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Angewandte Chemie - International Edition

Volumn 47, Issue 24, 2008, Pages 4584-4587

The homoleptic sandwich anion [Co(P2C2tBu 2)2]-: A versatile building block for phosphaorganometallic chemistry

(8) Wolf, Robert a Ehlers, Andreas W a Slootweg, J Chris a Lutz, Martin c Gudat, Dietrich b Hunger, Michael b Spek, Anthony L c Lammertsma, Koop a

a VU UNIVERSITY AMSTERDAM (Netherlands)

b UNIVERSITY OF STUTTGART (Germany)

c UTRECHT UNIVERSITY (Netherlands)

Author keywords

Cobalt; Density functional calculations; Hydrides; Phosphorus; Sandwich complexes

Indexed keywords

CHEMICAL REACTIONS;

COBALT; DENSITY FUNCTIONAL CALCULATIONS; HYDRIDES; PHOSPHORUS; SANDWICH COMPLEXES;

POLYCYCLIC AROMATIC HYDROCARBONS;

ANION; ANTHRACENE DERIVATIVE; COBALT; ORGANOMETALLIC COMPOUND; PHOSPHORUS;

ARTICLE; CHEMISTRY; DIMERIZATION; SYNTHESIS;

ANIONS; ANTHRACENES; COBALT; DIMERIZATION; ORGANOMETALLIC COMPOUNDS; PHOSPHORUS;

EID: 47149086804 PISSN: 14337851 EISSN: None Source Type: Journal
DOI: 10.1002/anie.200800813 Document Type: Article

Times cited : (47)

References (50)

1
- 0002591778
- G. Becker, G. Gresser, W. Uhl, Z. Naturforsch. B 1981, 36, 16;
- (1981) Z. Naturforsch. B , vol.36 , pp. 16
- Becker, G.¹ Gresser, G.² Uhl, W.³

2
- 0000531650
- b) M. Regitz, Chem. Rev. 1990, 90, 191;
- (1990) Chem. Rev , vol.90 , pp. 191
- Regitz, M.¹

3
- 0040546229
- c) A. C. Gaumont, J. Denis, Chem. Rev. 1994, 94, 1413;
- (1994) Chem. Rev , vol.94 , pp. 1413
- Gaumont, A.C.¹ Denis, J.²

4
- 0039056301
- d) J. F. Nixon, Coord. Chem. Rev. 1995, 145, 201;
- (1995) Coord. Chem. Rev , vol.145 , pp. 201
- Nixon, J.F.¹

5
- 0003963602
- Thieme, Stuttgart
- e) M. Regitz, O. J. Scherer, Multiple Bonds and Low Coordination Phosphorus Chemistry, Thieme, Stuttgart, 1990;
- (1990) Multiple Bonds and Low Coordination Phosphorus Chemistry
- Regitz, M.¹ Scherer, O.J.²

6
- 0003795078
- Wiley, Chichester
- f) K. B. Dillon, F. Mathey, J. F. Nixon, Phosphorus: The Carbon Copy, Wiley, Chichester, 1998;
- (1998) Phosphorus: The Carbon Copy
- Dillon, K.B.¹ Mathey, F.² Nixon, J.F.³

7
- 0141463985
- g) F. Mathey, Angew. Chem. 2003, 115, 1616;
- (2003) Angew. Chem , vol.115 , pp. 1616
- Mathey, F.¹

8
- 0037432895
- Angew. Chem. Int. Ed. 2003, 42, 1578.
- (2003) Angew. Chem. Int. Ed , vol.42 , pp. 1578

9
- 0034250675
- a) S. Saito, Y. Yamamoto, Chem. Rev. 2000, 100, 2901;
- (2000) Chem. Rev , vol.100 , pp. 2901
- Saito, S.¹ Yamamoto, Y.²

10
- 33745402207
- b) N. E. Schore, Chem. Rev. 1988, 88, 1081;
- (1988) Chem. Rev , vol.88 , pp. 1081
- Schore, N.E.¹

11
- 53649109873
- Transition Metal Alkyne Complexes: Transition Metal-Catalyzed Cyclotrimerization: D. B. Grotjahn in Comprehensive Organometallic Chemistry II, 12 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson, L. S. Hegedus), Pergamon, Oxford, 1995, pp. 741-770;
- c) "Transition Metal Alkyne Complexes: Transition Metal-Catalyzed Cyclotrimerization": D. B. Grotjahn in Comprehensive Organometallic Chemistry II, Vol. 12 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson, L. S. Hegedus), Pergamon, Oxford, 1995, pp. 741-770;

