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9
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0003898518
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Department of Chemistry, University of Glasgow, Scotland, excluding 6
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C.J. Gilmore, MITHRIL, Program for the Automatic Solution of Crystal Structures from X-ray data, Department of Chemistry, University of Glasgow, Scotland, 1984, excluding 6. For 6, G.M. Sheldrick, SHELXS-86, Program for Crystal Structure Determination, University of Göttingen, Germany, 1986.
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MITHRIL, Program for the Automatic Solution of Crystal Structures from X-ray Data
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Gilmore, C.J.1
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10
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1542777478
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For 6, University of Göttingen, Germany
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C.J. Gilmore, MITHRIL, Program for the Automatic Solution of Crystal Structures from X-ray data, Department of Chemistry, University of Glasgow, Scotland, 1984, excluding 6. For 6, G.M. Sheldrick, SHELXS-86, Program for Crystal Structure Determination, University of Göttingen, Germany, 1986.
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SHELXS-86, Program for Crystal Structure Determination
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Sheldrick, G.M.1
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12
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0003534160
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Universities of Western Australia, Geneva and Maryland
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S.R. Hall, H.D. Flack, J.M. Stewart, Xtal3.2, Program for X-ray Crystal Structure Analysis, Universities of Western Australia, Geneva and Maryland, 1992.
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(1992)
Xtal3.2, Program for X-ray Crystal Structure Analysis
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Hall, S.R.1
Flack, H.D.2
Stewart, J.M.3
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13
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85033923639
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CAChe Scientific, The calculations were carried out on a Power Macintosh 9500 (Apple) at the Information Processing Center of the Naruto University of Education
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ZINDO and EHMO (CAChe version 3.8), CAChe Scientific, 1995. The calculations were carried out on a Power Macintosh 9500 (Apple) at the Information Processing Center of the Naruto University of Education.
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(1995)
ZINDO and EHMO (CAChe Version 3.8)
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19
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85033936176
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note
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-1).
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24
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85033909803
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note
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All complexes in the series, pyse-N,O (4), pysi-N,O (5) and pyso-N,O (6), show fundamentally similar structures, comprised of the chelate system with a pyridine ring. The chelate Co-O-S-C-N portion of the ligand takes an envelope conformation, and the oxygen is deviated from the least-squares plane (0.49 Å for 4, 0.44 Å for 5 and 0.47 Å for 6). Deviation from planality as defined by the angle between the least-squares planes of CoSCN and the pyridine ring is 0.73° for 4, 3.15° for 5, and 0.97° for 6.
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