crystals of 12 were monoclinic, apparent space group I2/m, a = 8.176(4) Å, b = 16.881(8) Å, c = 13.367(7) Å, β = 105.265(7)°, Z= 2. Serious disorder of the amides (over four orientations each) was not resolvable, giving R = 0.078, and the unit cell and space group remain uncertain from the poor-quality data.
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    • University of Utrecht, The Netherlands
    • A. L. Spek, PLATON, University of Utrecht, The Netherlands, 2000.
    • (2000) PLATON
    • Spek, A.L.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.