Absorption or adsorption? Insights from molecular probes n-alkanes and cycloalkanes into modes of sorption by environmental solid matrices

Environmental Science and Technology

Volumn 42, Issue 11, 2008, Pages 3989-3995

  Endo, Satoshi ^a   Grathwohl, Peter ^a   Schmidt, Torsten C ^b  

^a UNIVERSITY OF TÜBINGEN   (Germany)

^b UNIVERSITY OF DUISBURG ESSEN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; ADSORBENTS; ADSORPTION; MOLECULAR STRUCTURE;

ENVIRONMENTAL SOLID MATRICES; SORPTION BEHAVIOR;

PARAFFINS;

ABSORBENT; ADSORBENT; ALKANE; CARBON; CYCLOALKANE; DIESEL FUEL; MINERAL; ORGANIC MATTER; SNOW;

ABSORPTION; ADSORBENTS; ADSORPTION; MOLECULAR STRUCTURE; PARAFFINS;

AEROSOL; ALKANE; MOLECULAR ANALYSIS; SORPTION;

ABSORPTION; ADSORPTION; AEROSOL; ARTICLE; ENVIRONMENTAL FACTOR; LINEAR ENERGY TRANSFER; MATHEMATICAL ANALYSIS; MOLECULAR PROBE; SOIL PROPERTY; SOLID STATE; SOOT; SURFACE PROPERTY;

ABSORPTION; ADSORPTION; ALKANES; CARBON; CYCLOPARAFFINS; ENVIRONMENTAL POLLUTANTS; POLYMERS; ZEOLITES;

EID: 44449171496     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es702470g     Document Type: Article

References (62)

