Regioselective H/D exchange at the side-chain of ethylbenzene on dealuminated zeolite H-Y studied by in situ MAS NMR-UV/Vis spectroscopy

ChemPhysChem

Volumn 9, Issue 8, 2008, Pages 1107-1109

  Huang, Jun ^a   Jiang, Yijiao ^a   Marthala, V R Reddy ^a   Ooi, Yean Sang ^a   Hunger, Michael ^a  

^a UNIVERSITY OF STUTTGART   (Germany)

Author keywords

Ethylbenzene; H D exchange; Heterogeneous catalysis; Regioselectivity; Zeolites

Indexed keywords

CATALYSIS; REGIOSELECTIVITY; ULTRAVIOLET VISIBLE SPECTROSCOPY; ZEOLITES;

CARBENIUM ION; CHEMICAL EQUATIONS; DEALUMINATED ZEOLITE; H/D EXCHANGE; HYDRIDE ABSTRACTION; LEWIS ACID SITE; REGIO-SELECTIVE; UV/ VIS SPECTROSCOPY;

ETHYLBENZENE;

EID: 45249121253     PISSN: 14394235     EISSN: 14397641     Source Type: Journal    
DOI: 10.1002/cphc.200800065     Document Type: Article

References (22)

1. a) G. A. Olah, A. Molnar, Hydrocarbon Chemistry, Wiley, New York, 1995;
2. b) A. Corma, Chem. Rev. 1995, 95, 559-614;
3. c)W. E. Farneth, R. J. Gorte, Chem. Rev. 1995, 95, 615-635;
4. d) J. Atzrodt, V. Derdau, T. Fey, J. Zimmermann, Angew. Chem. 2007, 119, 7890-7911;
5. Angew. Chem. Int. Ed. 2007, 46, 7744-7765.
6. a) P. M. Esteves, M. A. C. Nascimento, C. J. A. Mota, J. Phys. Chem. B 1999, 103, 10417-10420;
7. b) C. Tuma, J. Sauer, Angew. Chem. 2005, 117, 4847-4849;
8. c) T. Bucko, L. Benco, J. Hafner, J. G. Ángyán, J. Catal. 2007, 250, 171-183.
9. a) M. Haouas, S. Walspurger, F. Taulelle, J. Sommer, J. Am. Chem. Soc. 2004, 126, 599-606;
10. b) S. S. Arzumanov, S. I. Reshetnikov, A. G. Stepanov, V. N. Parmon, D. Freude, J. Phys. Chem. B 2005, 109, 19748-19757;
11. c) B. Schoofs, J. Schuermans, R. A. Schoonheydt, Microporous Mesoporous Mater. 2000, 35-36, 99-111;
12. d) I. I. Ivanova, N. S. Nesterenko, C. Fernandez, Catal. Today 2006, 113, 115-125;
13. e) J. Sommer, M. Hachoumy, F. Garin, D. Barthomeuf, J. Vedrine, J. Am. Chem. Soc. 1995, 117, 1135-1136.
14. M. Hunger, W. Wang, Chem. Commun. 2004, 584-585.
15. J. H. Lunsford, P. N. Tutunjian, P.-J. Chu, E. B. Yeh, D. J. Zalewski, J. Phys. Chem. 1989, 93, 2590-2595.
16. H. Förster, I. Kiricsi, G. Tasi, I. Hannus, J. Mol. Struct. 1993, 296, 61-67.
17. J. Huang, Y. Jiang, V. R. R. Marthala, W. Wang, B. Sulikowski, M. Hunger, Microporous Mesoporous Mater. 2007, 99, 86-90.
18. G. A. Olah, Carbonium Ions, Vol. 1, Wiley-Interscience, New York, 1968, pp. 183.
19. A. Streitwieser, L. Reif, J. Am. Chem. Soc. 1960, 82, 5003-5005.
20. a) L. A. Clark, M. Sierka, J. Sauer, J. Am. Chem. Soc. 2004, 126, 936-947;
21. b) V. B. Kazansky, Catal. Today 1999, 51, 419-434.
22. U. Weiß, M. Weihe, M. Hunger, H. G. Karge, J. Weitkamp, Stud. Surf. Sci. Catal. 1997, 105, 973-980.