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Volumn 43, Issue 34, 2004, Pages 4460-4462

Reversible mechanochemistry of a PdII coordination polymer

Author keywords

Coordination polymers; Macrocycles; Phosphanes; Supramolecular chemistry; Ultrasound

Indexed keywords

MOLECULAR WEIGHT; PHOSPHORUS COMPOUNDS; POLYMERS; ULTRASONIC WAVES;

EID: 4544353287     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200460040     Document Type: Article
Times cited : (151)

References (21)
  • 5
    • 0034681492 scopus 로고    scopus 로고
    • a) U. Michelsen, C. A. Hunter, Angew. Chem. 2000, 112, 780; Angew. Chem. Int. Ed. 2000, 39, 764;
    • (2000) Angew. Chem. Int. Ed. , vol.39 , pp. 764
  • 17
    • 4544319235 scopus 로고    scopus 로고
    • note
    • top does not shift further, although the fraction of cyclic monomers is lower. Based on the assumption that 2 contains a small amount of monophosphane impurities, such as monofunctionalized polymer chains or chains with one oxidized phosphane group, which act as chain ends, the observed ceiling for the concentration-dependent degree of polymerization corresponds to approximately 3.5 % impurity in the polymeric ligands.
  • 20
    • 4544386929 scopus 로고    scopus 로고
    • note
    • Ligand-exchange rates in 2 are slow on the SEC timescale. A lifetime of approximately 13 h was found for the closely related system reported in reference [4].


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.