The preparation and X-ray crystal structure of [(AgI2) n]·n MF6 (M = Sb, As): Diiodine acting as a donor in the planar polymeric [(AgI2)n]n+

Angewandte Chemie - International Edition

Volumn 43, Issue 15, 2004, Pages 1995-1998

  Cameron, T Stanley ^b   Passmore, Jack ^a   Wang, Xinping ^a  

^a UNIVERSITY OF NEW BRUNSWICK   (Canada)

^b DALHOUSIE UNIVERSITY   (Canada)

Author keywords

Coordination modes; Iodine; Raman spectroscopy; Silver; Structure elucidation

Indexed keywords

HALOGEN COMPOUNDS; IODINE; IONS; POLYMERS;

DIHALOGEN HOMOLEPTIC SPECIES; MOLECULAR DIIODINE;

CRYSTAL STRUCTURE;

ANTIMONY; ARSENIC; CATION; IODINE; METAL DERIVATIVE; SILVER; SULFUR DIOXIDE;

ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; HALOGENATION; IONIZATION; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; MOLECULAR MECHANICS; PHASE SEPARATION; POLYMERIZATION; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 4544302899     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200352969     Document Type: Article

References (49)

1. a) R. J. Gillespie, J. Passmore, Adv. Inorg. Chem. 1975, 17, 49;
2. b) S. Brownridge, I. Krossing, J. Passmore, H. D. B. Jenkins, H. K. Roobottom, Coord. Chem. Rev. 2000, 197, 397, and references therein.
3. a) H. W. Roesky, M. Thomas, J. Schimkowiak, P. G. Jones, W. Pinkert, G. M. Sheldrick, J. Chem. Soc. Chem. Commun. 1982, 895;
4. b) T. S. Cameron, A. Decken, I. Dionne, M. Fang, I. Krossing, J. Passmore, Chem. Eur. J. 2002, 8, 3386.
5. D. Aris, J. Beck, A. Decken, I. Dionne, I. Krossing, J. Passmore, E. Rivard, F. Steden, X. P. Wang, Phosphorus, Sulfur Silicon Relat. Elem. 2004, in press.
6. a) I. Krossing, J. Am. Chem. Soc. 2001, 123, 4603;
7. b) D. V. Deubel, J. Am. Chem. Soc. 2002, 124, 12312.
8. a) G. Frenking, N. Fröhlich, Chem. Rev. 2000, 100, 717, and references therein;
9. b) A. J. Lupinetti, G. Frenking, S. H. Strauss, Angew. Chem. 1998, 110, 2229; Angew. Chem. Int. Ed. 1998, 37, 2113;
10. b) A. J. Lupinetti, G. Frenking, S. H. Strauss, Angew. Chem. 1998, 110, 2229; Angew. Chem. Int. Ed. 1998, 37, 2113;
11. c) H. Willner, F. Aubke, Chem. Eur. J. 2003, 9, 1668.
12. +, respectively (see Supporting Information and references therein);
13. n+.
14. a) D. Schröder, R. Brown, P. Schwerdtfeger, X. Wang, X. Yang, L. Wang, H. Schwarz, Angew. Chem. 2003, 115, 323; Angew. Chem. Int. Ed. 2003, 42, 311;
15. a) D. Schröder, R. Brown, P. Schwerdtfeger, X. Wang, X. Yang, L. Wang, H. Schwarz, Angew. Chem. 2003, 115, 323; Angew. Chem. Int. Ed. 2003, 42, 311;
16. b) H. Schwarz, Angew. Chem. 2003, 115, 4580; Angew. Chem. Int. Ed. 2003, 42, 4443.
17. b) H. Schwarz, Angew. Chem. 2003, 115, 4580; Angew. Chem. Int. Ed. 2003, 42, 4443.
18. a) K. Persson, Acta Crystallogr. Sect. B 1979, 35, 302;
19. b) R. Birnstock, D. Britton, Z. Kristallogr. 1970, 132, 87;
20. c) G. A. Bowmaker, A. Camus, B. W. Skelton, A. H. White, J. Chem. Soc. Dalton Trans. 1990, 727;
21. d) G. Helgesson, S. Jagner, Inorg. Chem. 1991, 30, 2574.
22. a) Organic 12 adducts: E. L. Rimmer, R. D. Bailey, T. W. Hanks, W. T. Pennington, Chem. Eur. J. 2000, 6, 22, 4071; P. Deplanv, J. R. Ferraro, M. L. Mercuri, E. F. Trogu, Coord. Chem. Rev. 1999, 188, 71; J. Janczak, Y. M. Idemori, Inorg. Chem. 2002, 41, 5059;
23. a) Organic 12 adducts: E. L. Rimmer, R. D. Bailey, T. W. Hanks, W. T. Pennington, Chem. Eur. J. 2000, 6, 22, 4071; P. Deplanv, J. R. Ferraro, M. L. Mercuri, E. F. Trogu, Coord. Chem. Rev. 1999, 188, 71; J. Janczak, Y. M. Idemori, Inorg. Chem. 2002, 41, 5059;
24. a) Organic 12 adducts: E. L. Rimmer, R. D. Bailey, T. W. Hanks, W. T. Pennington, Chem. Eur. J. 2000, 6, 22, 4071; P. Deplanv, J. R. Ferraro, M. L. Mercuri, E. F. Trogu, Coord. Chem. Rev. 1999, 188, 71; J. Janczak, Y. M. Idemori, Inorg. Chem. 2002, 41, 5059;