1. Chiou, C. T.; Peters, L. J.; Freed, V. H. A physical concept of soil-water equilibriums for nonionic organic compounds. Science 1979, 206, 831-832.
2. Karickhoff, S. W.; Brown, D. S.; Scott, T. A. Sorption of hydrophobic pollutants on natural sediments. Water Res. 1979, 13, 241-248.
3. Allen-King, R. M.; Grathwohl, P.; Ball, W. P. New modeling paradigms for the sorption of hydrophobic organic chemicals to heterogeneous carbonaceous matter in soils, sediments, and rocks. Adv. Water Resour. 2002, 25, 985-1016.
4. Cornelissen, C.; Gustafsson, O.; Bucheli, T. D.; Jonker, M. T. O.; Koelmans, A. A.; van Noort, P. C. M. Extensive sorption of organic compounds to black carbon, coal, and kerogen in sediments and soils: Mechanisms and consequences for distribution, bioaccumulation, and biodegradation. Environ. Sci. Technol. 2005, 39, 6881-6895.
5. OC correlations. Environ. Sci. Technol. 1990, 24, 1687-1693.
6. Kleineidam, S.; Schueth, C.; Grathwohl, P. Solubility-normalized combined adsorption-partitioning sorption isotherms for organic pollutants. Environ. Sci. Technol. 2002, 36, 4689-4697.
7. Jeong, S.; Werth, C. J. Evaluation of methods to obtain geosorbent fractions enriched in carbonaceous materials that affect hydrophobic organic chemical sorption. Environ. Sci. Technol. 2005, 39, 3279-3288.
8. Pignatello, J. J.; Lu, Y.; LeBoeuf, E. J.; Huang, W.; Song, J.; Xing, B. Nonlinear and competitive sorption of apolar compounds in black carbon-free natural organic materials. J. Environ. Qual. 2006, 35, 1049-1059.
9. Pignatello, J. J.; Kwon, S.; Lu, Y. Effect of natural organic substances on the surface and adsorptive properties of environmental black carbon (char): Attenuation of surface activity by humic and fulvic acids. Environ. Sci. Technol. 2006, 40, 7757-7763.
10. Cornelissen, G.; Gustafsson, O. Effects of added PAHs and precipitated humic acid coatings on phenanthrene sorption to environmental black carbon. Environ. Pollut. 2006, 141, 526-531.
11. Roth, C. M.; Goss, K. U.; Schwarzenbach, R. P. Sorption of a diverse set of organic vapors to diesel soot and road tunnel aerosols. Environ. Sci. Technol. 2005, 39, 6632-6637.
12. Roth, C. M.; Goss, K. U.; Schwarzenbach, R. P. Sorption of a diverse set of organic vapors to urban aerosols. Environ. Sci. Technol. 2005, 39, 6638-6643.
13. Goss, K.-U.; Bronner, G. What is so special about the sorption behavior of highly fluorinated compounds. J. Phys. Chem. A 2006, 110, 9518-9522.
14. Denayer, J. F. M.; Ocakoglu, A. R.; Martens, J. A.; Baron, G. V. Investigation of inverse shape selectivity in alkane adsorption on SAPO-5 zeolite using the tracer chromatography technique. J. Catal 2004, 226, 240-244.
15. Denayer, J. F. M.; Ocakoglu, R. A.; Thybaut, J.; Marin, G.; Jacobs, P.; Martens, J.; Baron, G. V. n- and isoalkane adsorption mechanisms on zeolite MCM-22. J. Phys. Chem. B 2006, 110, 8551-8558.
16. Brendle, E.; Papirer, E. A new topological index for molecular probes used in inverse gas chromatography for the surface nanorugosity evaluation. 1. Method of evaluation. J. Colloid Interface Sci. 1997, 194, 207-216.
17. Smiciklas, I. D.; Milonjic, S. K.; Zee, S. An inverse gas chromatographic study of the adsorption of alkanes on hydroxyapatite. J. Mater. Sci. 2000, 35, 2825-2828.
18. Yampolskii, Y. P.; Soloviev, S. A.; Gringolts, M. L. Thermodynamics of sorption in and free volume of poly(5,6-bis(trimethylsilyl)norbornene). Polymer 2004, 45, 6945-6952.
19. Dorris, G. M.; Gray, D. G. Adsorption of n-alkanes at zero surface coverage on cellulose paper and wood fibers. J. Colloid Interface Sci. 1980, 77, 353-362.
20. Goss, K.-U. The air/surface adsorption equilibrium of organic compounds under ambient conditions. Crit. Rev. Environ. Sci. Technol. 2004, 34, 339-389.
