Ligand Dehydrogenation in Ruthenium - Amine Complexes: Reactivity of 1,2-Ethanediamine and 1,1,1-Tris(aminomethyl)ethane

Inorganic Chemistry

Volumn 36, Issue 13, 1997, Pages 2804-2815

  Bernhard, Paul ^c   Bull, Daryl J ^a   Bürgi, Hans Beat ^b   Osvath, Peter ^a,d   Raselli, Andrea ^b   Sargeson, Alan M ^a  

^a AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

^b UNIVERSITY OF BERN   (Switzerland)

^c CIBA GEIGY LTD   (Switzerland)

^d CSIRO   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000283097     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic961021q     Document Type: Article

References (56)

1. Goto, M.; Takeshita, M.; Kanda, N.; Sakai, T.; Goedken, V. L. Inorg. Chem. 1985, 24, 582.
2. Goedken, V. L. J. Chem. Soc., Chem. Commun. 1972, 207.
3. Olson, D. C.; Vasilevskis. J. Inorg. Chem. 1971, 10, 463.
4. Barefield, E. K.; Mocella, M. T. J. Am. Chem. Soc. 1975, 97, 4238.
5. Morliere, P.; Patterson, L. K. Inorg, Chem. 1982, 21, 1833.
6. Maruthamuthu, P.; Patterson, L. K.; Ferraudi, G. Inorg, Chem. 1978, 17, 3157.
7. Jaacobi, M.; Meyerstein, D.; Lilie, J. Inorg. Chem. 1979, 18, 429.
8. Curtis, N. F. J. Chem. Soc. A 1971, 2834.
9. Lane, B. C.; Lester, J. E.; Basolo, F. J. Chem. Soc., Chem. Commun. 1971, 1618.
10. McWhinnie, W. K.; Miller, J. D.; Watts, J. B.; Wadden, D. Y. J. Chem. Soc., Chem. Commun. 1971, 629.
11. Mahoney, D. F.; Beattie, J. K. Inorg. Chem. 1973, 12, 2561.
12. Diamond, S. E.; Tom, G. M.; Taube, H. J. Am. Chem. Soc. 1975, 97, 2661.
13. Wong, K.-Y.; Che, C.-M.; Li, C.-K.; Chiu, W.-H.; Zhou, Z.-Y.; Mak, T. C. W. J. Chem. Soc., Chem. Commun. 1992, 754.
14. Ridd, M. J.; Keene, F. R. J. Am. Chem. Soc. 1981, 103, 5733.
15. Keene, F. R.; Ridd, M. J.; Snow, M. R. J. Am. Chem. Soc: 1983, 105, 7075.
16. Adcock, P. A.; Keene, F. R.; Smythe, R. E.; Snow, M. R. Inorg. Chem. 1984, 23, 2336.
17. Whebell, G. W.; Keene, F. R. Aust. J. Chem. 1986, 39, 2027.
18. Alvarez, V. E.; Allen, R. J.; Matsubara, T.; Ford, P. C. J. Am. Chem. Soc. 1974, 96, 7686.
19. Miller, J. D.; Watts, J. B.; Waddan, D. Y. Inorg. Chim. Acta 1975, 12, 267.
20. Brown, G. M.; Weaver, T. R.; Keene, F. R.; Meyer, T. J. Inorg. Chem. 1976, 15, 190.
21. Keene, F. R.; Salmon, D. J.; Meyer, T. J. J. Am. Chem. Soc. 1976, 98, 1884.
22. Hoshino, Y.; Okuyama, F.; Nanba, A.; Shimizu, K.; Sato, G. P. Bull, Chem. Soc. Jpn. 1992, 65, 876.
23. Lay, P. A. Ph.D. Thesis, Australian National University, 1981.
24. Lay, P. A.; Sargeson, A. M.; Skelton, B. W.; White, A. H. J. Am. Chem. Soc. 1982, 104, 6161.