12
- 0000331770
- d) A. Efraty, Chem. Rev. 1977, 77, 691.
- (1977) Chem. Rev , vol.77 , pp. 691
- Efraty, A.¹

13
- 53649106724
- Selected examples: a C. Topf, T. Clark, F. W. Heinemann, M. Hennemann, S. Kummer, H. Pritzkow, U. Zenneck, Angew. Chem. 2002, 114, 4221;
- Selected examples: a) C. Topf, T. Clark, F. W. Heinemann, M. Hennemann, S. Kummer, H. Pritzkow, U. Zenneck, Angew. Chem. 2002, 114, 4221;

14
- 2242493583
- Angew. Chem. Int. Ed. 2002, 41, 4047;
- (2002) Angew. Chem. Int. Ed , vol.41 , pp. 4047

15
- 0037033449
- b) M. D. Francis, P. B. Hitchcock, Chem. Commun. 2002, 86;
- (2002) Chem. Commun , pp. 86
- Francis, M.D.¹ Hitchcock, P.B.²

16
- 45449100917
- c) M. Scheer, D. Himmel, B. P. Johnson, C. Kuntz, M. Schiffer, Angew. Chem. 2007, 119, 4045;
- (2007) Angew. Chem , vol.119 , pp. 4045
- Scheer, M.¹ Himmel, D.² Johnson, B.P.³ Kuntz, C.⁴ Schiffer, M.⁵

17
- 34250776602
- Angew. Chem. Int. Ed. 2007, 46, 3971.
- (2007) Angew. Chem. Int. Ed , vol.46 , pp. 3971

18
- 0001050008
- F. G. N. Cloke, P. B. Hitchcock, J. F. Nixon, D. M. Vickers, J. Organomet. Chem. 2001, 635, 212.
- (2001) J. Organomet. Chem , vol.635 , pp. 212
- Cloke, F.G.N.¹ Hitchcock, P.B.² Nixon, J.F.³ Vickers, D.M.⁴

19
- 0342778188
- a) F. G. N. Cloke, K. R. Flower, P. B. Hitchcock, J. F. Nixon, J. Chem. Soc. Chem. Commun. 1994, 489;
- (1994) J. Chem. Soc. Chem. Commun , pp. 489
- Cloke, F.G.N.¹ Flower, K.R.² Hitchcock, P.B.³ Nixon, J.F.⁴

20
- 0029784122
- b) P. L. Arnold, F. G. N. Cloke, P. B. Hitchcock, J. F. Nixon, J. Am. Chem. Soc. 1996, 118, 7630.
- (1996) J. Am. Chem. Soc , vol.118 , pp. 7630
- Arnold, P.L.¹ Cloke, F.G.N.² Hitchcock, P.B.³ Nixon, J.F.⁴

21
- 0001496166
- A. G. Avent, F. G. N. Cloke, K. R. Flower, P. B. Hitchcock, J. F. Nixon, D. M. Vickers, Angew. Chem. 1994, 106, 2406;
- (1994) Angew. Chem , vol.106 , pp. 2406
- Avent, A.G.¹ Cloke, F.G.N.² Flower, K.R.³ Hitchcock, P.B.⁴ Nixon, J.F.⁵ Vickers, D.M.⁶

22
- 33748248345
- Angew. Chem. Int. Ed. Engl. 1994, 33, 2330.
- (1994) Angew. Chem. Int. Ed. Engl , vol.33 , pp. 2330

23
- 33646457204
- J. E. Ellis, Inorg. Chem. 2006, 45, 3167.
- (2006) Inorg. Chem , vol.45 , pp. 3167
- Ellis, J.E.¹

24
- 0346882750
- W. W. Brennessel, V. G. Young, Jr., J. E. Ellis, Angew. Chem. 2002, 114, 1259;
- (2002) Angew. Chem , vol.114 , pp. 1259
- Brennessel, W.W.¹ Young Jr., V.G.² Ellis, J.E.³

25
- 0037006844
- Angew. Chem. Int. Ed. 2002, 41, 1211.
- (2002) Angew. Chem. Int. Ed , vol.41 , pp. 1211

