Structure correlation in bispidine coordination compounds - Isomerism and tuneable reactivity

Crystal Engineering

Volumn 6, Issue 4 SPEC. ISS., 2003, Pages 197-211

  Comba, Peter ^a   Kerscher, Marion ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

Bispidine; Bond stretch; Isomerism; Rigid; Structure correlation

Indexed keywords

CATALYSTS; COORDINATION REACTIONS; COPPER; CRYSTAL ORIENTATION; ELECTRONIC STRUCTURE; IONS; IRON; ISOMERS; PARAMETER ESTIMATION; POTENTIAL ENERGY; STABILITY;

BISPIDINE; BOND STRETCH; ISOMERISM; RIGID; STRUCTURE CORRELATION;

AROMATIC COMPOUNDS;

EID: 4344692396     PISSN: 14630184     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cryseng.2004.04.002     Document Type: Article

References (55)

1. Y. Miyahara, K. Goto, T. Inazu, Chemistry Letters (2000) 620.
2. Miyahara Y., Goto K., Inazu T. Tetrahedron Lett. 42:2001;3097.
3. Comba P., Pritzkow H., Schiek W. Angew. Chem. 113:2001;2556 Comba P., Pritzkow H., Schiek W. Angew. Chem. Int. Ed. 40:2001;2465.
4. Comba P., Pritzkow H., Schiek W. Angew. Chem. 113:2001;2556 Comba P., Pritzkow H., Schiek W. Angew. Chem. Int. Ed. 40:2001;2465.
5. G.D. Hosken, R.D. Hancock, J. Chem. Soc., Chem. Commun. (1994) 1363.
6. G.D. Hosken, C.C. Allan, J.C.A. Boeyens, R.D. Hancock, J. Chem. Soc., Dalton Trans. (1995) 3705.
7. Cheklov A.N. Zh. Strukt. Khim. 41:2000;359.
8. Börzel H., Comba P., Hagen K.S., Katsichtis C., Pritzkow H. Chem. Eur. J. 6:2000;914.
9. Börzel H., Comba P., Hagen K.S., Merz M., Lampeka Y.D., Lienke A., Linti G., Pritzkow H., Tsymbal L.V. Inorg. Chim. Acta. 337:2002;407.
10. P. Comba, M. Merz, H. Pritzkow, Eur. J. Inorg. Chem. (2003) 1711.
11. M. Bukowski, P. Comba, C. Limberg, M. Merz, L. Que Jr., T. Wistuba, Angew. Chem. 116 (2004) 1303.
12. These generally have a ketone at C9 (upon complexation this often is hydrolyzed to a diol), ester groups at C1,5 and methyl substituents at N3,7 (if the amines are not donor-substituted or linked); these substituents are often omitted for clarity in the structural plots in this publication.
13. Comba P., Schiek W. Coord. Chem. Rev. 238-239:2003;21.
14. P. Comba, S. Kuwata, G.A. Lawrance, in preparation.
15. C. Bleiholder, H. Börzel, P. Comba, A. Heydt, M. Kerscher, S. Kuwata, G. Laurenczy, G.A. Lawrance, A. Lienke, B. Martin, M. Merz, B. Nuber, H. Pritzkow, in preparation.
16. Comba P., Lienke A. Inorg. Chem. 40:2001;5206.
17. P. Comba, M. Kerscher, A. Roodt, submitted.
18. Börzel H., Comba P., Katsichtis C., Kiefer W., Lienke A., Nagel V., Pritzkow H. Chem. Eur. J. 5:1999;1716.
19. Börzel H., Comba P., Hagen K.S., Kerscher M., Pritzkow H., Schatz M., Schindler S., Walter O. Inorg. Chem. 41:2002;5440.
20. H. Börzel, P. Comba, H. Pritzkow, J. Chem. Soc., Chem. Commun. (2001) 97.
21. Comba P., Kerscher M., Merz M., Müller V., Pritzkow H., Remenyi R., Schiek W., Xiong Y. Chem. Eur. J. 8:2002;5750.
