Complete and partial epoxidation of plant oils by lipase-catalyzed perhydrolysis

Industrial Crops and Products

Volumn 9, Issue 2, 1999, Pages 125-132

  Rusch Gen Klaas M ^a   Warwel, S ^a  

^a Fed Ctr C   (Germany)

Author keywords

Epoxidation; Hydrogen peroxide; Lipase; Perhydrolysis; Plant oils

Indexed keywords

EID: 0039354072     PISSN: 09266690     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0926-6690(98)00023-5     Document Type: Article

References (15)

1. Baumann H., Bühler M., Fochem H., Hirsinger F., Zoebelein H., Falbe J. Natürliche Fette und Öle - nachwachsende Rohstoffe für die chemische Industrie. Angew. Chem. 100:1988;42-88.
2. Björkling F., Godtfredsen S.E., Kirk O. Lipase-mediated formation of peroxycarboxylic acids used in catalytic epoxidation of alkenes. J. Chem. Soc. Chem. Commun. 1990:1990;1301-1303.
3. Björkling F., Frykman H., Godtfredsen S.E., Kirk O. Lipase catalyzed synthesis of peroxycarboxylic acids and lipase mediated oxidations. Tetrahedron. 48:1992;4587-4592.
4. Carlson, K.D., Schneider, W.J., Chang, S.D., Princen, L.H., 1981. Vernonia galamensis seed oil - a new source for epoxy coatings. In: Pryde, E.H., Princen, L.H., Mukherjee, K.D. (Eds.), New Sources of Fats and Oils. AOCS, Champaign, pp. 297-318.
5. Eierdanz, H., 1993. Industrielle fettchemie - rohstoffe, verfahren, produkte. In: Eggersdorfer, M., Warwel, S., Wulff, G., (Eds.), Nachwachsende Rohstoffe - Perspektiven für die Chemie. VCH, Weinheim, pp. 23-32.
6. Formo, M.W., 1982. Miscellaneous oil and fat products. In: Swern, D. (Ed.), Bailey's Industrial Oil and Fat Products, 4th ed. Wiley, New York, pp. 366-371.
7. Kirk O., Christensen M.W., Damhus T., Godtfredsen S.E. Enzyme catalyzed degradation and formation of peroxycarboxylic acids. Biocatalysis. 11:1994;65-77.
8. Kuo M.-C., Chou T.-C. Kinetics and mechanism of the catalyzed epoxidation of oleic acid with oxygen in the presence of benzaldehyde. Ind. Eng. Chem. Res. 26:1987;277-284.
9. Martinez de la Cuesta P.J., Rus Martinez E., Cotoruelo Minguez L.M. Epoxidation de aceite de soja refinado mediante hidroperoxido de isopropilbenceno. Grasas y Aceites. 36:1985;181-185.
10. Rangarajan B., Havey A., Grulke E.A., Culnan P.D. Kinetic Parameters of a two-phase model for in situ epoxidation of soybean oil. J. Am. Oil Chem. Soc. 72:1995;1161-1169.
11. Rüsch gen Klaas M., Warwel S. Chemo-enzymatic epoxidation of unsaturated fatty acids esters and plant oils. J. Am. Oil Chem. Soc. 73:1996;1453-1457.
12. Rüsch gen. Klaas M., Warwel S. Lipase-Catalyzed Preparation of Peroxy Acids and their Use for Epoxidation. J. Mol. Catal. A. 117:1997;311-319.
13. Sonnet P.E., Lankin M.E., McNeill G.P. Reactions of dioxiranes with selected oleochemicals. J. Am. Oil. Chem. Soc. 72:1995;199-204.
14. Ucciani, E., Debal, A., Rafaralahitsimba, G., 1993. Epoxidation of Fatty Acid Methyl Esters with Hydroperoxide and Molybdenum Oxide. Fat Sci. Technol. 95, 236-239.
15. Warwel S., Rüsch gen. Klaas M. Chemo-enzymatic epoxidation of unsaturated carboxylic acids. J. Mol. Catal. B. 1:1995;29-35.