26
- 53649097607
- X-ray data were collected on a Nonius Kappa CCD diffractometer with rotating anode (graphite monochromator, λ, 0.71073 Å) up to a resolution of (sin θ/λ)max, 0.65 Å-1 at a temperature of 150 K. The structures were solved by direct methods (SHELXS-97)[20] and refined with SHELXL-97[20] against F2 of all reflections. Non-hydrogen atoms were refined with anisotropic displacement parameters. Hydrogen atoms were introduced in calculated positions and refined with a riding model. Geometry calculations and checking for higher symmetry was performed with the PLATON program, 21] 1: [C20H40KO8](C 20H36CoP4, Mw, 906.92, red block, 0.48 x 0.30 x 0.21 mm3, monoclinic, P2 1/c (no. 14, a, 10.2813(9, b, 23.7637(2, c, 19.9146(9) Å, β
- 3. CCDC-676286 (1), -676287 (2), -676288 (3), and -676289 (4) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.

27
- 84985738583
- a) P. Binger, R. Milczarek, R. Mynott, C. Krüger, Y.-H. Tsay, E. Raabe, M. Regitz, Chem. Ber. 1988, 121, 637;
- (1988) Chem. Ber , vol.121 , pp. 637
- Binger, P.¹ Milczarek, R.² Mynott, R.³ Krüger, C.⁴ Tsay, Y.-H.⁵ Raabe, E.⁶ Regitz, M.⁷

28
- 0000844343
- b) P. Binger, R. Milczarek, R. Mynott, M. Regitz, W. Rosch, Angew. Chem. 1986, 98, 645;
- (1986) Angew. Chem , vol.98 , pp. 645
- Binger, P.¹ Milczarek, R.² Mynott, R.³ Regitz, M.⁴ Rosch, W.⁵

29
- 84985580916
- Angew. Chem. Int. Ed. Engl. 1986, 25, 644;
- (1986) Angew. Chem. Int. Ed. Engl , vol.25 , pp. 644

30
- 51149204965
- c) P. B. Hitchcock, M. J. Maah, J. F. Nixon, J. Chem. Soc. Chem. Commun. 1986, 737.
- (1986) J. Chem. Soc. Chem. Commun , pp. 737
- Hitchcock, P.B.¹ Maah, M.J.² Nixon, J.F.³

31
- 37049081280
- T. Wettling, G. Wolmershäuser, P. Binger, M. Regitz, J. Chem. Soc. Chem. Commun. 1990, 1541.
- (1990) J. Chem. Soc. Chem. Commun , pp. 1541
- Wettling, T.¹ Wolmershäuser, G.² Binger, P.³ Regitz, M.⁴

32
- 53649088035
- 2D](D- 2) was prepared for comparison and found to display spectroscopic properties identical to those of H-2; see the Supporting Information for details.
- 2D](D- 2) was prepared for comparison and found to display spectroscopic properties identical to those of H-2; see the Supporting Information for details.

33
- 53649089651
- Geometry optimizations and frequency calculations were performed with the Gaussian 03 suite of programs (Gaussian 03, Revision C.02, M. J. Frisch et al., Gaussian, Inc., Wallingford CT, 2004),
- Geometry optimizations and frequency calculations were performed with the Gaussian 03 suite of programs (Gaussian 03, Revision C.02, M. J. Frisch et al., Gaussian, Inc., Wallingford CT, 2004),

34
- 4243943295
- using the exchange-correlation potential PBE (J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 1996, 77, 3865),
- using the exchange-correlation potential PBE (J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 1996, 77, 3865),

35
- 49049133260
- the SDD basis set for cobalt (P. Fuentealba, H. Preuss, H. Stoll, L. von Szentpaly, Chem. Phys. Lett. 1982, 89, 418), and the 6-311G(d,p) basis set for all other atoms; see the Supporting Information for details.
- the SDD basis set for cobalt (P. Fuentealba, H. Preuss, H. Stoll, L. von Szentpaly, Chem. Phys. Lett. 1982, 89, 418), and the 6-311G(d,p) basis set for all other atoms; see the Supporting Information for details.

36
- 53649085001
- This assumption is supported by the calculated 1H and 31P NMR chemical shifts of 2a: δ(1H, 2.4 (CoH, 0.9 (tBu, 1.4 ppm (tBu, δ31P, 179, 32, and 123 ppm. These values are in good agreement with those observed experimentally at -80 °C. The hydrogen atom interacting with cobalt displays a characteristic high-field shift while the most shielded signal in the 31P NMR spectrum is assigned to the protonated phosphorus atom
- 31P NMR spectrum is assigned to the protonated phosphorus atom.

