Sb8(GaCl4)2: Isolation of a homopolyatomic antimony cation

Angewandte Chemie - International Edition

Volumn 43, Issue 19, 2004, Pages 2540-2543

  Lindsjö, Martin ^a   Fischer, Andreas ^a   Kloo, Lars ^a  

^a ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

Author keywords

Antimony; Cluster compounds; Polycations; Raman spectroscopy

Indexed keywords

BENZENE; CHEMICAL BONDS; POSITIVE IONS;

SQUARE-ANTIPRSMATIC GEOMETRY; WADE RULES;

ANTIMONY COMPOUNDS;

ANTIMONY; CATION;

ANALYTIC METHOD; ARTICLE; CHEMICAL BINDING; CHEMICAL PROCEDURES; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; ELECTRON TRANSPORT; ISOLATION PROCEDURE; MATHEMATICAL MODEL; REACTION ANALYSIS; X RAY ANALYSIS; X RAY DIFFRACTION;

EID: 4544280172     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200353578     Document Type: Article

References (38)

1. a) H. G. von Schnering, Angew. Chem. 1981, 93, 44; Angew. Chem. Int. Ed. Engl. 1981, 20, 33;
2. a) H. G. von Schnering, Angew. Chem. 1981, 93, 44; Angew. Chem. Int. Ed. Engl. 1981, 20, 33;
3. b) J. D. Corbett, Chem. Rev. 1985, 85, 383;
4. c) S. Ulvenlund, L. Bengtsson-Kloo in Metal Clusters in Chemistry, Vol. 1 (Eds.: P. Braunstein, L. A. Oro, P. R. Raithby) Wiley-VCH, Weinheim, 1999, p. 561-602.
5. a) R. J. Gillespie, J. Passmore, Adv. Inorg. Chem. Radiochem. 1975, 17, 49;
6. b) J. D. Corbett, Prog. Inorg. Chem. 1976, 21, 129;
7. c) S. Brownridge, I. Krossing, J. Passmore, H. D. B. Jenkins, H. K. Roobottom, Coord. Chem. Rev. 2000, 197, 397.
8. D. G. Adolphson, J. D. Corbett, D. J. Merryman, J. Am. Chem. Soc. 1976, 98, 7234.
9. U. Bolle, W. Tremel, J. Chem. Soc. Chem. Commun. 1992, 91.
10. a) A. Hershaft, J. D. Corbett, Inorg. Chem. 1963, 2, 979;
11. b) N. J. Bjerrum, C. R. Boston, G. P. Smith, Inorg. Chem. 1967, 6, 1162.
12. R. C. Burns, R. J. Gillespie, W.-C. Luk, Inorg. Chem. 1978, 17, 3596.
13. S. Ulvenlund, L. Bengtsson-Kloo, K. Ståhl, J. Chem. Soc. Faraday Trans. 1995, 91, 4223.
14. a) J. D. Corbett, F. C. Albers, J. Am. Chem. Soc. 1960, 82, 533;
15. b) B. L. Bruner, J. D. Corbett, J. Inorg. Nucl. Chem. 1961, 20, 62.
16. a) M. Sorlie, G. P. Smith, J. Inorg. Nucl. Chem. 1981, 43, 931;
17. b) J. D. Corbett, S. Winbush, F. C. Albers, J. Am. Chem. Soc. 1957, 79, 3020.
18. P. A. W. Dean, R. J. Gillespie, J. Chem. Soc. D 1970, 853.
19. S. Ulvenlund, K. Ståhl, L. Bengtsson-Kloo, Inorg. Chem. 1996, 35, 223.
20. S. Ulvenlund, PhD Thesis, Lund University, Sweden, 1995.
21. 2 = 0.0646; GOF = 1.088 for 4569 unique reflections and 163 parameters; Flack parameter x = 0.03(2); min./max. residual electron density 0.88/-0.84. Further details on the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany (fax: (+49)7247-808-666; e-mail: crysdata@fiz-karlsruhe.de), on quoting the depository number CSD-413 577.
22. a) K. Wade, Adv. Inorg. Chem. Radiochem. 1976, 18, 1;
23. b) A. N. Kuznetsov, L. Kloo, M. Lindsjö, J. Rosdahl, H. Stoll, Chem. Eur. J. 2001, 7, 2821.
24. a) B. Krebs, M. Mummert, C. Brendel, Angew. Chem. 1982, 94, 453; Angew. Chem. Int. Ed. Engl. 1982, 21, 445;
25. a) B. Krebs, M. Mummert, C. Brendel, Angew. Chem. 1982, 94, 453; Angew. Chem. Int. Ed. Engl. 1982, 21, 445;
26. b) J. Beck, C. J. Brendel, L. Bengtsson-Kloo, B. Krebs, M. Mummert, A. Stankowski, S. Ulvenlund, Chem. Ber. 1996, 129, 1219.
27. M. Lindsjö, A. Fischer, L. Kloo, unpublished results.
28. a) A. D. Becke, K. E. Edgecombe, J. Chem. Phys. 1990, 92, 5397;
29. b) A. Savin, R. Nesper, S. Wengert, T. F. Fässler, Angew. Chem. 1997, 109, 1892; Angew. Chem. Int. Ed. Engl 1997, 36, 1808.
30. b) A. Savin, R. Nesper, S. Wengert, T. F. Fässler, Angew. Chem. 1997, 109, 1892; Angew. Chem. Int. Ed. Engl 1997, 36, 1808.
31. J. Beck, M. Dolg, S. Schlüter, Angew. Chem. 2001, 113, 2347; Angew. Chem. Int. Ed. 2001, 40, 2287.
32. J. Beck, M. Dolg, S. Schlüter, Angew. Chem. 2001, 113, 2347; Angew. Chem. Int. Ed. 2001, 40, 2287.
33. M. J. Taylor, J. Chem. Soc. A, 1970, 2812.
34. Gaussian98 (Revision A7), M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, V. G. Zakrzewski, J. A. Montgomery, R. E. Stratmann, J. C. Burant, S. Dapprich, J. M. Millam, A. D. Daniels, K. N. Kudin, M. C. Strain, O. Farkas, J. Tomasi, V. Barone, M. Cossi, R. Cammi, B. Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G. A. Petersson, P. Y. Ayala, Q. Cui, K. Morokuma, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. Cioslowski, J. V. Ortiz, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, C. Gonzalez, M. Challacombe, P. M. W. Gill, B. G. Johnson, W. Chen, M. W. Wong, J. L. Andres, M. Head-Gordon, E. S. Replogle, J. A. Pople, Gaussian Inc., Pittsburgh, PA, 1998.
35. a) W. Küchle, M. Dolg, H. Stoll, H. Preuss, Mol. Phys. 1991, 74, 1245;
36. b) A. Bergner, M. Dolg, W. Küchle, H. Stoll, H. Preuss, Mol. Phys. 1993, 80, 1431.
37. a) S. Noury, X. Krokidis, F. Fuster, B. Silvi, ToPMoD Package, 1997;
38. b) S. Noury, X. Krokidis, F. Fuster, B. Silvi, Comput. Chem. 1999, 23, 597.