Stereospecific free radical polymerization of vinyl esters using fluoroalcohols as solvents

Macromolecules

Volumn 31, Issue 22, 1998, Pages 7598-7605

  Yamada, Kazunobu ^a,b   Nakano, Tamaki ^a   Okamoto, Yoshio ^a  

^a NAGOYA UNIVERSITY   (Japan)

^b UNITIKA LTD   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; FLUORINE COMPOUNDS; FREE RADICAL POLYMERIZATION; HYDROGEN BONDS; MOLECULAR STRUCTURE; MONOMERS; ORGANIC SOLVENTS; POLYVINYL ACETATES; STEREOCHEMISTRY;

FLUOROALCOHOLS; HETEROTACTICITY; HOMOPOLYMERS; POLYVINYL PIVALATE; STEREOREGULARITY; STEREOSPECIFICITY; SYNDIOTACTICITY;

POLYESTERS;

EID: 0032480672     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma980889s     Document Type: Article

References (43)

1. For reviews, see: (a) Finch, C. A., Ed. Polyvinyl Alcohol - Developments; Wiley: Chichester, 1992. (b) Fujii, K. J. Polym. Sci., Macromol. Rev. 1971, 5, 431. (c) PVA no Sekai (The World of PVA); Kobunshi Kankokai: Kyoto, 1992.
2. For reviews, see: (a) Finch, C. A., Ed. Polyvinyl Alcohol - Developments; Wiley: Chichester, 1992. (b) Fujii, K. J. Polym. Sci., Macromol. Rev. 1971, 5, 431. (c) PVA no Sekai (The World of PVA); Kobunshi Kankokai: Kyoto, 1992.
3. For reviews, see: (a) Finch, C. A., Ed. Polyvinyl Alcohol - Developments; Wiley: Chichester, 1992. (b) Fujii, K. J. Polym. Sci., Macromol. Rev. 1971, 5, 431. (c) PVA no Sekai (The World of PVA); Kobunshi Kankokai: Kyoto, 1992.
4. Matsuzawa, S.; Yamaura, K.; Noguchi, H.; Hayashi, H. Makromol. Chem. 1973 165, 217.
5. Matsuzawa, S.; Yamaura, K.; Noguchi, H. Makromol. Chem. 1973, 168, 27.
6. Nozakura, S.; Sumi, M.; Uoi, M.; Okamoto, T.; Murahashi, S. J. Polym. Sci., Polym. Chem. Ed. 1973, 11, 279.
7. Fukae, R.; Kawakami, K.; Yamamoto, T.; Sangen, O.; Kato, T.; Kamachi, M. Polym. J. 1995, 27, 1257.
8. Fukae, R.; Yamamoto, T.; Fujita, Y.; Kawatsuki, N.; Sangen, O.; Kamachi, M. Polym. J. 1997, 29, 293.
9. Nakano, T.; Makita, K.; Okamoto, Y. Polym. J. 1998, 30, 681.
10. Yamada, K.; Nakano, T.; Okamoto, Y. Polym. J. 1998, 30, 641.
11. Imai, K.; Shiomi, T.; Oda, N.; Otsuka, H. J. Polym. Sci., Part A 1986, 24, 3225.
12. Yamamoto, T.; Yamamoto, T.; Minamizawa, T.; Hirota, M. Kobunshi Ronbunshu 1979, 36, 557; Chem. Abstr. 1991, 158200.
13. Yamamoto, T.; Yamamoto, T.; Minamizawa, T.; Hirota, M. Kobunshi Ronbunshu 1979, 36, 557; Chem. Abstr. 1991, 158200.
14. Kador, U.; Mehnert, P. Makromol. Chem. 1971, 144, 29.
15. Schrems, O.; Oberhoffer, H. M.; Luck, W. A. P. J. Phys. Chem. 1984, 88, 4335.
16. Luck, W. A. P.; Peil, S. J. Mol. Struct. 1990, 224, 185.
17. The preliminary results of VAc polymerization have been reported (Yamada, K.; Nakano, T.; Okamoto, Y. Proc. Jpn. Acad. 1998, 74 (B), 46).
18. Zutty, N. L.; Welch, F. J. J. Polym. Sci. 1960, 43, 445.
19. 3, room temperature). (CAS registry no. 25432-06-8).
20. Kamachi, M.; Liaw, D. J.; Nozakura, S. Polym. J. 1979, 11, 921.
21. Clarke, J. T.; Howard, R. O.; Stockmayer, W. H. Makromol. Chem. 1961, 44/46, 427.
22. Filler, R.; Schure, R. M. J. Org. Chem. 1967, 32, 1217.
23. Fordham, J. W. L. J. Polym. Sci. 1959, 39, 321.
24. Hatada, K.; Sugino, H.; Ise, H.; Kitayama, T.; Okamoto, Y.; Yuki, H. Polym. J. 1980, 12, 55.
25. (a) Goodman, M.; Brandrup, J. J. Polym. Sci., Part A 1965, 3, 327.
26. (b) Brame, E. G., Jr.; Vogl, O. J. Macromol. Sci. 1967, A1, 277.
27. Nozakura, S.; Ishihara, S.; Inaba, Y.; Matsumura, K.; Murahashi, S. J. Polym. Sci., Polym. Chem. Ed. 1973, 11, 1053.
28. (a) Kitayama, T.; Zhang, Y.; Hatada, K. Polym. J. 1994, 26, 868.
29. (b) Kitayama, T.; Hirano, T.; Hatada, K. Tetrahedron 1997, 53, 15263.
30. Kobayashi, M.; Ishizone, T.; Hirao, A.; Nakahama, S.; Kobayashi, M. Polym. Prepr. Jpn. 1997, 46 (2), 183.
31. Balakrishnan, T.; Devarajan, R.; Santappa, M. J. Polym. Sci., Polym. Chem. Ed. 1984, 22, 1909.
32. Gotoh, Y.; Iihara, T.; Kanai, N.; Hirai, H. Chem. Lett. 1990, 2157.
33. (a) Wu, T. K.; Sheer, M. L. Macromolecules 1977, 10, 529.
34. (b) Ovenall, D. W. Macromolecules 1984, 17, 1458.
35. (c) Hikichi, K.; Yasuda, M. Polym. J. 1987, 19, 1003.
36. Bovey, F. A.; Mirau, P. A. NMR of Polymers; Academic Press: San Diego, CA, 1996; p 133.
37. (a) Connors, K. A. Binding Constants: The Measurement of Molecular Complex Stability; Wiley: New York, 1987; p 24-28.
38. (b) Gil, V. M. S.; Oliveira, N. C. J. Chem. Educ. 1990, 67, 473.
39. (c) Macomber, R. S. J. Chem. Educ. 1992, 69, 375.
40. The data fitting was performed using a BASIC program written by Professor M. Sawada and Dr. Y. Takai (Osaka University).
41. Yuki, H.; Hatada, K.; Niimori, T.; Kikuchi, Y. Polym. J. 1970, 1, 36.
42. Fukae, R.; Yamamoto, T.; Sangen, O.; Saso, T.; Kato, T.; Kamachi, M. Polym. J. 1990, 22, 636.
43. Lyoo, W. S.; Ha, W. S. J. Polym. Sci., Part A 1997, 35, 55.