Nitrophenolate as a building block for lanthanide chains and clusters

Angewandte Chemie - International Edition

Volumn 39, Issue 3, 2000, Pages 549-551

  Bürgstein, Markus R ^a   Roesky, Peter W ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

Author keywords

Chain structures; Cluster compound; Coordination chemistry; Hydrolyses; Rare earth compounds

Indexed keywords

LANTHANIDE; LIGAND; POTASSIUM ION;

ARTICLE; CHEMICAL BINDING; CRYSTALLIZATION; HYDROLYSIS; NONHUMAN; SYNTHESIS; X RAY DIFFRACTION;

EID: 0039598715     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(20000204)39:3<549::AID-ANIE549>3.0.CO;2-G     Document Type: Article

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18. 2 = 0.2224.
19. We consider a K-O interaction to be a coordinating interaction if the K-O distance is significantly shorter than 300 pm.
20. 2 = 0.1524. In both structures the H atoms could not be refined.
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26. Compound 2a was made four times and 2b twice. The lattice constants of the obtained crystals were determined by single-crystal X-ray diffraction each time and found to be the same.
27. X-ray structure analyses: General: All data sets were collected by STOE-IPDS. The structure was solved by Patterson methods (SHELXS-86 and SHELXL-93) and refined by full-matrix least-square techniques. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publications no. CCDC-134394 (1a), -134395 (1b), -136363 (2a), and -134397 (2b). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: ( + (44) 1223-336-033; email: deposit@ccdc.cam.ac.uk).