Electrocatalytic activity of phthalocyanines bearing thiophenes for hydrogen production from water

International Journal of Hydrogen Energy

Volumn 33, Issue 13, 2008, Pages 3281-3288

  Osmanbaş, Ömer A ^a   Koca, Atif ^a   Kandaz, Mehmet ^b   Karaca, Fatma ^a  

^a MARMARA UNIVERSITY   (Turkey)

^b SAKARYA UNIVERSITY   (Turkey)

Author keywords

Electrocatalyst; Electropolymerization; Hydrogen; Phthalocyanine; Proton reduction; Spectroelectrochemistry

Indexed keywords

BIOELECTRIC PHENOMENA; CATALYST ACTIVITY; DYES; ELECTROCATALYSIS; ELECTROCATALYSTS; ELECTROCHEMICAL SENSORS; GAS FUEL MANUFACTURE; GAS PRODUCERS; HYDROGEN; METALLIZING; ORGANIC POLYMERS; PROTONS; SOLUTIONS; SULFUR COMPOUNDS; THIOPHENE; TRANSITION METALS;

AQUEOUS SOLUTIONS; COBALT PHTHALOCYANINE (COPC); ELECTRO CATALYSTS; ELECTROCATALYTIC; ELECTROCATALYTIC ACTIVITY (ECA); ELECTRON REDUCTION; METALLO-PHTHALOCYANINES; MODIFIED ELECTRODES; PHTHALOCYANINES (PCS); PROTON REDUCTION; SPECTROELECTROCHEMICAL PROPERTIES; VOLTAMMETRIC; VOLTAMMETRIC ANALYSIS;

HYDROGEN PRODUCTION;

EID: 47049122194     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2008.04.018     Document Type: Article

References (28)

1. McDowall W., and Eames M. Towards a sustainable hydrogen economy: a multi-criteria sustainability appraisal of competing hydrogen futures. Int J Hydrogen Energy 32 (2007) 4611-4626
2. Sherif S.A., Barbir F., and Veziroglu T.N. Wind energy and the hydrogen economy-review of the technology. Sol Energy 78 (2005) 647-660
3. Muradov N.Z., and Veziroǧlu T.N. From hydrocarbon to hydrogen-carbon to hydrogen economy. Int J Hydrogen Energy 30 (2005) 225-237
4. Goltsov V.A., and Veziroglu T.N. A step on the road to hydrogen civilization. Int J Hydrogen Energy 27 (2002) 719-723
5. Contreras A., Guirado R., and Veziroglu T.N. Design and simulation of the power control system of a plant for the generation of hydrogen via electrolysis, using photovoltaic solar energy. Int J Hydrogen Energy 32 (2007) 4635-4640
6. Midilli A., and Dincer I. Key strategies of hydrogen energy systems for sustainability. Int J Hydrogen Energy 32 (2007) 511-524
7. Fujishima A., and Honda K. Electrochemical photolysis of water at a semiconductor electrode. Nature 238 (1972) 37-38
8. Osmanbaş O.A., Koca A., Özçeşmeci I., Okur A.I., and Gül A. Voltammetric, spectroelectrochemical, and electrocatalytic properties of thiol-derivatized phthalocyanines. Electrochim Acta 53 (2008) 4969-4980
9. Marshall A., Børresen B., Hagen G., Tsypkin M., and Tunold R. Hydrogen production by advanced proton exchange membrane (PEM) water electrolysers-reduced energy consumption by improved electrocatalysis. Energy 32 (2007) 431-436
10. Trueba M., Trasatti S.P., and Trasatti S. Electrocatalytic activity for hydrogen evolution of polypyrrole films modified with noble metal particles. Mater Chem Phys 98 (2006) 165-171
11. Kaneko M., and Wohrle D. Polymer-coated electrodes-new materials for science and industry. Adv Polym Sci 84 (1988) 141-228
12. Bhugun I., Lexa D., and Saveant J.M. Homogeneous catalysis of electrochemical hydrogen evolution by iron(0) porphyrins. J Am Chem Soc 118 (1996) 3982-3983
13. Koca A., Şener M.K., Koçak M.B., and Gül A. Investigation of the electrocatalytic activity of metalophthalocyanine complexes for hydrogen production from water. Int J Hydrogen Energy 31 (2006) 2211-2216
14. Koca A., and Şahin M. Photocatalytic hydrogen production by direct sun light from sulfide/sulfite solution. Int J Hydrogen Energy 27 (2002) 363-367
15. Zagal J.H. Metallophthalocyanines as catalysts in electrochemical reactions. Coord Chem Rev 119 (1992) 89-136
16. Capon J.F., Gloaguen F., Schollhammer P., and Talarmin J. Catalysis of the electrochemical H-2 evolution by di-iron sub-site models. Coord Chem Rev 249 (2005) 1664-1676
17. Pantani O., Mallart E.A., Aukauloo A., and Millet P. Electroactivity of cobalt and nickel glyoximes with regard to the electro-reduction of protons into molecular hydrogen in acidic media. Electrochem Commun 9 (2007) 54-58
18. Abea T., Fujita T., Sekimoto K., Tajiri A., and Kaneko M. Electroactivity of cobalt and nickel glyoximes with regard to the electro-reduction of protons into molecular hydrogen in acidic media. J Mol Catal A 201 (2003) 55-62
19. Cook M.J. Thin film formulations of substituted phthalocyanines. J Mater Chem 6 (1996) 677-689
20. Reddinger J.L., and Reynolds J.R. Electroactive, pi-conjugated polymers based on transition metal-containing thiophenes. Synth Met 84 (1997) 225-226
21. Yarasir M.N., Kandaz M., Şenkal B.F., Koca A., and Salih B. Polytopic cation receptor functional phthalocyanines: synthesis, characterization, electrochemistry and metal ion binding. Polyhedron 26 (2007) 1139-1147
22. Yarasir M.N., Kandaz M., Şenkal B.F., Koca A., and Salih B. Selective heavy metal receptor functional phthalocyanines bearing thiophenes: synthesis, characterization, spectroscopy and electrochemistry. Dyes Pigm 77 (2008) 7-15
23. Leznoff C.C., and Lever A.B.P. In: Leznoff C.C., and Lever A.B.P. (Eds). Phthalocyanines: properties and applications vol. 1-4 (1996), VCH, Weinheim
24. Obirai J., and Nyokong T. Synthesis, spectral and electrochemical characterization of mercaptopyrimidine-substituted cobalt, manganese and Zn(II) phthalocyanine complexes. Electrochim Acta 50 (2005) 3296-3304
25. Koca A., Özkaya A.R., Selçukoǧlu M., and Hamuryudan E. Electrochemical and spectroelectrochemical characterization of the phthalocyanines with pentafluorobenzyloxy substituents. Electrochim Acta 52 (2007) 2683-2690
26. Muthuraman G., Shim Y.B., Yoon J.H., and Won M.S. Simultaneous immobilization of cobalt tetrasulfonated phthalocyanine during electropolymerization of pyrrole in presence of surfactants: a study of film morphology and its conductivity. Synth Met 150 (2005) 165-173
27. Li H.W., and Guarr T.F. Formation of electronically conductive thin-films of metal phthalocyanines via electropolymerization. J Chem Soc Chem Commun 13 (1989) 832-834
28. Zhao F., Zhang J., Abe T., Wöhrle D., and Kaneko M. Electrocatalytic proton reduction by phthalocyanine cobalt derivatives incorporated in poly(4-vinylpyridine-co-styrene) film. J Mol Catal A 145 (1999) 245-256