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(c) Desroy, N.; Le Roux, R.; Phansavath, P.; Chiummiento, L.; Bonini, C.; Genêt, J.-P. Tetrahedron Lett. 2003, 44, 1763-1766.
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Park, P. K.; O'Malley, S. J.; Schmidt, D. R.; Leighton, J. L. J. Am. Chem. Soc. 2006, 128, 2796-2797.
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(a) Whitehead, A.; McReynolds, M. D.; Moore, J. D.; Hanson, P. R. Org. Lett. 2005, 7, 3375-3378.
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(b) Whitehead, A.; McParland, J. P.; Hanson, P. R. Org. Lett. 2006, 8, 5025-5028.
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4444282084
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Burke and coworkers have shown this protocol to be compatible with multiple acetate protecting groups; see: Lucas, B. S, Luther, L. M, Burke, S. D. Org. Lett. 2004, 6, 2965-2968
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Burke and coworkers have shown this protocol to be compatible with multiple acetate protecting groups; see: Lucas, B. S.; Luther, L. M.; Burke, S. D. Org. Lett. 2004, 6, 2965-2968.
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16
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59849106162
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This reaction occurs via a highly regio- and stereoselective anti-SN2′ attack at the C(22) olefinic carbon within bicyclic phosphate 7 where proper orthogonal alignment of the C=Cπ* and C-OP(O)σ* orbitals allows for anti-S N2′ attack to proceed exclusively on the convex face of 7; see Scheme 4 in ref 5a
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N2′ attack to proceed exclusively on the convex face of 7; see Scheme 4 in ref 5a.
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17
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23944510563
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For selective silylation of similar 1,3-diols, see: a
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For selective silylation of similar 1,3-diols, see: (a) Soltani, O.; De Brabander, J. K. Org. Lett. 2005, 7, 2791-2793.
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33845557644
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(b) Rand, C. L.; Van Horn, D. E.; Moore, M. W.; Negishi, E. J. Org. Chem. 1981, 46, 4093-4096.
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23
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0035874732
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Inoue, A.; Kitagawa, K.; Shinokubo, H.; Oshima, K. J. Org. Chem. 2001, 66, 4333-4339.
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Inoue, A.1
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Shinokubo, H.3
Oshima, K.4
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24
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0001213599
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These results are in accordance with literature precedence that larger counterions effect the Felkin selectivity; see: Mengel, A, Reiser, O. Chem. Rev. 1999, 99, 1191-1223
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These results are in accordance with literature precedence that larger counterions effect the Felkin selectivity; see: Mengel, A.; Reiser, O. Chem. Rev. 1999, 99, 1191-1223.
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27
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38349121101
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Marshall and coworkers reported protonolysis products under Oppolzer conditions with similar homoallylic protected vinyl iodides, which we witnessed in unsuccessful reactions, along with decomposed aldehyde; see: Marshall, J. A, Eidam, P. M. Org. Lett. 2008, 10, 93-96
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Marshall and coworkers reported protonolysis products under Oppolzer conditions with similar homoallylic protected vinyl iodides, which we witnessed in unsuccessful reactions, along with decomposed aldehyde; see: Marshall, J. A.; Eidam, P. M. Org. Lett. 2008, 10, 93-96.
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28
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0001164834
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(a) Mori, Y.; Kuhara, M.; Takeuchi, A.; Suzuki, M. Tetrahedron Lett. 1988, 29, 5419-22.
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Suzuki, M.4
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0027729991
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4) failed to generate the desired C23 stereochemistry. (a) Evans, D. A.; Ng, H. P.; Rieger, D. L. J. Am. Chem. Soc. 1993, 115, 11446-59.
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4) failed to generate the desired C23 stereochemistry. (a) Evans, D. A.; Ng, H. P.; Rieger, D. L. J. Am. Chem. Soc. 1993, 115, 11446-59.
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32
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0031747783
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(c) Evans, D. A.; Kim, A. S.; Metternich, R.; Novack, V. J. J. Am. Chem. Soc. 1998, 120, 5921-5942.
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Evans, D.A.1
Kim, A.S.2
Metternich, R.3
Novack, V.J.4
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33
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0034734340
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Second generation Hoveyda-Grubbs catalyst: Garber, S. B.; Kingsbury, J. S.; Gray, B. L.; Hoveyda, A. H. J. Am. Chem. Soc. 2000, 122, 8168-8179.
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Second generation Hoveyda-Grubbs catalyst: Garber, S. B.; Kingsbury, J. S.; Gray, B. L.; Hoveyda, A. H. J. Am. Chem. Soc. 2000, 122, 8168-8179.
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34
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Myers, A. G.; Zheng, B.; Movassaghi, M. J. Org. Chem. 1997, 62, 7505-7507.
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Myers, A.G.1
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0037118313
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For examples of diimide reductions in synthesis, see: (a) Haukaas, M. H, O'Doherty, G. A. Org. Lett. 2002, 4, 1771-1774
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For examples of diimide reductions in synthesis, see: (a) Haukaas, M. H.; O'Doherty, G. A. Org. Lett. 2002, 4, 1771-1774.
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