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4644239504
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note
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Only binding of dabco to the "outside" of ZnP was observed, as seen for tbpy. We attribute this to the bulkiness of dabco, which cannot be easily accommodated within the cavity in ZnP.
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26
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0345219779
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27
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4644332273
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note
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It is proposed that a structural rearrangement of the host and/or electrostatic interactions occur upon binding of V and these alterations are responsible for the observed allosteric effect Current investigations are focused on high-level molecular-modeling studies to obtain further insight into the processes reported herein.
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