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Encyclopedia of Polymer Science and Engineering
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F. E. Bailey and J. V. Koleske, Poly(ethylene oxide) (Academic, New York, 1976).
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10
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85037206381
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(Formula presented) is the polymer radius of gyration and N the number of monomer units on the chain
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(Formula presented) is the polymer radius of gyration and N the number of monomer units on the chain.
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13
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0016984999
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S. Saeki, N. Kuwahara, M. Nakata and M. Kaneko, Polymer 17, 685 (1976).
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Saeki, S.1
Kuwahara, N.2
Nakata, M.3
Kaneko, M.4
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14
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0027539998
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Y. C. Bae, J. J. Shim, D. S. Soane and J. M. Prausnitz, J. Appl. Polym. Sci. 47, 1193 (1993).
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Bae, Y.C.1
Shim, J.J.2
Soane, D.S.3
Prausnitz, J.M.4
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17
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0026866809
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R. L. Cook, H. E. King, Jr., and D. G. Peiffer, Macromolecules 25, 2928 (1992).
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Macromolecules
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Cook, R.L.1
King, H.E.2
Peiffer, D.G.3
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0001265713
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R. L. Cook, H. E. King, Jr., and D. G. Peiffer, Phys. Rev. Lett. 69, 3072 (1992).
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Cook, R.L.1
King, H.E.2
Peiffer, D.G.3
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21
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85037213925
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They do not, however, address the issue of the closed loops shrinking to a point
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They do not, however, address the issue of the closed loops shrinking to a point.
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-
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24
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85037250870
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(private communication)
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J. C. Selser (private communication).
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Selser, J.C.1
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Poole, P.P.1
Sciortino, F.2
Grande, T.3
Stanley, H.E.4
Angell, C.A.5
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28
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85037235209
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We show in Sec. IV that application of pressure reduces the effective number of bonding sites f/N<1; thus, we will express all derived quantities explicitly in terms of f/N
-
We show in Sec. IV that application of pressure reduces the effective number of bonding sites f/N<1; thus, we will express all derived quantities explicitly in terms of f/N.
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29
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0003879578
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Addison-Wesley, Reading, MA
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S. A. Safran, Statistical Thermodynamics of Surfaces, Interfaces, and Membranes (Addison-Wesley, Reading, MA, 1994).
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Safran, S.A.1
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32
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85037231484
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The second virial coefficient v shown in Eq. (17) is identical to that found by MT 1, indicating that fluctuations in m/N do not contribute to the free energy at the second virial level
-
The second virial coefficient v shown in Eq. (17) is identical to that found by MT 1, indicating that fluctuations in m/N do not contribute to the free energy at the second virial level.
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33
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33947300434
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on PEO in water suggest that the fraction of 'intact bonds' does not change significantly upon increasing temperature from 30t°C to 80t°C. Rather than 'break,' the H bond may bend, which would distort the local water network. In our theory, a bond is either completely formed or 'broken'; thus our theory would predict the number of broken bonds to be greater than the actual PEO in water system, which, in principle, exhibits bond bending
-
NMR experiments of K.-J. Liu and J. L. Parsons, Macromolecules 2, 529 (1969), on PEO in water suggest that the fraction of 'intact bonds' does not change significantly upon increasing temperature from 30t°C to 80t°C. Rather than 'break,' the H bond may bend, which would distort the local water network. In our theory, a bond is either completely formed or 'broken'; thus our theory would predict the number of broken bonds to be greater than the actual PEO in water system, which, in principle, exhibits bond bending.
-
(1969)
Macromolecules
, vol.2
, pp. 529
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Parsons, J.L.1
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36
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85037196337
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MT 1, Bae et al. 14, and the present authors compared our calculated binodals to the cloud points, which were assumed to be a measurement of the coexistence curve rather than the spinodal. This is not obvious and requires further investigation
-
MT 1, Bae et al. 14, and the present authors compared our calculated binodals to the cloud points, which were assumed to be a measurement of the coexistence curve rather than the spinodal. This is not obvious and requires further investigation.
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