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The ion pairs in the vapour phase of charged systems dissociate again into free ions at densities (or concentrations, in electrolyte solutions) much lower than those considered here
-
The ion pairs in the vapour phase of charged systems dissociate again into free ions at densities (or concentrations, in electrolyte solutions) much lower than those considered here.
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6], for instance, thermally decomposes above T ≈ 349°C; see: Huddleston, J.; Visser, A. E.; Reichert, W. M.; Willauer, H. D.; Broker, G. A.; Rogers, R. D. Green Chem. 2001, 3, 156-164.
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6], for instance, thermally decomposes above T ≈ 349°C; see: Huddleston, J.; Visser, A. E.; Reichert, W. M.; Willauer, H. D.; Broker, G. A.; Rogers, R. D. Green Chem. 2001, 3, 156-164.
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8444242982
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All of the ILs were prepared by alkylation of the corresponding imidazole bases with bromoalkanes followed by anion metathesis with potassium hexafluorophosphate, or lithium bis{(trifluoromethyl)sulfonyl}imide, respectively using literature methods: (a) Gordon, C. M, Holbrey, J. D, Kennedy, A, Seddon, K. R. J. Mater. Chem, 1998, 8, 2627-2636
-
All of the ILs were prepared by alkylation of the corresponding imidazole bases with bromoalkanes followed by anion metathesis with potassium hexafluorophosphate, or lithium bis{(trifluoromethyl)sulfonyl}imide, respectively using literature methods: (a) Gordon, C. M.; Holbrey, J. D.; Kennedy, A.; Seddon, K. R. J. Mater. Chem., 1998, 8, 2627-2636.
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33
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44449088913
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+ is the 1,3-dimethylimidazolium cation.
-
+ is the 1,3-dimethylimidazolium cation.
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38
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0033901932
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39
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44449152524
-
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The conductivity per ion σ/x is related to the molar conductivit by a simple transformation. The x-dependence of the two quantities is qualitatively the same.
-
The conductivity per ion σ/x is related to the molar conductivit by a simple transformation. The x-dependence of the two quantities is qualitatively the same.
-
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40
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1342344772
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44
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44449143426
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1/2) without further tuning.
-
1/2) without further tuning.
-
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45
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44449151533
-
-
The atomic charges for naphthalene, not listed in ref 29, have been determined by fitting the molecular electrostatic potential computed by Møller-Plesset perturbation theory of second order (MP2).
-
The atomic charges for naphthalene, not listed in ref 29, have been determined by fitting the molecular electrostatic potential computed by Møller-Plesset perturbation theory of second order (MP2).
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46
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44449094553
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The result might be different in IL with a long hydrocarbon tail, since in that case there is the formation of a mesophase reference. Gorden, C. Am.; Holbrey, J. D.; Kennedy, A. R.; Seddon, K. R. J. Mater. Chem. 1998, 8, 2627-2636.
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The result might be different in IL with a long hydrocarbon tail, since in that case there is the formation of a mesophase reference. Gorden, C. Am.; Holbrey, J. D.; Kennedy, A. R.; Seddon, K. R. J. Mater. Chem. 1998, 8, 2627-2636.
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50
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44449085353
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See page 451 of ref 3
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See page 451 of ref 3.
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44449138065
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44449105534
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The structures described in the text are not easy to identify in the printed Figure 5. However, they are clearly seen by visualising configurations even with simple graphic tools that allow to rotate the simulated samples. For this reason, the atomic coordinates of selected configurations at x = 0.075 and x = 0.1 are added to the Supporting Information.
-
The structures described in the text are not easy to identify in the printed Figure 5. However, they are clearly seen by visualising configurations even with simple graphic tools that allow to rotate the simulated samples. For this reason, the atomic coordinates of selected configurations at x = 0.075 and x = 0.1 are added to the Supporting Information.
-
-
-
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59
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0001672773
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See, for instance
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See, for instance: Ciccotti, G.; Jacucci, G.; McDonald, I. R. Phys. Rev. A 1976, 13, 426-436.
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Ciccotti, G.1
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60
-
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44449136950
-
-
- is 10%, see the Supporting Information.
-
- is 10%, see the Supporting Information.
-
-
-
-
61
-
-
44449167567
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-
-. See Table 2 in ref 44.
-
-. See Table 2 in ref 44.
-
-
-
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62
-
-
44449084839
-
-
2 in the k → 0 limit.
-
2 in the k → 0 limit.
-
-
-
-
63
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13444266043
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For example
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For example: Deetlefs, M.; Hardacre, C.; Nieuwenhuyzen, M.; Sheppard, O.; Soper, A. K. J. Phys. Chem. B 2005, 109, 1593-1598.
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Deetlefs, M.1
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Sheppard, O.4
Soper, A.K.5
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