Anomalously high-density glass of ethylbenzene prepared by vapor deposition at temperatures close to the glass-transition temperature

Chemical Physics Letters

Volumn 459, Issue 1-6, 2008, Pages 109-112

  Ishii, Kikujiro ^a   Nakayama, Hideyuki ^a   Hirabayashi, Shin ^a   Moriyama, Ryo ^a  

^a GAKUSHUIN UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL MODIFICATION; ETHYLBENZENE; GLASS; GLASS TRANSITION;

GLASS TRANSITION TEMPERATURE (TG); HIGH-DENSITY; MOLAR VOLUME (MV);

VAPOR DEPOSITION;

EID: 45449116879     PISSN: 00092614     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cplett.2008.05.050     Document Type: Article

References (19)

1. Hikawa H., Oguni M., and Suga H. J. Non-Cryst. Solids 101 (1988) 90
2. Oguni M., Hikawa H., and Suga H. Thermochim. Acta 158 (1990) 143
3. Takeda K., Yamamuro O., and Suga H. J. Phys. Chem. 99 (1995) 1602
4. Ishii K., Nakayama H., Okamura T., Yamamoto M., and Hosokawa T. J. Chem. Phys. B 107 (2003) 876
5. Ishii K., Takei M., Yamamoto M., and Nakayama H. Chem. Phys. Lett. 398 (2004) 377
6. Swallen S.F., et al. Science 315 (2007) 353
7. Kearns K.L., Swallen S.F., Ediger M.D., Wu T., and Yu L. J. Chem. Phys. 127 (2007) 154702
8. Ishii K., Nakayama H., Yagasaki Y., Ando K., and Kawahara M. Chem. Phys. Lett. 222 (1994) 117
9. Ishii K., Yoshida M., Suzuki K., Sakurai H., Shimayama T., and Nakayama H. Bull. Chem. Soc. Jpn. 74 (2001) 435
10. Nakayama H., Ohta S., Onozuka I., Nakahara Y., and Ishii K. Bull. Chem. Soc. Jpn. 77 (2004) 1117
11. Ishii K., Kobayashi Y., Sakai K., and Nakayama H. J. Phys. Chem. 110 (2006) 24827
12. K. Ishii, H. Nakayama, in: M. Tokuyama, I. Oppenheim, H. Nishiyama (Eds.), Complex Systems, The Fifth International Workshop on Complex Systems, AIP Conference Proceedings, vol. 982, 2008, p. 119.
13. Ch. Wohlfarth, B. Wohlfarth, in: M.D. Lechner (Ed.) Landolt-Börnstein, Numerical Date and Functional Relationships in Science and Technology, New Series, III/38B, Springer, 1996 (Chapter 2).
14. Barlow A.J., Lamb J., and Matheson A.J. Proc. Roy. Soc. London Ser. A 292 (1966) 322
15. Yamamuro O., Tsukushi I., Lindqvist A., Takahara S., Ishikawa M., and Matsuo T. J. Phys. Chem. B 102 (1998) 1605
16. Ishii K., Okamura T., Ishikawa N., and Nakayama H. Chem. Lett. 30 (2001) 52
17. K. Ishii, H. Nakayama, in press, manuscript in preparation.
18. Bauer C., Böhmer R., Moreno-Flores S., Richert R., Sillescu H., and Neher D. Phys. Rev. E 61 (2000) 1755
19. The explanation of the dynamics given here by the present authors is slightly different from the discussion by Ediger and coworkers [6,7] in which they assumed a large molecular mobility in the top few nanometers of the glass during deposition. The present authors consider in contrast that the dynamic interaction responsible to the formation of the dense glass may be restricted in a small range within a few molecules around a deposited molecule. This is related to the anomalous intermolecular conformation described in the last part of the paper.