Study of the conformational change of poly(N-isopropyl-acrylamide)-grafted chains in water with neutron reflection: Molecular weight dependence at high grafting density

Journal of Polymer Science, Part B: Polymer Physics

Volumn 42, Issue 17, 2004, Pages 3302-3310

  Yim, H ^a   Kent, M S ^a   Satija, S ^b   Mendez, S ^c   Balamurugan, S S ^c   Balamurugan, S ^c   Lopez, G P ^c  

^a SANDIA NATIONAL LABORATORIES   (United States)

^b NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

^c UNIVERSITY OF NEW MEXICO   (United States)

Author keywords

Conformational analysis; Grafted polymers; Neutron reflectivity; Poly (N isopropylacrylamide)

Indexed keywords

GRAFTING DENSITY; TEMPERATURE-RESPONSIVE POLYMERS;

BRUSHES; CONFORMATIONS; GOLD; GRAFTING (CHEMICAL); MOLECULAR WEIGHT; NEUTRON REFLECTION; SHRINKAGE; SURFACE TREATMENT; WATER;

GRAFT COPOLYMERS;

EID: 4444323508     PISSN: 08876266     EISSN: None     Source Type: Journal    
DOI: 10.1002/polb.20169     Document Type: Article

References (50)

1. Schild, H. G. Prog Polym Sci 1992, 17, 163.
2. Kubota, K.; Fujishige, S.; Ando, I. J Phys Chem 1990, 94, 5154.
3. Wu, C.; Zhou, S. Macromolecules 1995, 28, 8381.
4. Wang, X.; Qiu, X.; Wu, C. Macromolecules 1998, 31, 2972.
5. Lin, S.-Y.; Chen, K.-S.; Chu, L.-R. Polymer 1999, 40, 2619.
6. Katsumoto, Y.; Tanaka, T.; Sato, H.; Ozaki, Y. J Phys Chem A 2002, 106, 3429.
7. Hirotsu, S.; Yamamoto, L; Matsuo, A.; Okajim, T.; Furukawa, H.; Yamamoto, T. J Phys Soc Jpn 1995, 64, 2898.
8. Hoffman, A. S. J Controlled Release 1987, 6, 297.
9. Stayton, P. S.; Shimoboji, T.; Long, C.; Chilkoti, A.; Chen, G.; Harris, J. M.; Hoffman, A. S. Nature 1995, 378, 472.
10. Feil, H.; Bae, Y. H.; Jan, F.; Kim, S. W. J Membr Sci 1991, 64, 283.
11. Park, Y. S.; Ito, Y.; Imanishi, Y. Langmuir 1998, 14, 910.
12. Yamada, N.; Okano, T.; Sakai, H.; Karikusa, F.; Sawasaki, Y.; Sakurai, Y. Makromol Chem Rapid Commun 1990, 11, 571.
13. Okano, T.; Yamada, N.; Okuhara, M.; Sakai, H.; Sakurai, Y. Biomaterials 1995, 16, 297.
14. Kawaguchi, H.; Fujimoto, K.; Mizuhara, Y. Colloid Polym Sci 1992, 270, 53.
15. Huber, D. L.; Manginell, R. P.; Samara, M. A.; Kim, B.; Bunker, B. C. Science 2003, 301, 352.
16. Okano, T.; Kikuchi, A.; Sakurai, Y.; Takei, Y.; Ogata, N. J Controlled Release 1995, 36, 125.
17. Ista, L. K.; Perez-Luna, V. H.; Lopez, G. P. Appl Environ Microbiol 1999, 65, 2552.
18. Russell, T. P. Mater Sci Rep 1990, 5, 171.
19. Kent, M. S. Macromol Rapid Commun 2000, 21, 243.
20. Fragento-Cusani, G. J Phys: Condens Matter 2001, 13, 4973.
21. Krueger, S. Curr Opin Colloid Interface Sci 2001, 6, 111.
22. Balamurugan, S.; Mendez, S.; Balamurugan, S. S.; O'Brien, M. J., II; Lopez, G. P. Langmuir 2003, 19, 2545.
23. Kidoaki, S.; Ohya, S.; Nakayama, Y.; Matsuda, T. Langmuir 2001, 17, 2402.
24. Jones, D. M.; Smith, J. R.; Huck, W. T. S.; Alexander, C. Adv Mater 2002, 14, 1130.
