Bonding, backbonding, and spin-polarized molecular orbitals: Basis for magnetism and semiconducting transport in V[TCNE]x∼2

Physical Review Letters

Volumn 100, Issue 25, 2008, Pages

  Kortright, J B ^a   Lincoln, D M ^b   Edelstein, R Shima ^b   Epstein, A J ^b  

^a LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^b OHIO STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; ATOMIC SPECTROSCOPY; CHEMICAL BONDS; CIRCULAR DICHROISM SPECTROSCOPY; COVALENT BONDS; DICHROISM; FLOW INTERACTIONS; MAGNETIC SEMICONDUCTORS; MAGNETISM; MOLECULAR MODELING; MOLECULAR ORBITALS; MOLECULES; OPTICAL PROPERTIES; QUANTUM CHEMISTRY; ROCKETS; SPIN DYNAMICS; X RAY FILMS; X RAY SPECTROSCOPY;

(PL) PROPERTIES; AMERICAN PHYSICAL SOCIETY (APS); ATOMIC CALCULATIONS; BACK-BONDING INTERACTIONS; BONDING INTERACTIONS; LIGAND FIELDS; MAGNETIC (CE); MAGNETIC CIRCULAR DICHROISM (MCD); ORBITALS; SPECTRA (CO); X-RAY ABSORPTION (XANES) SPECTROSCOPIES;

ABSORPTION SPECTROSCOPY;

EID: 46349088211     PISSN: 00319007     EISSN: 10797114     Source Type: Journal    
DOI: 10.1103/PhysRevLett.100.257204     Document Type: Article

References (24)

1. J.S. Miller and A.J. Epstein, Chem. Commun. (Cambridge) 13 (1998) 1319. CHCOFS 1364-548X 10.1039/a800922h
2. A.J. Epstein, MRS Bull. 28, 492 (2003). MRSBEA 0883-7694
3. J.M. Manriquez, Science 252, 1415 (1991). SCIEAS 0036-8075 10.1126/science.252.5011.1415
4. V.N. Prigodin, Adv. Mater. 14, 1230 (2002). ADVMEW 0935-9648 10.1002/1521-4095(20020903)14:17<1230::AID-ADMA1230>3.0.CO;2-5
5. N.P. Raju, J. Appl. Phys. 93, 6799 (2003). JAPIAU 0021-8979 10.1063/1.1556120
6. J.W. Yoo, Phys. Rev. Lett. 97, 247205 (2006). PRLTAO 0031-9007 10.1103/PhysRevLett.97.247205
7. J.W. Yoo, Phys. Rev. Lett. 99, 157205 (2007). PRLTAO 0031-9007 10.1103/PhysRevLett.99.157205
8. D. Haskel, Phys. Rev. B PRBMDO 0163-1829 70, 054422 (2004). 10.1103/PhysRevB.70.054422
9. K.I. Pokhodnya, A.J. Epstein, and J.S. Miller, Adv. Mater. ADVMEW 0935-9648 12, 410 (2000). 10.1002/(SICI)1521-4095(200003)12:6<410::AID- ADMA410>3.0.CO;2-B
10. C. Tengstedt, Phys. Rev. B PRBMDO 0163-1829 69, 165208 (2004). 10.1103/PhysRevB.69.165208
11. C. Tengstedt, Phys. Rev. Lett. 96, 057209 (2006). PRLTAO 0031-9007 10.1103/PhysRevLett.96.057209
12. M.P. de Jong, Phys. Rev. B PRBMDO 0163-1829 75, 064407 (2007). 10.1103/PhysRevB.75.064407
13. F. de Groot and A. Kotani, Core Level Spectroscopy of Solids (CRC Press, Boca Raton, 2008).
14. P. Frank, Inorg. Chem. 41, 3269 (2002). INOCAJ 0020-1669 10.1021/ic011221o
15. T. Mallah, Science 262, 1554 (1993). SCIEAS 0036-8075 10.1126/science.262.5139.1554
16. W.R. Entley and G.S. Girolami, Science 268, 397 (1995). SCIEAS 0036-8075 10.1126/science.268.5209.397
17. P. Carra, Phys. Rev. Lett. 70, 694 (1993). PRLTAO 0031-9007 10.1103/PhysRevLett.70.694
18. A. Zheludev, J. Am. Chem. Soc. 116, 7243 (1994). JACSAT 0002-7863 10.1021/ja00095a030
19. M.-J. Hubin-Franskin, J. Chem. Phys. 106, 35 (1997). JCPSA6 0021-9606 10.1063/1.473200
20. C.I. Oprea, A. Damian, and M.A. Girtu, J. Optoelectron. Adv. Mater. 1454-4164 8, 191 (2006).
21. G.Y. Guo, J. Phys. Condens. Matter 8, L747 (1996). JCOMEL 0953-8984 10.1088/0953-8984/8/49/005
22. A.J. Epstein and J.S. Miller, Mol. Cryst. Liq. Cryst. 233, 171 (1993). MCLCA5 0026-8941 10.1080/10587259308054959
23. F.A. Cotton, Advanced Inorganic Chemistry (Wiley-Interscience, New York, 1999).
24. J.S. Miller, Angew. Chem., Int. Ed. ACIEF5 1433-7851 45, 2508 (2006). 10.1002/anie.200503277