Enantiomer-selective radical cyclopolymerization of rac-2,4-pentanediyl dimethacrylate using a ruthenium-mediated chiral atom transfer radical polymerization initiating system

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 42, Issue 18, 2004, Pages 4563-4569

  Tsuji, Masashi ^a   Aoki, Towako ^a   Sakai, Ryosuke ^a   Satoh, Toshifumi ^a   Kaga, Harumi ^b   Kakuchi, Toyoji ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

^b NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

Author keywords

Atom transfer radical polymerization (ATRP); Chiral; Cyclopolymerization; Enantiomer selective polymerization; Kinetics (polym.); Optically active polymers; Racemic monomer; Rate constant

Indexed keywords

CATALYST SELECTIVITY; COPOLYMERIZATION; FREE RADICAL POLYMERIZATION; INITIATORS (CHEMICAL); MONOMERS; RATE CONSTANTS; SYNTHESIS (CHEMICAL);

ATOM TRANSFER RADICAL POLYMERIZATION (ATRP); CHIRAL; CYCLOPOLYMERIZATION; ENANTIOMER-SELECTIVE POLYMERIZATION; KINETICS (POLYM); OPTICALLY ACTIVE POLYMERS; RACEMIC MONOMER;

STEREOCHEMISTRY;

EID: 4544262582     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/pola.20354     Document Type: Article

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