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4344705424
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Cleaner reactions were seen when a large excess of DMAD was employed. The large excess favors reaction of 3b with DMAD as a dienophila over reaction of 3b with the product 4b acting as a dienophile.
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23
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4344595034
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note
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17O NMR spectrum, integrations are estimated to be accurate to within ∼10%.
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40
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4344595035
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note
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3a-c are the first spectrally characterized isobenzofuryl carbene complexes.
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