25. Lay, P. A.; Sargeson, A. M. Inorg. Chim. Acta 1992, 198-200, 449.
26. Keene, F. R.; Lay, P. A.; Sneddon, G. E.; Whebell, G. W. Aust. J. Chem. 1993, 46, 1763.
27. Schwarz, F.; Schöllhorn, H.; Thewalt, U.; Lippert, B. J. Chem. Soc. Chem. Commun. 1990, 1282.
28. Tovrog, B. S.; Diamond, S. E.; Mares, F. J. Am. Chem. Soc. 1979, 101, 5067.
29. Ridd, M. J.; Gakowski, D. J.; Sneddon, G. E.; Keene, F. R. J. Chem. Soc., Dalton Trans. 1992, 1949.
30. Thompson, M. S.; Meyer, T. J. J. Am. Chem. Soc. 1982, 104, 4106.
31. Hagen, K. S.; Sargeson, A. M. Unpublished.
32. Bernhard, P.; Sargeson, A. M. J. Am. Chem. Soc. 1989, 111, 597.
33. Smolenaers, P. J. Ph.D. Thesis, University of Sydney, 1981.
34. 24-26For x = 2 or 3 (tridentate and bidentate ligands, respectively), it is likely that two ligands are each singly deprotonated in the same manner.
35. Albert, A.; Serjeant, E. P. The Determination of lionization Constants, 3rd ed.; Chapman and Hall: London, 1984.
36. Osborne, M. R. In Numerical Methods for Non-Linear Optimization; Lootsma, F. A., Ed.; Academic Press: New York, 1972: Chapter 11.
37. IGOR Version 1.26, Wavemetrics Inc.
38. KaleidaGraph Version 3.0.1, Abelbeck Software.
39. Shriver, D. F.; Drezdzon, M. A. The Manipulation of Air Sensitive Compounds; 2nd ed.; Wiley: New York. 1986.
40. Bernhard, P.; Bull, D. J.; Bürgi, H. B.; Raselli, A.; Sargeson, A. M. In preparation.
41. Meyer, T. J.; Taube, H. Inorg. Chem. 1968, 7, 2369.
42. Elibernd, H.; Beattie, J. K. Inorg. Chem. 1969, 8, 893.
43. Elsbernd, H.; Beattie, J. K. J. Chem. Soc. (A) 1970, 2598.
44. Sharpe, A. G. The Chemistry of Cyano Complexes of the Transition Metals; Academic Press: London, 1976.
45. Bernhard, P.; Sargeson, A. M.; Anson, F. C. Inorg. Chem. 1988, 27, 2754.
46. 1 + 0.69 V, I = 0.5 M (Kläning, U. Department of Chemistry, Aarhus University, Aarhus C, Denmark. Unpublished.
47. Bernhard, P.; Sargeson, A. M. J. Chem. Soc., Chem. Commun. 1985, 1516.
48. -1 at I = 0.2 M.
49. Bernhard, P.; Anson, F. C. Inorg. Chem. 1989, 28, 3272.
50. Bernhard, P.; Bürgi, H. B.; Raselli, A.; Sargeson, A. M. Inorg. Chem. 1989, 28, 3234.
51. Patel, A.; Ludi. A.; Bürgi, H. B.; Raselli, A.; Bigler, P. Inorg. Chem. 1992, 31, 3405.
52. Bernhard, P.; Sargeson, A. M. Inorg. Chem. 1988, 27, 2582.
53. Beattie, J. K.; Smolenaers, P. J. J. Phys. Chem. 1986, 90, 3684.
54. Brown, G. M.; Sutin, N. J. Am. Chem. Soc. 1979, 101, 883.
55. Waysbort, D.; Navon, G. J. Chem. Soc., Chem. Commun. 1971, 1410.
56. Bernhard, P.; Bull, D. J.; Robinson, W. T.; Sargeson, A. M. Aust. J. Chem. 1992, 45, 1241.