Magnetic compensation in the bimetallic oxalates

Physical Review B - Condensed Matter and Materials Physics

Volumn 77, Issue 17, 2008, Pages

  Reis, Peter ^a,b   Fishman, Randy S ^b   Reboredo, Fernando A ^b   Moreno, Juana ^a  

^a UNIVERSITY OF NORTH DAKOTA   (United States)

^b OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 44449109656     PISSN: 10980121     EISSN: 1550235X     Source Type: Journal    
DOI: 10.1103/PhysRevB.77.174433     Document Type: Article

References (18)

1. H. Tamaki, Z. J. Zhong, N. Matsumoto, S. Kida, M. Koikawa, N. Achiwa, Y. Hashimoto, and H. Õkawa, J. Am. Chem. Soc. JACSAT 0002-7863 10.1021/ja00044a004 114, 6974 (1992).
2. See, the review R. Clément, S. Decurtins, M. Gruselle, and C. Train, Monatsch. Chem. MOCMB7 0026-9247 134, 117 (2003), and references therein.
3. C. Mathonière, S. G. Carling, D. Yusheng, and P. Day, J. Chem. Soc., Chem. Commun. 1994, 1551. 0022-4936
4. C. Mathonière, C. J. Nuttall, S. G. Carling, and P. Day, Inorg. Chem. INOCAJ 0020-1669 10.1021/ic950703v 35, 1201 (1996).
5. C. J. Nuttall and P. Day, Chem. Mater. CMATEX 0897-4756 10.1021/cm980177g 10, 3050 (1998).
6. E. Coronado, J. R. Galán-Mascarós, C. J. Gómez-García, and J. M. Martinez-Agudo, Adv. Math. ADMTA4 0001-8708 10.1002/(SICI)1521-4095(199905)11:7<558::AID-ADMA558>3.0.CO;2-2 11, 558 (1999)
7. E. Coronado, J. R. Galán-Mascarós, C. J. Gómez-García, J. Ensling, and P. Gütlich, Chem.-Eur. J. CEUJED 0947-6539 10.1002/(SICI)1521-3765(20000204)6:3<552::AID-CHEM552>3. 0.CO;2-U 6, 552 (2000).
8. G. Tang, Y. He, F. Liang, S. Li, and Y. Huang, Physica B (Amsterdam) 392, 337 (2007). 0921-4526
9. R. S. Fishman and F. A. Reboredo, Phys. Rev. Lett. PRLTAO 0031-9007 10.1103/PhysRevLett.99.217203 99, 217203 (2007)
10. R. S. Fishman and F. A. Reboredo, Phys. Rev. B PRBMDO 0163-1829 10.1103/PhysRevB.77.144421 77, 144421 (2008).
11. E. Coronado, J. R. Galán-Mascarós, and C. Martí-Fastaldo, J. Mater. Chem. JMACEP 0959-9428 10.1039/b602250b 16, 2685 (2006).
12. K. S. Min, A. L. Rhinegold, and J. S. Miller, Inorg. Chem. INOCAJ 0020-1669 10.1021/ic051373+ 44, 8433 (2005).
13. J. Larionova, B. Mombelli, J. Sanchiz, and O. Kahn, Inorg. Chem. INOCAJ 0020-1669 10.1021/ic970531x 37, 679 (1998).
14. E. Coronado, J. R. Galán-Mascarós, C. J. Gómez-García, and V. Laukhin, Nature (London) NATUAS 0028-0836 10.1038/35044035 408, 447 (2000).
15. M. Clemente-León, E. Coronado, J. R. Galán-Mascarós, and C. J. Gómez-García, Chem. Commun. (Cambridge) 1997, 1727. 1359-7345
16. In most 3d and 4d bimetallic oxalates, the orbital-correlation energy is weak, so the total orbital angular momentum Lt of the electrons is not a good quantum number and Hund's second rule is not obeyed. Even if Lt is a good quantum number, however, the formalism developed in this paper can still be employed because the C3 -symmetric crystal-field potential will split the Lt =2 (3 dn, n=1, 4, 6, or 9) or Lt =3 (n=2, 3, 7, or 8) multiplets into a sequence of singlets and doublets.
17. B. Bleaney and K. W. H. Stevens, Rep. Prog. Phys. RPPHAG 0034-4885 10.1088/0034-4885/16/1/304 16, 108 (1953).
18. O. Kahn, Molecular Magnetism (VCH, New York, 1994).