22. 3)}-fragment, these structures are - at least with a constant metal ion - isomeric, and bond-stretch or distortional isomers [20,22-24].
23. Stohrer W.-D., Hoffmann R. J. Am. Chem. Soc. 74:1972;779.
24. Parkin G. Chem. Rev. 93:1993;887.
25. Rohmer M.M., Bénard M. Chem. Soc. Rev. 30:2001;340.
26. Comba P., Hambley T.W., Okon N., Lauer G. MOMEC97, A Molecular Modeling Package for Inorganic Compounds, Heidelberg:1997.
27. Bol J.E., Buning C., Comba P., Reedijk J., Ströhle M. J. Comput. Chem. 19:1998;512.
28. Comba P., Okon N., Remenyi R. J. Comput. Chem. 20:1999;781.
29. P. Comba, B. Nuber, A. Ramlow, J. Chem. Soc., Dalton Trans. (1997) 347.
30. P. Comba, S. Kuwata, H. Pritzkow, unpublished data.
31. Ambundo E.A., Deydier M.-V., Grall A.J., Agnera-Vega N., Dressel L.T., Cooper T.H., Heeg N.J., Ochrymowycz L.A., Rorabacher D.B. Inorg. Chem. 38:1999;4233.
32. Evans D.A., Faul M.M., Bilodean M.T. J. Org. Chem. 56:1991;6744.
33. Evans D.A., Faul M.M., Bilodean M.T. J. Am. Chem. Soc. 116:1994;2742.
34. Halfen J.A., Hallman J.K., Schultz J.A., Emerson J.P. Organometallics. 18:1999;5435.
35. Halfen J.A., Fox D.C., Mehn M.P., Que L. Inorg. Chem. 40:2001;5060.
36. Brandt P., Södergren M.J., Andersson P.G., Norrby P.-O. J. Am. Chem. Soc. 122:2000;8013.
37. P. Comba, H. Rohwer, unpublished data.
38. P. Comba, M. Kerscher, H. Pritzkow, unpublished data.
39. Kim C., Chen K., Kim J., Que L. Jr. J. Am. Chem. Soc. 119:1997;5964.
40. K. Chen, M. Costas, L. Que Jr., J. Chem. Soc., Dalton Trans. (2002) 672.
41. Roelfes G., Lubben M., Hage R., Que J., Feringa L.B.L. Chem. Eur. J. 6:2000;2152.
42. M. Bukowski, P. Comba, C. Lopez de Laorden, M. Merz, L. Que Jr., in preparation.
43. Jahn H.A., Teller E. Proc. Roy. Soc. A. 116:1937;220.
44. Figgis B.N., Hitchman M.A. Ligand Field Theory and its Applications. 2000;Wiely-VCH, Weinheim, New York.
45. Hitchman M.A., Yablokov Y.V., Petrashen V.E., Augustyniak-Jablokov M.A., Stratemeier H., Riley M.J., Lukaszewicz K., Tomaszewski P.E., Pietraszko A. Inorg. Chem. 41:2002;229.
46. Bersuker I.B. Chem. Rev. 101:2001;1067.
47. T. Astley, P.J. Ellis, H.C. Freeman, M.A. Hitchman, F.R. Keene, E.R.T. Tiekink, J. Chem. Soc., Dalton Trans. (1995) 595.
48. Simmons C.J., Hitchman M.A., Stratemeier H., Schultz A.J. J. Am. Chem. Soc. 115:1993;11304.
49. Comba P., Hauser A., Kerscher M., Pritzkow H. Angew. Chem. 115:2003;4675 Comba P., Hauser A., Kerscher M., Pritzkow H. Angew. Chem. Int. Ed. 42:2003;4536.
50. Comba P., Hauser A., Kerscher M., Pritzkow H. Angew. Chem. 115:2003;4675 Comba P., Hauser A., Kerscher M., Pritzkow H. Angew. Chem. Int. Ed. 42:2003;4536.
51. P. Comba, B. Martin, A. Prikhod'ko, H. Pritzkow, H. Rohwer, submitted.
52. Bernhardt P.V., Comba P., Hambley T.W., Massoud S.S., Stebler S. Inorg. Chem. 31:1992;2644.
53. Comba P. Coord. Chem. Rev. 123:1993;1.
54. Comba P. Coord. Chem. Rev. 200-202:2000;217.
55. Irving H., Williams R.J.P. Nature. 162:1948;746.