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Volumn 41, Issue 11, 2008, Pages 4029-4036

Theoretical studies on the thermodynamic product size distribution in nucleation - Elongation polymerization under imbalanced stoichiometry

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTIONS; CHEMICALS; COMMINUTION; DIMERIZATION; ELECTRIC FIELD EFFECTS; ELONGATION; EPITAXIAL GROWTH; MOLECULAR WEIGHT; MOLECULES; MONOMERS; NUCLEATION; NUCLEOPHILES; POLYMERIZATION; POLYMERS; SIZE DETERMINATION; STOICHIOMETRY; THERMODYNAMICS;

EID: 45849141636     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma071884a     Document Type: Article
Times cited : (18)

References (50)
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    • For representative synthetic systems exhibiting helical supramolecular structures, see: a
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  • 11
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    • For few examples of synthetic polymerizations exhibiting N-E characteristics, see: a
    • For few examples of synthetic polymerizations exhibiting N-E characteristics, see: (a) Kern, W.; Jaacks, V. J. Polym. Sci. 1960, 48, 399-404.
    • (1960) J. Polym. Sci , vol.48 , pp. 399-404
    • Kern, W.1    Jaacks, V.2
  • 20
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    • For examples of previous models suitable for studying N-E polymerizations, see: (a) Oosawa, F, Kasai, M. J. Mol. Biol. 1962, 4, 10-21
    • For examples of previous models suitable for studying N-E polymerizations, see: (a) Oosawa, F.; Kasai, M. J. Mol. Biol. 1962, 4, 10-21.
  • 23
    • 0000273919 scopus 로고    scopus 로고
    • (d) Martin, R. B. Chem. Rev. 1996, 96, 3043-3064.
    • (1996) Chem. Rev , vol.96 , pp. 3043-3064
    • Martin, R.B.1
  • 25
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    • 2nd ed, Ciferri, A, Ed, Taylor & Francis: London, Chapter 3
    • (f) van der School, P. Supramolecular Polymers, 2nd ed.; Ciferri, A., Ed.; Taylor & Francis: London, 2005; Chapter 3.
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    • van der School, P.1
  • 27
    • 0042910568 scopus 로고    scopus 로고
    • A classical example of polymerization yielding high polymers under imbalanced stoichiometry is interfacial polymerization:(a) Morgan, P. W, Kwolek, S. L. J. Chem. Educ. 1959, 36, 182-185
    • A classical example of polymerization yielding high polymers under imbalanced stoichiometry is interfacial polymerization:(a) Morgan, P. W.; Kwolek, S. L. J. Chem. Educ. 1959, 36, 182-185.
  • 29
    • 0042808785 scopus 로고    scopus 로고
    • For a more recent example of synthetic polymerization under imbalanced stoichiometry, see: c
    • For a more recent example of synthetic polymerization under imbalanced stoichiometry, see: (c) Kimura, K.; Kohama, S.; Yamashita, Y. Macromolecules 2003, 36, 5043-5046.
    • (2003) Macromolecules , vol.36 , pp. 5043-5046
    • Kimura, K.1    Kohama, S.2    Yamashita, Y.3
  • 30
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    • In this case, crystallization of the polymer product was responsible for driving the polymer growth and excluding the monofunctional monomer
    • (d) Kimura, K.; Kohama, S.; Yamashita, Y. Macromolecules 2002, 35, 7545-7552. In this case, crystallization of the polymer product was responsible for driving the polymer growth and excluding the monofunctional monomer.
    • (2002) Macromolecules , vol.35 , pp. 7545-7552
    • Kimura, K.1    Kohama, S.2    Yamashita, Y.3
  • 33
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    • The calculations were conducted using Mathematica 4.2. Representative numerical solutions were obtained when the software failed to generate algebraic solutions.
    • The calculations were conducted using Mathematica 4.2. Representative numerical solutions were obtained when the software failed to generate algebraic solutions.
  • 34
    • 45849143167 scopus 로고    scopus 로고
    • Here only two exemplary sets of conditions are chosen to illustrate the distinct behaviors of the two types of polymerizations; results of more diverse systems can be conveniently obtained by applying various conditions of interest to eqs S2-S13 provided in the Supporting Information
    • Here only two exemplary sets of conditions are chosen to illustrate the distinct behaviors of the two types of polymerizations; results of more diverse systems can be conveniently obtained by applying various conditions of interest to eqs S2-S13 provided in the Supporting Information.
  • 35
    • 45849134753 scopus 로고    scopus 로고
    • Although not obvious from Figure 1, this conclusion holds when [AV [B]0= l cf. ref 4
    • 0= l (cf. ref 4).
  • 41
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    • More recently, van der Schoot et al. have developed a statistical mechanical model suitable for evaluating the helical transition of supramolecular polymers exhibiting N - E characteristics: (a) van der Schoot, P.; Michels, M. A. J.; Brunsveld, L.; Sijbesma, R. P.; Ramzi, A. Langmuir 2000, 16, 10076-10083.
    • More recently, van der Schoot et al. have developed a statistical mechanical model suitable for evaluating the helical transition of supramolecular polymers exhibiting N - E characteristics: (a) van der Schoot, P.; Michels, M. A. J.; Brunsveld, L.; Sijbesma, R. P.; Ramzi, A. Langmuir 2000, 16, 10076-10083.
  • 50
    • 45849122362 scopus 로고    scopus 로고
    • When data were handled numerically, slight differences may occur between the calculation results from the three different methods due to small numerical errors
    • When data were handled numerically, slight differences may occur between the calculation results from the three different methods due to small numerical errors.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.