A stereodivergent approach to 5a-carba-α-D-gluco-, -α-D-galacto and -β-L-gulopyranose pentaacetates from D-mannose, based on 6-exo-dig radical cyclization and Barton-Mccombie radical deoxygenation

European Journal of Organic Chemistry

Volumn , Issue 8, 2004, Pages 1830-1840

  Gómez, Ana M ^a   Moreno, Eduardo ^a   Valverde, Serafín ^a   López, J Cristóbal ^a  

^a INSTITUTO DE QUÍMICA ORGÁNICA GENERAL   (Spain)

Author keywords

Carbohydrates; D Mannose; Radical cyclization; Radical deoxygenation; Synthesis design

Indexed keywords

2,3:4,6 DI O ISOPROPYLIDINE DEXTRO MANNOPYRANOSE; 5A CARBA ALPHA DEXTRO GLUCOPYRANOSE PENTAACETATE; ACETIC ACID DERIVATIVE; ALPHA DEXTRO GALACTOPYRANOSE PENTAACETATE; BETA LEVO GULOPYRANOSE PENTAACETATE; CARBOHYDRATE; CARBOHYDRATE DERIVATIVE; MANNOSE; TRIMETHYLSILYLACETYLIDE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CYCLIZATION; DEOXYGENATION; OZONOLYSIS; STEREOCHEMISTRY;

EID: 4544386777     PISSN: 1434193X     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejoc.200300339     Document Type: Article

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