Avoiding olefin isomerization during decyanation of alkylcyano α,ω-dienes: A deuterium labeling and structural study of mechanism

Journal of Organic Chemistry

Volumn 73, Issue 13, 2008, Pages 4962-4970

  Rojas, Giovanni ^a   Wagener, Kenneth B ^a  

^a University of Florida   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTIONS; COMPLEXATION; DEUTERIUM; ELECTRON TRANSITIONS; HYDROGEN; ISOMERIZATION; ISOMERS; LABELING; OLEFINS; PROCESS DESIGN; PROCESS ENGINEERING; SYNTHESIS (CHEMICAL);

(E ,3E) PROCESS; AMERICAN CHEMICAL SOCIETY (ACS); CHEMICAL EQUATIONS; DEUTERATION; DEUTERIUM LABELLING; HYDROGEN DONORS; INTRAMOLECULAR CYCLIZATION; MECHANISTIC INVESTIGATIONS; MOLECULAR DESIGNS; OLEFIN ISOMERIZATION; PRODUCT MIXTURES; QUANTITATIVE YIELDS; REACTION CONDITIONS; STRUCTURAL STUDIES; SYNTHESIS (OF CHIRAL IONIC LIQUIDS); TWO-STEP SYNTHETIC PATHWAY;

CHEMISTRY;

ALCOHOL; ALKADIENE; DEUTERIUM; HYDROGEN;

ARTICLE; CYANATION; CYCLIZATION; DECYANATION; ELIMINATION REACTION; ISOMERIZATION; ISOTOPE LABELING; MOLECULAR MODEL; NONHUMAN; OLEFINATION; PROCESS DESIGN; QUANTITATIVE ANALYSIS; STRUCTURE ANALYSIS;

EID: 46849110635     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo800640j     Document Type: Article

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