Alfred Werner's inorganic counterparts of racemic and mesomeric tartaric acid: A milestone revisited

Inorganic Chemistry

Volumn 43, Issue 20, 2004, Pages 6249-6254

  Jackson, W Gregory ^a   McKeon, Josephine A ^a   Cortez, Silvia ^a  

^a UNIVERSITY OF NEW SOUTH WALES   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

TARTARIC ACID;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL BINDING; ISOMER; OPTICAL RESOLUTION; PROTON NUCLEAR MAGNETIC RESONANCE; RACEMIC MIXTURE;

COBALT; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; STEREOISOMERISM; TARTRATES;

EID: 4644339120     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic040042e     Document Type: Article

References (40)

1. Werner, A.; King, V. L. Ber. Dtsch. Chem. Ges. 1911, 44, 1887.
2. Werner, A. Ber. Dtsch. Chem. Ges. 1914, 47, 3087.
3. Jørgensen, S. M. Z. Anorg. Chem. 1898, 16, 184.
4. Werner, A. Ber. Dtsch. Chem. Ges. 1913, 46, 3674.
5. Kauffman, G. B. Coord. Chem. Rev. 1972, 9, 339.
6. Kauffman, G. B. Coord. Chem. Rev. 1974, 12, 105.
7. Thewalt, U. Acta Crystallogr. 1970, B26, 81.
8. Thewalt, U.; Marsh, R. E. Inorg. Chem. 1970, 9, 1604.
9. Thewalt, U.; Marsh, R. E. J. Am. Chem. Soc. 1967, 89, 6362.
10. Wieghardt, K.; Weiss, J.; Siebert, H. Z. Anorg. Allg. Chem. 1968, 383, 151.
11. Wieghardt, K.; Weiss, J.; Siebert, H. Z. Anorg. Allg. Chem. 1968, 361, 169.
12. Weiss, J.; Siebert, H.; Wieghardt, K. Acta Crystallogr. 1970, B26, 1709.
13. Goldstein, P. Diss. Abstr. 1964, 24, 2708.
14. Chatt, J.; Duncanson, L. A.; Gatehouse, B. M.; Lewis, J.; Nyholm, R. S.; Tobe, M. L.; Todd, P. F.; Venanzi, L. M. J. Chem. Soc. A 1959, 4073.
15. Gatehouse, B. M. J. Inorg. Nucl. Chem. 1958, 8, 79.
16. Nakamoto, K.; Fujita, J.; Murata, H. Bull. Chem. Soc. Jpn. 1958, 80, 4817.
17. Davies, R.; Mon, M.; Sykes, A. G.; Weil, J. A. Inorg. Synth. 1970, 12, 197.
18. Bailar, J. C., Jr. As quoted in ref 6.
19. Fallab, S.; Zehnder, M.; Thewalt, U. Helv. Chim. Acta 1980, 63, 1491.
20. Thewalt, U.; Marsh, R. E. Inorg. Chem. 1971, 10, 1789.
21. Thewalt, U.; Struckmeier, G. Z. Anorg. Allg. Chem. 1976, 163.
22. Lifschitz, J. Z. Phys. Chem. 1925, 114, 485.
23. Garbett, K.; Gillard, R. D. J. Chem. Soc. A 1968, 1725.
24. Jackson, W. G.; McKeon, J. A. 2004, in review.
25. Werner, A. Justus Liebigs Ann. Chem. 1910, 375, 1.
26. Werner, A.; Kuh, H.; Wust, P. Ber. Dtsch. Chem. Ges. 1914, 47, 1961.
27. Garbett, K.; Gillard, R. D. Chem. Commun. 1965, 45.
28. Werner went to some pains to reconstruct a racemic isomer from a 1:1 mixture of the separated D and L forms and to show through solubility measurements that it was different than his inactive meso complex.
29. Kitson, R. E. Anal. Chem. 1950, 22, 664.
30. Although the bridging nitro complex is reported as very unreactive (ref 17), the bridge can be completely cleaved in base, readily, and also in hot triflic acid with heating.
31. Barro, R.; Marsh, R. E.; Schaefer, W. P. Inorg. Chem. 1970, 9, 2131.
32. Yamanari, K.; Shimura, Y. Chem. Lett. 1984, 761.
33. Murata, M.; Kojima, M.; Hioki, A.; Miyagawa, M.; Hirotsu, M.; Nakajima, K.; Kita, M.; Kashino, S.; Yoshikawa, Y. Coord. Chem. Rev. 1998, 174, 109.
34. Jackson, W. G.; Sargeson, A. M. Inorg. Chem. 1988, 27, 1068.
35. Jackson, W. G.; Rahman, A. F. M. M.; Craig, D. C. Inorg. Chem. 2003, 42, 383.
36. Mori, M.; Weil, J. A. J. Am. Chem. Soc. 1967, 89, 3732.
37. Mori, M.; Weil, J. A.; Ishiguro, M. J. Am. Chem. Soc. 1968, 90, 615.
38. Stevenson, M. B.; Sykes, A. G. J. Chem. Soc. A 1969, 3979.
39. - ion first reduces the superoxo to the peroxo ion.
40. Buckingham, D. A.; Cresswell, P. J.; Sargeson, A. M.; Jackson, W. G. Inorg. Chem. 1981, 20, 1647.