21. Onjia, A. E.; Milonjic, S. K.; Rajakovic, L. V. Inverse gas chromatography of chromia. Part I. Zero surface coverage. J. Serb. Chem. Soc. 2001, 66, 259-271.
22. Abraham, M. H.; Chadha, H. S. Applications of a solvation equation to drug transport properties. In Lipophilicity in Drug Action and Toxicology, Pliska, V., Testa, B., van de Waterbeemd, H., Eds.; VCH Verlagsgesellschaft mbH: Weinheim, 1996; pp 311-337.
23. Goss, K.-U.; Schwarzenbach, R. P. Linear free energy relationships used to evaluate equilibrium partitioning of organic compounds. Environ. Sci. Technol. 2001, 35, 1-9.
24. Abraham, M. H.; McGowan, J. C. The use of characteristic volumes to measure cavity terms in reversed phase liquid chromatography. Chromatographia 1987, 23, 243-246.
25. Abraham, M. H.; Ibrahim, A.; Zissimos, A. M. Determination of sets of solute descriptors from chromatographic measurements. /. Chromatogr. A 2004, 1037, 29-47.
26. Abraham, M. H.; Chadha, H. S.; Whiting, G. S.; Mitchell, R. C. Hydrogen bonding. 32. An analysis of water-octanol and water-alkane partitioning and the DlogP parameter of setter. J. Pharm. Sci. 1994, 83, 1085-1100.
27. Abraham, M. H.; Ibrahim, A. Gas to olive oil partition coefficients: A linear free energy analysis. J. Chem. Inform. Model. 2006, 46, 1735-1741.
28. Diaz, E.; Ordonez, S.; Vega, A.; Coca, J. Adsorption characterisation of different volatile organic compounds over alumina, zeolites and activated carbon using inverse gas chromatography. J. Chromatogr., A 2004, 1049, 139-146.
29. Diaz, E.; Ordonez, S.; Vega, A.; Coca, J. Characterization of Co, Fe and Mn-exchanged zeolites by inverse gas chromatography. J. Chromatogr., A 2004, 1049, 161-169.
30. Denayer, J. F.; Souverijns, W.; Jacobs, P.A.; Martens, J. A.; Baron, G. V. High-temperature low-pressure adsorption of branched C5-C8 alkanes on zeolite beta, ZSM-5, ZSM-22, zeolite Y, and mordenite. J. Phys. Chem. B 1998, 102, 4588-4597.
31. 4-5. Microporous Mesoporour Mater. 1997, 11, 195-205.
32. Bilgic, C.; Askin, A. Evaluation of the thermodynamic parameters for the adsorption of some hydrocarbons on alumina and molecular sieves 3A and 5A by inverse gas chromatography. J. Chromatogr., A 2003, 1006, 281-286.
33. Moreno-Castilla, C.; Fernandez-Morales, I.; Domingo-Garcia, M.; Lopez-Garzon, F. J. Carbon molecular sieves produced by the fixation of sulfur surface complexes. Chromatographia 1985, 20, 709-712.
34. Domingo-Garcia, M.; Fernandez-Morales, I.; Lopez-Garzon, F. J.; Moreno-Castilla, C.; Prados-Ramirez, M. J. The dynamic adsorption of several hydrocarbons on active carbons. J. Colloid Interface Sci. 1990, 136, 160-167.
35. 4-5. Adsorption 1999, 5, 345-357.
36. Goss, K.-U. Comment on "Influence of soot carbon on the soil-air partitioning of polycyclic aromatic hydrocarbon. Environ. Sci. Technol. 2004, 38, 1622-1623.
37. Weckwerth, J. D.; Carr, P. W.; Vitha, M. F.; Nasehzadeh, A. A comparison of gas-hexadecane and gas-apolane partition coefficients. Anal. Chem. 1998, 70, 3712-3716.
38. Du, Q.; Hattam, P.; Munk, P. Inverse gas chromatography. 7. Polymer-solvent interactions of hydrocarbon polymers. J. Chem. Eng. Data 1990, 35, 367-371.
39. Abraham, M. H.; Platts, J. A.; Hersey, A.; Leo, A. J.; Taft, R. W. Correlation and estimation of gas-chloroform and water-chloroform partition coefficients by a linear free energy relationship method. J. Pharm. Sci. 1999, 88, 670-679.
40. Abraham, M. H.; Whiting, G. S.; Carr, P. W.; Ouyang, H. Hydrogen bonding. Part 45. The solubility of gases and vapors in methanol at 298 K: An LFER analysis. J. Chem. Soc. Perkin Trans. 2 1998, 1385-1390.
41. PhysProp, Syracuse Research Corporation. http://www.syrres.com/.
42. Arancibia, E. L.; Catoggio, J. A. Gas-chromatographic study of solution and adsorption of hydrocarbons on glycols. II. Ethylene glycol. J. Chromatogr. 1982, 238, 281-290.
