One-carbon homologation of unsymmetrical ketones through magnesium β-oxido carbenoid rearrangement and trapping the enolate intermediates with electrophiles

Tetrahedron

Volumn 64, Issue 30-31, 2008, Pages 7199-7210

  Tanaka, Shu ^a   Anai, Takehiro ^a   Tadokoro, Makoto ^a   Satoh, Tsuyoshi ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

Author keywords

Oxido carbenoid; Homologation of ketones; Magnesium carbenoid; Rearrangement; Ring expansion

Indexed keywords

1 CHLOROETHYL 4 TOLYL SULFOXIDE; CARBENOID; CYCLOHEXANONE DERIVATIVE; KETONE DERIVATIVE; MAGNESIUM; SULFOXIDE;

ARTICLE; CRYSTAL STRUCTURE; DIASTEREOISOMER; GRIGNARD REACTION; PRIORITY JOURNAL; REACTION ANALYSIS;

EID: 45449086020     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2008.05.079     Document Type: Article

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