Total synthesis and stereochemical assignment of myriaporones 1, 3, and 4

Angewandte Chemie - International Edition

Volumn 43, Issue 13, 2004, Pages 1728-1730

  Fleming, Kristen N ^a   Taylor, Richard E ^a  

^a UNIVERSITY OF NOTRE DAME   (United States)

Author keywords

Aldol reaction; Diastereoselectivity; Epoxidation; Natural products; Total synthesis

Indexed keywords

NITRILE RESINS; OXIDATION; REACTION KINETICS; SYNTHESIS (CHEMICAL);

ALDOL REACTION; NITRILE OXIDE;

STEREOCHEMISTRY;

NITRIC OXIDE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLOADDITION; EPOXIDATION; STEREOCHEMISTRY;

ALKENES; EPOXY COMPOUNDS; MOLECULAR CONFORMATION; PYRANS; STEREOISOMERISM;

EID: 4544297587     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200353348     Document Type: Article

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24. During the review of this manuscript, we learnt of a successful total synthesis of myriaporones 1, 3, and 4 through a sequence that involves an early-stage incorporation of the epoxide. See preceding Communication in this issue: M. Pérez, C. del Pozo, F. Reyes, A. Rodríguez, A. Francesch, A. M. Echavarren, C. Cuevas, Angew. Chem. 2004, 116, 1756; Angew. Chem. Int. Ed. 2004, 43, 1724.
25. During the review of this manuscript, we learnt of a successful total synthesis of myriaporones 1, 3, and 4 through a sequence that involves an early-stage incorporation of the epoxide. See preceding Communication in this issue: M. Pérez, C. del Pozo, F. Reyes, A. Rodríguez, A. Francesch, A. M. Echavarren, C. Cuevas, Angew. Chem. 2004, 116, 1756; Angew. Chem. Int. Ed. 2004, 43, 1724.