Energy dispersive X-ray diffraction study of phase development during hardening of calcium phosphate bone cements with addition of chitosan

Acta Biomaterialia

Volumn 4, Issue 4, 2008, Pages 1089-1094

  Rau, J V ^a   Generosi, A ^b   Smirnov, V V ^c   Ferro, D ^a   Rossi Albertini, V ^b   Barinov, S M ^c  

^a CNR   (Italy)

^b CNR   (Italy)

^c RUSSIAN ACADEMY OF SCIENCES   (Russian Federation)

Author keywords

Calcium phosphate bone cements; Chitosan; Phase transformations; X ray diffraction

Indexed keywords

BONE; BONE CEMENT; CALCIUM PHOSPHATE; HARDENING; SETTING; X RAY DIFFRACTION;

CALCIUM PHOSPHATE BONE CEMENT; CEMENT-BASED; ENERGY-DISPERSIVE X-RAY DIFFRACTION; PHASE DEVELOPMENT; PHASES TRANSFORMATION; SETTING REACTIONS; TETRACALCIUM PHOSPHATE; TRI-CALCIUM PHOSPHATES; X- RAY DIFFRACTIONS; X-RAY DIFFRACTION STUDIES;

CHITOSAN;

BONE CEMENT; CALCIUM PHOSPHATE; CHITOSAN; MAGNESIUM CARBONATE; PHOSPHORIC ACID;

ARTICLE; CHEMICAL REACTION; ENERGY; KINETICS; MOLECULAR WEIGHT; PRIORITY JOURNAL; SOLID; X RAY DIFFRACTION;

EID: 44649167802     PISSN: 17427061     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.actbio.2008.01.006     Document Type: Article

References (17)

1. LeGeros R.Z., Chohayeb A., and Shulman A. Apatitic calcium phosphates: possible dental restorative materials. J Dent Res 61 (1982) 343
2. Brown W.E., and Chow L.C. A new calcium phosphate water-setting cement. In: Brown P.W. (Ed). Cements research progress 1986 (1987), Ohio, Westerville, Berlin
3. Takagi S., Chow L.C., and Ishikawa K. Formation of hydroxyapatite in new calcium phosphate cements. Biomaterials 19 (1998) 1593-1599
4. Fernandez E., Gil F.J., Ginebra M.P., Driessens F.C.M., Planell J.A., and Best S.M. Calcium phosphate bone cements for clinical applications. J Mater Sci Mater Med 10 (1999) 169-176
5. Bohner M., Gbureck U., and Barralet J.E. Technological issues for the development of more efficient calcium phosphate bone cements: a critical assessment. Biomaterials 26 (2005) 6423-6429
6. Bohner M. Calcium orthophosphates in medicine: from ceramics to calcium phosphate cements. Injury 31 S (2000) 37-47
7. Mayazaki S., Ishii K., and Nadai T. The use of chitin and chitosan as drug carrier. Chem Pharm Bull (Tokyo) 29 (1981) 3067-3069
8. Liu C., Shen W., Gu Y., and Hu L. Mechanism of the hardening process for a hydroxyapatite cement. J Biomed Mater Res 35 (1997) 75-80
9. Generosi A., Smirnov V.V., Rau J.V., Rossi Alberini V., Ferro D., and Barinov S.M. Phase development in the hardening process of two calcium phosphate bone cements: an energy dispersive X-ray diffraction study. Mater Res Bull 43 (2008) 561-571
10. Fujishiro Y., Takahashi K., and Sato T. Preparation and compressive strength of a-tricalcium phosphate/gelatin gel composite cement. J Biomed Mater Res 54 (2001) 525-530
11. Bigi A., Bracci B., and Panzavolta S. Effect of added gelatin on the properties of calcium phosphate cement. Biomaterials 25 (2004) 2893-2899
12. Maruyama M., and Ito M. In vitro properties of a chitosan-bonded self-hardening paste with hydroxyapatite granules. J Biomed Mater Res 32 (1996) 527-532
13. Ito M., Miyazaki A., Yamagishi T., Yagasaki H., Hasem A., and Oshida Y. Experimental development of a chitosan-bonded beta tricalcium phosphate bone filling paste. Biomed Mater Eng 4 (1994) 439-449
14. Liu H., Li H., Cheng W., Yang Y., Zhu M., and Zhou C. Novel injectable calcium phosphate/chitosan composites for bone substitute materials. Acta Biomater 2 (2006) 557-565
15. Carey L.E., Xu H.H.K., Simon Jr. C.G., Takagi S., and Chow L.C. Premixed rapid-setting calcium phosphate composites for bone repair. Biomaterials 26 (2005) 5002-5014
16. Caminiti R., and Rossi Alberini V. The kinetics of phase transition observed by energy dispersive x-ray diffraction. Int Rev Phys Chem 18 (1999) 263-299
17. Paci B., Generosi A., Rossi Alberini V., Agostinelli E., Varvaro G., and Fiorani D. Structural and morphological characterization by energy dispersive X-ray diffractometry and reflectometry measurements of Cr/Pt bilayer films. Chem Mater 16 (2004) 292-298