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Volumn 47, Issue 12, 2008, Pages 5314-5323

Redox transformations of bis(2,2′-bipyridine)(1-methyl-1-pyridin-2- yl-ethylamine)ruthenium(II)

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Indexed keywords


EID: 46949101667     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic800483g     Document Type: Article
Times cited : (4)

References (60)
  • 28
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    • Fisch, M. J.; et al. Gaussian 03, revision D.01; Gaussian, Inc.: Wallingford, CT, 2004.
    • Fisch, M. J.; et al. Gaussian 03, revision D.01; Gaussian, Inc.: Wallingford, CT, 2004.
  • 44
    • 46949104192 scopus 로고    scopus 로고
    • Although the kinetics for the proton-coupled electron transfer are slow in this pH region (pH 4-7, spectroelectrochemical measurements were performed over sufficiently long times (40-60 min between points) to permit equilibration. Above pH 7, however, the kinetics were too slow for equilibration even on this time scale, thus establishing an upper limit on the pH range for which reliable data could be obtained
    • Although the kinetics for the proton-coupled electron transfer are slow in this pH region (pH 4-7), spectroelectrochemical measurements were performed over sufficiently long times (40-60 min between points) to permit equilibration. Above pH 7, however, the kinetics were too slow for equilibration even on this time scale, thus establishing an upper limit on the pH range for which reliable data could be obtained.
  • 45
    • 46949106520 scopus 로고    scopus 로고
    • -1) where the values were found to be independent of the sweep rate. Although wave I is quasireversible in this pH region (pH < 2.2), the half-wave potentials provide reasonable approximations of the values that would be obtained were the system reversible.
    • -1) where the values were found to be independent of the sweep rate. Although wave I is quasireversible in this pH region (pH < 2.2), the half-wave potentials provide reasonable approximations of the values that would be obtained were the system reversible.
  • 48
    • 46949107915 scopus 로고    scopus 로고
    • McCleverty, J. A, Meyer, T. J, Eds, Elsevier: New York
    • Richardson, D. E. In Comprehensive Coordination Chemistry II; McCleverty, J. A., Meyer, T. J., Eds.; Elsevier: New York, 2004; Vol. 2, pp 633-642.
    • (2004) Comprehensive Coordination Chemistry II , vol.2 , pp. 633-642
    • Richardson, D.E.1
  • 50
    • 46949084464 scopus 로고    scopus 로고
    • 2 bond lies along the z axis and the Ru-N bond for the mpea pyridyl group lies along the x axis.
    • 2 bond lies along the z axis and the Ru-N bond for the mpea pyridyl group lies along the x axis.
  • 51
    • 46949089929 scopus 로고    scopus 로고
    • The nitrogen is the more electronegative element in the Ru-N bond and therefore is regarded as having sole ownership of the shared electrons for the purpose of assigning formal charges and oxidation states
    • The nitrogen is the more electronegative element in the Ru-N bond and therefore is regarded as having sole ownership of the shared electrons for the purpose of assigning formal charges and oxidation states.
  • 53
    • 46949107453 scopus 로고    scopus 로고
    • There are weak effects associated with the ability of the solvent to donate a hydrogen bond (a). These effects, which likely arise from solvent interactions with the pyridyl ligands, are similar in magnitude for the two complexes.
    • There are weak effects associated with the ability of the solvent to donate a hydrogen bond (a). These effects, which likely arise from solvent interactions with the pyridyl ligands, are similar in magnitude for the two complexes.
  • 54
    • 46949105913 scopus 로고    scopus 로고
    • -1.
    • -1.
  • 55
    • 46949098230 scopus 로고    scopus 로고
    • -, and protonation thus occurs at the oxygen.
    • -, and protonation thus occurs at the oxygen.
  • 60
    • 46949087037 scopus 로고    scopus 로고
    • Glendening, E. D, Reed, A. E, Carpenter, J. E, Weinhold, F. NBO, version 3.1. Implemented with Gaussian03
    • Glendening, E. D.; Reed, A. E.; Carpenter, J. E.; Weinhold, F. NBO, version 3.1. Implemented with Gaussian03.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.