A chemically modified platinum electrode as a bidentate diamine ligand for forming well-defined, immobilized bis(ζ1-P-ether phosphane)(diamine)ruthenium(II) complexes

Angewandte Chemie - International Edition

Volumn 43, Issue 15, 2004, Pages 2025-2028

  Novak, Filip ^a   Speiser, Bernd ^a   Lindner, Ekkehard ^a   Lu, Zhong Lin ^a   Mayer, Hermann A ^a  

^a UNIVERSITY OF TÜBINGEN   (Germany)

Author keywords

Cyclic voltammetry; Electrochemistry; Heterogeneous catalysis; Hydrogenation; Surface chemistry

Indexed keywords

CATALYST ACTIVITY; CYCLIC VOLTAMMETRY; ELECTROCHEMICAL ELECTRODES; HYDROGENATION; ORGANOMETALLICS; SURFACE TREATMENT;

CHELATE TYPE STRUCTURES; ORGANOMETALLIC SPECIES; PLATINUM ELECTRODES;

PLATINUM;

DIAMINE; METAL COMPLEX; PHOSPHORUS DERIVATIVE; PLATINUM; RUTHENIUM COMPLEX; SILANE DERIVATIVE;

ARTICLE; CHEMICAL MODIFICATION; COMPLEX FORMATION; CYCLIC POTENTIOMETRY; DECOMPOSITION; ELECTRIC POTENTIAL; ELECTROCHEMICAL ANALYSIS; ELECTRODE; MOLECULAR INTERACTION; OXIDATION KINETICS;

EID: 4544379089     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200353399     Document Type: Article

References (30)

1. D. Astruc, Pure Appl. Chem. 2003, 75, 461-481.
2. R. Shenhar, V. M. Rotello, Acc. Chem. Res. 2003, 36, 549-561.
3. E. Lindner, T. Schneller, F. Auer, H. A. Mayer, Angew. Chem. 1999, 111, 2288-2309; Angew. Chem. Int. Ed. 1999, 38, 2154-2174.
4. E. Lindner, T. Schneller, F. Auer, H. A. Mayer, Angew. Chem. 1999, 111, 2288-2309; Angew. Chem. Int. Ed. 1999, 38, 2154-2174.
5. Z.-I. Lu, E. Lindner, H. A. Mayer, Chem. Rev. 2002, 102, 3543-3578.
6. In the context of catalysis, this is often also known as to "heterogenize".
7. D. R. Rolison, Science 2003, 299, 1698-1701.
8. Molecular Design of Electrode Surfaces (Ed.: R. W. Murray (Tech. Chem. (N.Y.) 1992, 22).
9. A. Jarzȩbińska, P. Rowiński, I. Zawisza, R. Bilewicz, L. Siegfried, T. Kaden, Anal. Chim. Acta 1999, 396, 1-12.
10. M.-S. Won, Y.-J. Bae, S.-S. Lee, Y.-B. Shim, Electroanalysis 2001, 13, 1003-1007.
11. C.-C. Hsueh, Y. Liu, M. Henry, M. S. Freund, Anal. Chim. Acta 1999, 397, 135-144.
12. R. W. Murray, Acc. Chem. Res. 1980, 13, 135-141.
13. K. D. Snell, A. G. Keenan, Chem. Soc. Rev. 1979, 259-282.
14. E. Lindner, S. Al-Gharabli, I. Warad, H. A. Mayer, S. Steinbrecher, E. Plies, M. Seiler, H. Bertagnolli, Z. Anorg. Allg. Chem. 2003, 629, 161-171.
15. Z.-L. Lu, K. Eichele, E. Lindner, H. A. Mayer, Inorg. Chem. Commun. 2003, 6, 365-369.
16. Z.-L. Lu, K. Eichele, I. Warad, H. A. Mayer, E. Lindner, Z.-j. Jiang, V. Schurig, Z. Anorg. Allg. Chem. 2003, 629, 1308-1315.
17. E. Lindner, I. Warad, K. Eichele, H. A. Mayer, Inorg. Chim. Acta 2003, 350, 49-56.
18. R. Noyori, T. Ohkuma, Angew. Chem. 2001,113, 40-75; Angew. Chem. Int. Ed. 2001, 40, 40-73.
19. R. Noyori, T. Ohkuma, Angew. Chem. 2001,113, 40-75; Angew. Chem. Int. Ed. 2001, 40, 40-73.
20. F. Novak, B. Speiser, H. A. Y. Mohammad, H. A. Mayer, Electrochim. Acta, in press.
21. J. R. Lenhard, R. W. Murray, J. Electroanal. Chem. 1977, 78, 195-201.
22. F. Novak, B. Speiser, C. Tittel, unpublished results.
23. 2).
24. E. Laviron, J. Electroanal. Chem. 1979, 100, 263-270.
25. J. R. Lenhard, R. W. Murray, J. Am. Chem. Soc. 1978, 100, 7870-7875.
26. B. Speiser in Encyclopedia of Electrochemistry, Vol. 3 (Eds.: A. J. Bard, M. Stratmann, P. Unwin), Wiley-VCH, Weinheim, 2003, chap. 2.1, pp. 81-104.
27. PP = 36.41 Hz). This is consistent with an asymmetric diamine ligand coordinated trans to the two phosphane groups.
28. G. Gritzner, J. Kůta, Pure Appl. Chem. 1984, 56, 461-466.
29. H. Angerstein-Kozlowska, B. E. Conway, W. B. A. Sharp, J. Electroanal. Chem. 1973, 43, 9-36.
30. P. R. Moses, L. M. Wier, J. C. Lennox, H. O. Finklea, J. R. Lenhard, R. W. Murray, Anal. Chem. 1978, 50, 576-585.