Synthesis of a biocompatible polymer using siloxane-based surfactants in supercritical carbon dioxide

Journal of Supercritical Fluids

Volumn 45, Issue 3, 2008, Pages 391-399

  Kwon, Soyoung ^a   Lee, Kyoungwon ^a   Bae, Won ^b   Kim, Hwayong ^a  

^a Seoul National University   (South Korea)

^b Miwon Co Ltd   (South Korea)

Author keywords

Dispersion polymerization; N vinyl 2 pyrrolidone; Poly(N vinyl 2 pyrrolidone); Supercritical carbon dioxide; Surfactant

Indexed keywords

CARBON DIOXIDE; MONOMERS; POLYMERIZATION; SURFACE ACTIVE AGENTS;

AZOBISISOBUTYRONITRILE; SILOXANE-BASED SURFACTANTS; SUPERCRITICAL CARBON DIOXIDE;

BIOPOLYMERS;

EID: 44149115970     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.supflu.2008.01.021     Document Type: Article

References (22)

1. Horák D., Kryśtůfek M., and Spěváček J. Effect of reaction parameters on the dispersion polymerization of 1-vinyl-2-pyrrolidone. J. Polym. Sci. Part A Polym. Chem. 38 (2000) 653-663
2. Galia A., Giaconia A., Iaia V., and Filardo G. Synthesis of hydrophilic polymers in supercritical carbon dioxide in the presence of a siloxane-based macromonomer surfactant: heterogeneous polymerization of 1-vinyl-2-pyrrolidone. J. Polym. Sci. Part A Polym. Chem. 42 (2004) 173-185
3. Berger T., McGhee B., Scherf U., and Steffen W. Polymerization of vinylpyrrolidone in supercritical carbon dioxide with a diblock copolymer stabilizer. Macromolecules 33 (2000) 3505-3507
4. 2 in green chemical synthesis and processing. J. Supercrit. Fluids 28 (2004) 121-191
5. Ajzengerg N., Trabelsi F., and Recasens F. What's new in industrial polymerization with supercritical solvents? A short review. Chem. Eng. Technol. 23 (2000) 829-839
6. Cooper A.I. Polymer synthesis and processing using supercritical carbon dioxide. J. Mater. Chem. 10 (2000) 207-234
7. Kendall J.L., Canelas D.A., Young J.L., and Desimone J.M. Polymerization in supercritical carbon dioxide. Chem. Rev. 99 (1999) 543-564
8. http://www.silicone.jp/e/ (Accessed 10 March. 2007).
9. Carson T., Lizotte J., and Desimone J.M. Dispersion polymerization of 1-vinyl-2-pyrrolidone in supercritical carbon dioxide. Macromolecules 33 (2000) 1917-1920
10. Bae W., Kwon S., Byun H., and Kim H. Phase behavior of the poly(vinyl pyrrolidone) + N-vinyl-2-pyrrolidone + carbon dioxide system. J. Supercrit. Fluids 30 (2004) 127-137
11. 2 + N-methyl caprolactam systems. J. Chem. Eng. Data 50 (2005) 1560-1563
12. McHugh M.A., and Krukonis V.J. Supercritical Fluid Extraction-Principles and Practice. second ed. (1994), Butterworth-Heinemann, Boston
13. Hsiao Y., Maury E.E., Desimone J.M., Mawson S., and Johnston K.P. Dispersion polymerization of methyl methacrylate stabilized with poly(1,l-dihydroperfluorooctyl acrylate) in supercritical carbon dioxide. Macromolecules 28 (1995) 8159-8166
14. 2-philic poly(ethylene oxide)-b-poly(1,1,2,2-tetrahydroperfluorodecyl acrylate) (PEO-b-PFDA) diblock copolymer in supercritical carbon dioxide. Polymer 45 (2004) 6789-6797
15. Barrett K.E.J. Dispersion Polymerization in Organic Media (1975), Wiley Interscience
16. Kiran E., DeBenedetti P.G., and Peters C.J. Supercritical Fluids. Fundamental and Applications (2000), Kluwer Academic Publication, London
17. Odian G. Principles of polymerization. third ed. (1991), Wiley Interscience
18. 2 with a siloxane-based macromonomer: 1. The particle growth regime. Macromolecules 31 (1998) 2838-2856
19. 2 on the glass transition temperature and mechanical properties of polystyrene. J. Poly. Sci. Poly. Phys. Ed. 20 (1982) 1371-1384
20. Horák D., Kryśtůfek M., and Spěváček J. Effect of reaction parameters on the particle size in the dispersion polymerization of 2-hydroxyethyl methacrylate. J. Polym. Sci. Part A Polym. Chem. 37 (1999) 3785-3792
21. Yates M.Z., Shah P.S., Johnston K.P., Lim K.T., and Webber S. Steric stabilization of colloids by poly(dimethylsiloxane) in carbon dioxide: effect of cosolvents. J. Colloid Interface Sci. 227 (2000) 176-184
22. ®: Polyvinylpyrrolidone for the Pharmaceutical Industry (1992), BASF Aktiengesellschaft, Germany