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Volumn 174, Issue 1, 1998, Pages 109-131

A complete series of stepwise oxidation of [Co(2-pyridinethiolato)(en)2]2+. Characterization of the 2-pyridinesulfenato-N,S and -N,O, 2-pyridinesulfinato-N,S and -N,O, and 2-pyridinesulfonato-N,O complexes

Author keywords

Cobalt complexes; Ligand oxidation; Sulfenato complexes; Sulfinato complexes; Sulfonato complexes; Thiolato complexes

Indexed keywords


EID: 0032119635     PISSN: 00108545     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0010-8545(97)00084-2     Document Type: Article
Times cited : (30)

References (25)
  • 9
    • 0003898518 scopus 로고
    • Department of Chemistry, University of Glasgow, Scotland, excluding 6
    • C.J. Gilmore, MITHRIL, Program for the Automatic Solution of Crystal Structures from X-ray data, Department of Chemistry, University of Glasgow, Scotland, 1984, excluding 6. For 6, G.M. Sheldrick, SHELXS-86, Program for Crystal Structure Determination, University of Göttingen, Germany, 1986.
    • (1984) MITHRIL, Program for the Automatic Solution of Crystal Structures from X-ray Data
    • Gilmore, C.J.1
  • 10
    • 1542777478 scopus 로고
    • For 6, University of Göttingen, Germany
    • C.J. Gilmore, MITHRIL, Program for the Automatic Solution of Crystal Structures from X-ray data, Department of Chemistry, University of Glasgow, Scotland, 1984, excluding 6. For 6, G.M. Sheldrick, SHELXS-86, Program for Crystal Structure Determination, University of Göttingen, Germany, 1986.
    • (1986) SHELXS-86, Program for Crystal Structure Determination
    • Sheldrick, G.M.1
  • 13
    • 85033923639 scopus 로고
    • CAChe Scientific, The calculations were carried out on a Power Macintosh 9500 (Apple) at the Information Processing Center of the Naruto University of Education
    • ZINDO and EHMO (CAChe version 3.8), CAChe Scientific, 1995. The calculations were carried out on a Power Macintosh 9500 (Apple) at the Information Processing Center of the Naruto University of Education.
    • (1995) ZINDO and EHMO (CAChe Version 3.8)
  • 19
    • 85033936176 scopus 로고    scopus 로고
    • note
    • -1).
  • 24
    • 85033909803 scopus 로고    scopus 로고
    • note
    • All complexes in the series, pyse-N,O (4), pysi-N,O (5) and pyso-N,O (6), show fundamentally similar structures, comprised of the chelate system with a pyridine ring. The chelate Co-O-S-C-N portion of the ligand takes an envelope conformation, and the oxygen is deviated from the least-squares plane (0.49 Å for 4, 0.44 Å for 5 and 0.47 Å for 6). Deviation from planality as defined by the angle between the least-squares planes of CoSCN and the pyridine ring is 0.73° for 4, 3.15° for 5, and 0.97° for 6.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.