Formation of hexacoordinate complexes of PhCCSiF3 with 2,2′-bipyridine and with 1,10-phenanthroline through intermolecular silicons⋯nitrogen interactions

Inorganic Chemistry

Volumn 43, Issue 19, 2004, Pages 5792-5794

  Nakash, Moshe ^a   Goldvaser, Michael ^a   Goldberg, Israel ^a  

^a TEL AVIV UNIVERSITY   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

1,10 PHENANTHROLINE; 2,2' BIPYRIDINE; LIGAND; METAL COMPLEX; NITROGEN; SILANE DERIVATIVE; SILICON DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; GEOMETRY; MOLECULAR INTERACTION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE; STOICHIOMETRY; SUPRAMOLECULAR CHEMISTRY;

EID: 4644256740     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic049125l     Document Type: Article

References (24)

1. (a) The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998.
2. (b) The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; Wiley: Chichester, U.K., 1989.
3. Comprehensive Supramolecular Chemistry; Atwood, J. L., Davies, J. E. D., Macnicol, D. D., Vögtle, F., Eds.; Elsevier: Oxford, 1996.
4. Nakash, M.; Goldvaser, M. J. Am. Chem. Soc. 2004, 126, 3436.
5. For recent reviews on hypervalent silicon compounds, see: (a) Kost, D.; Kalikhman, I. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; pp 1339-1445.
6. (b) Pestunovich, V.; Kirpichenko, S.; Voronkov, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; pp 1447-1537.
7. (c) Bassindale, A. R.; Glynn, S. J.; Taylor, P. G. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; pp 495-511.
8. (d) Holmes, R. R. Chem. Rev, 1996, 96, 927.
9. (e) Chuit, C.; Corriu, R. J. P.; Reye, C.; Young, J. C. Chem. Rev. 1993, 93, 1371.
10. (f) Corriu, R. J. P.; Young, J. C. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; Wiley: Chichester, U.K., 1989; pp 1241-1288.
11. (g) Tandura, S. N.; Voronkov, M. G.; Alekseev, N. V. Top. Curr. Chem. 1986, 131, 99.
12. Bain, V. A.; Killean, R. C. G.; Webster, M. Acta Crystallogr. 1969, B25, 156.
13. 4·bipy see: Adley, A. D.; Bird, P. H.; Fraser, A. R.; Onyszchuk, M. Inorg. Chem. 1972, 11, 1402.
14. 4·phen see: Nguyen, T. Q.; Qu, F.; Huang, X.; Janzen, A. F. Can. J. Chem. 1992, 70, 2089.
15. Si-F) at -91.0 ppm of free 1,8 and at a typical region for a hexacoordinate silicon structure.4
16. See Supporting Information for details.
17. 1H NMR spectra.
18. Connors, K. A. In Binding Constants: The Measurement of Molecular Complex Stability; Wiley: New York, 1987; pp 21-24.
19. o), R1 = 0.055 (wR2 = 0.104) for all unique data.
20. o), R1 = 0.099 (wR2 = 0.142) for all unique data.
21. Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, 1998; p 181-265.
22. Bondi, A. J. Phys. Chem. 1964, 68, 441.
23. Longer Si⋯N intermolecular bond length, of 2.257 Å, was calculated for the pentacoordinate complex of silane 1 with pyridine.3
24. This is also evident in the CPK representation of the complexes shown in Figures 2 and 3.