25. 2 complexes: J. A. M. van Beck, G. van Koten, W. J. J. Smeets, A. L. Spek, J. Am. Chem. Soc. 1986, 108, 5010; R. A. Gossage, A. D. Ryabov, A. L. Spek, D. J. Stufkens, J. A. M. van Beck, R. V. Eldik, G. van. Koten, J. Am. Chem. Soc. 1999, 121, 2488; R. Makiura, I. Nagasawa, N. Kimura, S. Ishimaru, H. Kitagawa, K. Ikeda, J. Chem. Soc. Chem. Commun. 2001, 1642; J. A. M. van Beek, G. van Koten, G. P. C. M. Dekker, E. Wissing, M. C. Zouberg, C. H. Stam, J. Organomet. Chem. 1990, 394, 659.
26. 2 complexes: J. A. M. van Beck, G. van Koten, W. J. J. Smeets, A. L. Spek, J. Am. Chem. Soc. 1986, 108, 5010; R. A. Gossage, A. D. Ryabov, A. L. Spek, D. J. Stufkens, J. A. M. van Beck, R. V. Eldik, G. van. Koten, J. Am. Chem. Soc. 1999, 121, 2488; R. Makiura, I. Nagasawa, N. Kimura, S. Ishimaru, H. Kitagawa, K. Ikeda, J. Chem. Soc. Chem. Commun. 2001, 1642; J. A. M. van Beek, G. van Koten, G. P. C. M. Dekker, E. Wissing, M. C. Zouberg, C. H. Stam, J. Organomet. Chem. 1990, 394, 659.
27. 2 complexes: J. A. M. van Beck, G. van Koten, W. J. J. Smeets, A. L. Spek, J. Am. Chem. Soc. 1986, 108, 5010; R. A. Gossage, A. D. Ryabov, A. L. Spek, D. J. Stufkens, J. A. M. van Beck, R. V. Eldik, G. van. Koten, J. Am. Chem. Soc. 1999, 121, 2488; R. Makiura, I. Nagasawa, N. Kimura, S. Ishimaru, H. Kitagawa, K. Ikeda, J. Chem. Soc. Chem. Commun. 2001, 1642; J. A. M. van Beek, G. van Koten, G. P. C. M. Dekker, E. Wissing, M. C. Zouberg, C. H. Stam, J. Organomet. Chem. 1990, 394, 659.
28. 2 complexes: J. A. M. van Beck, G. van Koten, W. J. J. Smeets, A. L. Spek, J. Am. Chem. Soc. 1986, 108, 5010; R. A. Gossage, A. D. Ryabov, A. L. Spek, D. J. Stufkens, J. A. M. van Beck, R. V. Eldik, G. van. Koten, J. Am. Chem. Soc. 1999, 121, 2488; R. Makiura, I. Nagasawa, N. Kimura, S. Ishimaru, H. Kitagawa, K. Ikeda, J. Chem. Soc. Chem. Commun. 2001, 1642; J. A. M. van Beek, G. van Koten, G. P. C. M. Dekker, E. Wissing, M. C. Zouberg, C. H. Stam, J. Organomet. Chem. 1990, 394, 659.
29. I. L. Karle, Chem. Phys. 1955, 23, 1739.
30. F. A. Cotton, E. V. Dikarev, M. A. Petrukhina, Angew. Chem. 2000, 112, 2452; Angew. Chem. Int. Ed. 2000, 39, 2362.
31. F. A. Cotton, E. V. Dikarev, M. A. Petrukhina, Angew. Chem. 2000, 112, 2452; Angew. Chem. Int. Ed. 2000, 39, 2362.
32. 2 = 0.173,
33. 2 = 0.143.
34. 6).
35. G. M. Sheldrick, SHELX-97 Programs for Crystal Structure Analysis (Release 97-2), Institute für Anorganische Chemie, Universilöt Göttingen, 1997.
36. G. M. Sheldrick, Crystallographic Computing (Eds.: G. M. Sheldrick, C. Kruger; R. Goddard), Oxford, 1985.
37. o = 2.38 Å, See: a) I. D. Brown in Structure and Bonding in Crystals. Vol. 2 (Eds.: M. O'Keefe, A. Navrotsky), Academic Press, London, 1981;
38. - is disordered.
39. J. Passmore, G. Sutherland, P. S. White, Inorg. Chem. 1981, 20, 2169.
40. a) S. Brownridge, PhD thesis, University of New Brunswick, Canada, 2001;
41. b) S. Brownridge, J. Passmore, P. D. Boyle, unpublished results;
42. c) A. Apblett, F. Grein, J. P. Johnson, J. Passmore, P. S. White, Inorg. Chem. 1986, 25, 422.
43. a) C. G. Davies, R. J. Gillespie, P. R. Ireland, J. M. Sowa, Can. J. Chem. 1974, 52, 2048;
44. b) G. Herzberg, The Spectra of Diatomic Molecules. Van Nostrand-Reinhold, Princeton, New Jersey, 1950.
45. -0.115.[21]
46. For M = Sb, the shortest I-F contacts are also the only significant interactions between I and F. The I-F3 (3.44(1) Å) is almost at the I-F van der Waals distance (3.45 Å)(Figure 1). In the case For M = As, I-I⋯F is 169.5 or 169.4° relative to two disordered F atoms (50% occupancy each; I-F distance: 2.9678(12) and 2.9887(11) Å).
47. The designated charge -0.115 is the average net charge on the F atoms deduced by Brown's approach for M = Sb,[15] assuming that the interaction is totally ionic.
48. M. P. Murchie, R. Kapoor, J. Passmore, G. Schatte, Inorg. Synth. 1996, 31, 80.
49. H. W. Roesky, M. Witt, Inorg. Synth. 1986, 24, 72.