Study of the catalyst deactivation in an industrial gasoil HDS reactor using a mini-scale laboratory reactor

Fuel

Volumn 87, Issue 12, 2008, Pages 2444-2449

  Kallinikos, L E ^a   Bellos, G D ^a   Papayannakos, N G ^a  

^a NATIONAL TECHNICAL UNIVERSITY OF ATHENS   (Greece)

Author keywords

Catalyst deactivation; HDS reactions; Mini scale reactors; Multiphase systems; Reactor model

Indexed keywords

CATALYST ACTIVITY; CATALYST DEACTIVATION; HYDRODESULFURIZATION; HYDROGEN; REACTION KINETICS;

INDUSTRIAL REACTORS; MINI SCALE REACTORS; MINI-SCALE HYDROTREATER; MULTIPHASE SYSTEMS; REACTOR MODEL;

CHEMICAL REACTORS;

EID: 43849099714     PISSN: 00162361     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuel.2008.03.007     Document Type: Article

References (21)

1. Directive of the European Parliament and of the Council, Brussels COM(2001) 241final; 11.05.2001.
2. Tanaka Y., Shimada H., Matsubayashi N., Nishijima A., and Nomura M. Accelerated deactivation of hydrotreating catalysts: comparison to long-term deactivation in a commercial plant. Catal Today 45 (1998) 319
3. Sie S.T. Consequences of catalysis deactivation for process design and operation. Appl Catal A: Gen 212 (2001) 129
4. Callejas M.A., Martinez M.T., Fierro J.L.G., Rial C., Jimenez-Mateos J.M., and Gomez-Garcia F.J. Structural and morphological study of metal deposition on an aged hydrotreating catalyst. Appl Catal A: Gen 220 (2001) 93
5. Furimsky E., and Massoth F.E. Deactivation of hydroprocessing catalysts. Catal Today 52 (1999) 381
6. Thakur D.S., and Thomas M.G. Catalyst deactivation in heavy petroleum and synthetic crude processing: a review. Appl Catal 15 (1985) 197
7. Seki H., and Yoshimoto M. Deactivation of HDS catalyst in two-stage RDS process II. Effect of crude oil and deactivation mechanism. Fuel Process Technol 69 (2001) 229
8. 3 hydrodesulfurization catalysts during a one-year commercial run. Catal Today 29 (1996) 261
9. Murti S.D.S., Choi K., Korai Y., and Mochida I. Performance of spent sulfide catalysts in hydrodesulfurization of straight run and nitrogen-removed gas oils. Appl Catal A: Gen 280 2 (2005) 133
10. Pazos J.M., Gonzalez J.C., and Salazar-Guillen A.J. Effect of catalyst properties and operating conditions on hydroprocessing of high-metals feeds. Ind Eng Chem Proc Des Dev 22 4 (1983) 653
11. Bej S.K., Dabral R.P., Gupta P.C., Mittal K.K., Sen G.S., Kapoor V.K., et al. Studies on the performance of a microscale trickle bed reactor using different sizes of diluent. Energy Fuel 14 3 (2000) 701
12. Bellos G.D., and Papayannakos N.G. The use of a three phase microreactor to investigate HDS kinetics. Catal Today 79-80 (2003) 349
13. 3 catalysts containing boron and phosphorus: part II. Hydrodenitrogenation and hydrodesulfurization using heavy gas oil derived from Athabasca bitumen. Appl Catal A: Gen 260 (2004) 153
14. Sie S.T., and Krishna R. Process development and scale up: III. Scale-up and scale-down of trickle bed processes. Rev Chem Eng 14 3 (1998) 203
15. Klinken J., and Dongen R.H. Catalyst dilution for improved performance of laboratory trickle - flow reactors. Chem Eng Sci 35 (1980) 59
16. Bellos G.D., Kallinikos L.E., Gounaris C.E., and Papayannakos N.G. Modelling of the performance of industrial HDS reactors using a hybrid neural network approach. Chem Eng Process 44 (2005) 505
17. Papayannakos N., and Georgiou G. Kinetics of hydrogen consumption during catalytic hydrodesulphurization of a residue in a trickle bed reactor. J Chem Eng Jpn 21 3 (1988) 244
18. Froment G.F., Depauw G.A., and Vanrysselberghe V. Kinetic modelling and reactor simulation in hydrodesulfurization of oil fractions. Ind Eng Chem Res 33 12 (1994) 2975
19. Tsamatsoulis D., and Papayannakos N. Investigation of intrinsic hydrodesulphurization kinetics of a VGO in a trickle bed reactor with backmixing effects. Chem Eng Sci 53 (1998) 3449
20. Ho T.C., and Aris R. On apparent second-order kinetics. AIChE J 33 6 (1987) 1050
21. Babich I.V., and Moulijn J.A. Science and technology of novel processes for deep desulfurization of oil refinery streams: a review. Fuel 82 (2003) 607