Aerobic oxidations catalyzed by chromium corroles

Journal of the American Chemical Society

Volumn 125, Issue 5, 2003, Pages 1162-1163

  Mahammed, Atif ^a   Gray, Harry B ^b   Meier Callahan, Alexandre E ^b   Gross, Zeev ^a  

^a TECHNION ISRAEL INSTITUTE OF TECHNOLOGY   (Israel)

^b CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHROMIUM DERIVATIVE;

ARTICLE; CATALYSIS; COMPLEX FORMATION; OXIDATION; OXYGENATION; REACTION ANALYSIS;

AEROBIOSIS; BIOMIMETIC MATERIALS; CATALYSIS; CHROMIUM; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; OXYGEN; PORPHYRINS; SPECTROPHOTOMETRY, ULTRAVIOLET;

EID: 0037419796     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja028216j     Document Type: Article

References (16)

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15. 3 (1 min. 100%; 2 days, 300%; 3 days, 500%) and exo-norbornene oxide (6 h, 70%), respectively. With cyclohexene, allylic oxidation products (6 h: 300% cyclohexene oxide, 9000% 2-cyclohexene-1-ol, 8000% 2-cyclohexene-1-one) indicate a radical mechanism. Yields were determined by GC relative to an internal standard and are reported after subtraction of products obtained in control reactions.
16. 3 by GC/ MS as well.