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Most alkali metal salts of polyoxometalates exhibit metaloxygen coordinatve interactions. For examples, see a) B. Hedman, Acta Chem. Scand. Ser. A 1978, 32, 439;
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19
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4644281396
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note
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2 groups of 1 and a bridging oxygen atom of the anion (C⋯O 3.180 Å).
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20
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4644273611
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A.M.C.T. PLATON, Utrecht University, Utrecht, The Netherlands, Spek, A.L. 1998
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21
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4644340256
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note
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2 group of 2 and terminal oxygen atoms of the anion (C⋯O 3.208 and 2.948 Å).
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22
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36
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4644247421
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note
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2 molecule into the pore.
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37
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0003506516
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Academic Press, London, UK
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S. J. Gregg, K. S. W. Sing, Adsorption, Surface Area and Porosity, Academic Press, London, UK, 1982.
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Gregg, S.J.1
Sing, K.S.W.2
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4644259173
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note
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Exchange of ethanol with the pre-included water seems unlikely, since the assembly after ethanol sorption still contained, as estimated from thermogravimetric and elemental analyses, two water molecules in addition to the four ethanol molecules per anion.
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39
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