Stereoselective synthesis of (+)-nephrosteranic acid, (+)-trans-cognac lactone, and (+)-trans-whisky lactone using a chiral cyclohexadienyl Ti compound

Chemistry - A European Journal

Volumn 10, Issue 17, 2004, Pages 4171-4185

  Schleth, Florian ^a,b   Vogler, Thomas ^a   Harms, Klaus ^a   Studer, Armido ^a,b  

^a PHILIPPS UNIVERSITY MARBURG   (Germany)

^b UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

Asymmetric synthesis; Cyclohexadienes; Lactones; Natural products; Synthetic methods; Titanates

Indexed keywords

ALCOHOLS; ALDEHYDES; AROMATIC COMPOUNDS; STEREOCHEMISTRY; TITANIUM COMPOUNDS;

3-METALATED 1,4-CYCLOHEXADIENES; 3-STANNYLATED 1,4-CYCLOHEXADIENES; CYCLOHEXADIENYL; ENANTIOSELECTIVITIES;

SYNTHESIS (CHEMICAL);

1,4 CYCLOHEXADIENE DERIVATIVE; 2,2 DIMETHYL ALPHA,ALPHA,ALPHA',ALPHA' TETRAPHENYL 1,3 DIOXOLANDIMETHANOL; ACID; ALDEHYDE DERIVATIVE; ALIPHATIC COMPOUND; ALKADIENE; ALLYL ALCOHOL; AROMATIC COMPOUND; BETA CYCLOHEXADIENYLDIISOPINOCAMPHEYLBORANE; BORANE DERIVATIVE; COGNAC LACTONE; GAMMA BUTYROLACTONE DERIVATIVE; LACTONE DERIVATIVE; LEWIS ACID; METHANOL DERIVATIVE; NEPHROSTERANIC ACID; TITANIUM DERIVATIVE; UNCLASSIFIED DRUG; WHISKY LACTONE;

ALLYLATION; ARTICLE; CATALYST; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; DIASTEREOISOMER; ENANTIOSELECTIVITY; REACTION ANALYSIS; SILYLATION; STEREOCHEMISTRY; SYNTHESIS; TECHNIQUE;

ALDEHYDES; CRYSTALLOGRAPHY, X-RAY; FURANS; INDICATORS AND REAGENTS; LACTONES; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR CONFORMATION; ORGANOMETALLIC COMPOUNDS; STEREOISOMERISM;

EID: 4644294612     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200400237     Document Type: Article

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