43. Arancibia, E. L.; Catoggio, J. A. Gas chromatographic study of solution and adsorption of hydrocarbons on glycols. I. Diethylene glycol and triethylene glycol. J. Chromatogr. 1980, 197, 135-145.
44. Plyasunov, A. V.; Shock, E. L. Thermodynamic functions of hydration of hydrocarbons at 298.15 K and 0.1 MPa. Geochim. Cosmochim. Acta 2000, 64, 439-468.
45. Tian, M.; Munk, P. Characterization of polymer-solvent interactions and their temperature dependence using inverse gas chromatography. J. Chem. Eng. Data 1994, 39, 742-755.
46. Yampolskii, Y. P.; Kaliuzhnyi, N. E.; Durgaryan, S. G. Thermodynamics of sorption in glassy poly(vinyltrimethylsilane). Macromolecules 1986, 19, 846-850.
47. Demertzis, P. G.; Riganakos, K. A.; Akrida-Demertzi, K.; Kontominas, M. G. Gas chromatographic studies on the compatibility of PVC with a migration resistant plasticizer. Angew. Makromol. Chem. 1991, 192, 81-91.
48. Castells, R. C.; Romero, L. M.; Nardillo, A. M. Thermodynamic consideration of the retention mechanism in a poly(perfluoroalkyl ether) gas chromatographic stationary phase used in packed columns. J. Chromatogr., A 1995, 715, 299-308.
49. Hoff, J. T.; Mackay, D.; Gillham, R.; Shiu, W. Y. Partitioning of organic chemicals at the air-water interface in environmental systems. Environ. Sci. Technol. 1993, 27, 2174-2180.
50. Markovic, M. M.; Kopecni, M. M.; Milonjic, S. K.; Ceranic, T. S. Thermodynamics of adsorption of organics on a cobalt-modified solid obtained from colloidal silica. J. Chromatogr. 1989, 463, 281-295.
51. Milonjic, S. K.; Zhigunova, L. K.; Pavasovic, V. L. Adsorption of organic liquids on alkaline earth-metal modified silica. Chromatographia 1988, 26, 324-328.
52. Djordjevic, N. M.; Kopecni, M. M.; Milonjic, S. K. Chromatographic and adsorptive properties of mercury sulfide. Chromatographia 1980, 13, 226-230.
53. Onjia, A. E.; Milonjic, S. K.; Todorovic, M.; Loos-Neskovic, C.; Fedoroff, M.; Jones, D. J. An inverse gas chromatography study of the adsorption of organics on nickel- and copper-hexacyanoferrates at zero surface coverage. J. Colloid Interface Sci. 2002, 251, 10-17.
54. Lopez-Garzon, F. J.; Fernandez-Morales, I.; Domingo-Garcia, M. A gas-solid chromatographic study of the adsorption of hydrocarbons and alcohols ongraphite. Chromatographia 1987, 23, 97-101.
55. Kalashnikova, E. V.; Kiselev, A. V.; Petrova, R. S.; Shcherbakova, K. D. Gas-chromatographic investigation of the adsorption equilibrium on graphitized diermal carbon black. I. Henry constants and heats of adsorption of C1-C6 hydrocarbons at zero coverage. Chromatographia 1971, 4, 495-500.
56. Elkington, P. A.; Curthoys, G. Heats of adsorption on carbon black surfaces. J. Phys. Chem. 1969, 73, 2321-2326.
57. Fernandez-Morales, I.; Guerrero-Ruiz, A.; Lopez-Garzon, F. J.; Rodriguez-Ramos, I.; Moreno-Castilla, C. Adsorption capacity of Saran carbons at high temperatures and under dynamic conditions. Carbon 1984, 22, 301-304.
58. Lopez-Garzon, F. J.; Moreno-Castilla, C.; Guerrero-Ruiz, A.; Rodriguez-Reinoso, F.; Lopez-Gonzalez, J.d.D. High-temperature adsorption of hydrocarbons by activated carbons prepared from olive stones. Adsorpt. Sci. Technol. 1984, 1, 103-109.
59. Alentiev, A. Y.; Shantarovich, V. P.; Merkel, T. C.; Bondar, V. I.; Freeman, B. D.; Yampolskii, Y. P. Gas and vapor sorption, permeation, and diffusion in glassy amorphous Teflon AF1600. Macromolecules 2002, 35, 9513-9522.
60. Hurrass, J.; Schaumann, G. E. Is glassiness a common characteristic of soil organic matter. Environ. Sci. Technol. 2005, 39, 9534-9540.
61. Goss, K. U.; Schwarzenbach, R. P. Empirical prediction of heats of vaporization and heats of adsorption of organic compounds. Environ. Sci. Technol. 1999, 33, 3390-3393.
62. Roth, C. M.; Goss, K.-U.; Schwarzenbach, R. P. Sorption of diverse organic vapors to snow. Environ. Sci. Technol. 2004, 38, 4078-4084.