Chiral Lewis acid promoted asymmetric Michael addition reaction of 2-(trimethylsilyloxy)furans

Synlett

Volumn , Issue 5, 1997, Pages 568-570

  Kitajima, Hiroshi ^a   Katsuki, Tsutomu ^a  

^a KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002691788     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1997-3235     Document Type: Article

References (47)

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43. 3). The optical purity (>99% ee) was verified by HPLC analysis using Dicel Chiralcel OD-R.
44. -3. R = 0.034.
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47. The reaction in the absence of HFIP gave the desired Michael adduct of 92% ee in 37% yield, though anti-selectivity was slightly increased to 10.5:1.