37
- 53349137598
- S. Ito, M. Kibuchi, M. Yoshifuji, A. J. Arduengo III, T. A. Konovalova, L. D. Kispert, Angew. Chem. 2006, 118, 4447;
- (2006) Angew. Chem , vol.118 , pp. 4447
- Ito, S.¹ Kibuchi, M.² Yoshifuji, M.³ Arduengo III, A.J.⁴ Konovalova, T.A.⁵ Kispert, L.D.⁶

38
- 33746275937
- Angew. Chem. Int. Ed. 2006, 45, 4341.
- (2006) Angew. Chem. Int. Ed , vol.45 , pp. 4341

39
- 0033533955
- A. S. Weller, C. D. Andrews, A. D. Burrows, M. Green, J. M. Lynam, M. F. Mahon, C. Jones, Chem. Commun. 1999, 2147.
- (1999) Chem. Commun , pp. 2147
- Weller, A.S.¹ Andrews, C.D.² Burrows, A.D.³ Green, M.⁴ Lynam, J.M.⁵ Mahon, M.F.⁶ Jones, C.⁷

40
- 38649133878
- M. M. Al-Ktaifani, P. B. Hitchcock, J. F. Nixon, J. Organomet. Chem. 2008, 693, 611.
- (2008) J. Organomet. Chem , vol.693 , pp. 611
- Al-Ktaifani, M.M.¹ Hitchcock, P.B.² Nixon, J.F.³

41
- 51149214048
- For related triphosphacyclopentadiene complexes, see: a
- For related triphosphacyclopentadiene complexes, see: a) V. Caliman, P. B. Hitchcock, J. F. Nixon, J. Chem. Soc. Chem. Commun. 1995, 1661;
- (1995) J. Chem. Soc. Chem. Commun , pp. 1661
- Caliman, V.¹ Hitchcock, P.B.² Nixon, J.F.³

42
- 0007730767
- b) P. B. Hitchcock, J. F. Nixon, N. Sakarya, Chem. Commun. 1996, 2751;
- (1996) Chem. Commun , pp. 2751
- Hitchcock, P.B.¹ Nixon, J.F.² Sakarya, N.³

43
- 0002593631
- c) V. Caliman, P. B. Hitchcock, J. F. Nixon, L. Nyulaszi, N. Sakarya, Chem. Commun. 1997, 1305;
- (1997) Chem. Commun , pp. 1305
- Caliman, V.¹ Hitchcock, P.B.² Nixon, J.F.³ Nyulaszi, L.⁴ Sakarya, N.⁵

44
- 0003366098
- d) V. Caliman, P. B. Hitchcock, J. F. Nixon, Heteroat. Chem. 1998, 9, 1.
- (1998) Heteroat. Chem , vol.9 , pp. 1
- Caliman, V.¹ Hitchcock, P.B.² Nixon, J.F.³

45
- 53649086253
- Our assignment is supported by the calculated 31P NMR chemical shifts of 4: δ(31P, 61 (P3, 45 (P1, 51 (P4, 54 (P2, 67 ppm P5, see the Supporting Information for details
- 31P) = -61 (P3), +45 (P1), +51 (P4), +54 (P2), +67 ppm (P5); see the Supporting Information for details.

46
- 37549039510
- G. M. Sheldrick, Acta Crystallogr. Sect. A 2007, 64, 112.
- (2007) Acta Crystallogr. Sect. A , vol.64 , pp. 112
- Sheldrick, G.M.¹

47
- 0001792356
- A. L. Spek, J. Appl. Crystallogr. 2003, 36, 7.
- (2003) J. Appl. Crystallogr , vol.36 , pp. 7
- Spek, A.L.¹

48
- 0037393379
- A. J. M. Duisenberg, L. M. J. Kroon-Batenburg, A. M. M. Schreurs, J. Appl. Crystallogr. 2003, 36, 220.
- (2003) J. Appl. Crystallogr , vol.36 , pp. 220
- Duisenberg, A.J.M.¹ Kroon-Batenburg, L.M.J.² Schreurs, A.M.M.³

49
- 0344214714
- University of Göttingen, Germany
- G. M. Sheldrick, Twinabs-V1.05. University of Göttingen, Germany, 2005.
- (2005) Twinabs-V1.05
- Sheldrick, G.M.¹

50
- 0013670239
- R. Herbst-Irmer, G. M. Sheldrick, Acta Crystallogr. Sect. B 1998, 54, 443.
- (1998) Acta Crystallogr. Sect. B , vol.54 , pp. 443
- Herbst-Irmer, R.¹ Sheldrick, G.M.²

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