25. Walldal, C.; Wall, S. Colloid Polym Sci 2000, 278, 936.
26. Zhu, P. W.; Napper, D. H. J Colloid Interface Sci 1994, 164, 489.
27. Zhu, P. W.; Napper, D. H. Colloids Surf A 1996, 113, 145.
28. Takei, Y.; Aoki, T.; Saui, K.; Ogata, N.; Sakurai, Y.; Okano, T. Macromolecules 1994, 27, 6163.
29. Schmitt, F.-J.; Park, C.; Simon, J.; Ringsdorf, H.; Israelachvili, J. Langmuir 1998, 14, 2838.
30. Yim, H.; Kent, M. S.; Huber, D. L.; Satija, S.; Majewski, J.; Smith, G. S. Macromolecules 2003, 36, 5244.
31. Yim, H.; Kent, M. S.; Mendez, S.; Balamurugan, S.; Balamurugan, S. S.; Lopez, G. P.; Satija, S. Macromolecules 2004, 37, 1994.
32. 2. Under the assumption that the surface density was constant for all polymerizations with 90% OH termination, this value combined with the dry film thickness data yields the M values given in the text.
33. Kubota, K.; Fujishige, S.; Ando, I. Polym J 1990, 22, 15.
34. Satija, S. K.; Majkrzak, C. F.; Russell, T. P.; Sinha, S. K.; Sirota, E. B.; Hughes, G. J. Macromolecules 1990, 23, 3860. The liquid cell used in these experiments was a modification of this original design that allowed the use of circular 4-in. silicon wafers.
35. Styrkas, D.; Doran, S. J.; Gilchrist, V.; Keddie, J. L.; Lu, J. R.; Murphy, E.; Sackin, R.; Su, T.-J.; Tzitzinou, A. In Polymer Surfaces and Interfaces III; Richards, R. W.; Peace, S. K., Eds.; Wiley: New York, 1999.
36. The fact that the limiting scaling behavior of brushes is approached at ∑ ∼ 20 has been shown in numerical SCF calculations by Mark Whitmore and his colleagues (Memorial University of New-foundland) in a private communication.
37. Auroy, P.; Auvray, L.; Leger, L. Phys Rev Lett 1991, 66, 721.
38. g values for M = 71,000 g/mol. However, if the data in Figure 15 of ref. 50 for the layer height of tethered PS chains (M = 60,000 g/mol) in a good solvent, which cover ∑ = 1-20, are scaled to M = 71,000 g/mol and extrapolated to ∑ = 78, we obtain a value of 590 Å for the first moment, which is much greater than our observed value for PNIPAM in water at 20 °C of 270 Å.
39. Baulin V. A.; Halperin, A. Macromol Theory Simul 2003, 12, 549.
40. Baulin, V. A.; Zhulina, E. B.; Halperin, A. J Chem Phys 2003, 119, 10977.
41. Matsuyama, A.; Tanaka, F. Phys Rev Lett 1990, 65, 341.
42. Bekiranov, S.; Bruinsma, R.; Pincus, P. Phys Rev E 1997, 55, 577.
43. Dormidontova, E. Macromolecules 2002, 35, 987.
44. Karlstrom, G. J Phys Chem 1985, 89, 4962.
45. de Gennes, P.-G. C R Acad Sci Paris II 1991, 117, 313.
46. Afroze, F.; Nies, E.; Berghmans, H. J Mol Struct 2000, 554, 55.
47. Szleifier, I.; Carignano, M. A. Adv Chem Phys 1996, 94, 165.
48. Hugo, Y.; Ueno, N.; Noda, I. Polym J 1983, 15, 367.
49. Mendez, S.; Curro, J. G.; McCoy, J. D. Private communication, 2004.
50. Kent, M. S.; Lee, L. T.; Factor, B. J.; Rondelez, F.; Smith, G. S. J Chem Phys 1995, 103, 2330.