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28
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43149114577
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Crystal data for 1: C23H42CoN 12OP3S3, MW, 750.74 red needles, 0.22 x 0.06 x 0.01 mm, Cu Kα radiation, γ, 1.541 80 Å, monoclinic, space group P21, a, 9.703(7) Å, b, 15.243(12) Å, c, 10.459(8) Å, β, 92.80(6)°, V, 1545(2) Å3, Z, 2, ρcalcd, 1.614 g cm -3, μ(Cu Kα, 8.08 mm-1, T, 100(2) K, no. of collected reflns, 11 947, no. of unique reflns, 5434, no. of reflections with I > 2σ(I, 3016 (Rint, 0.0951, Flack parameter, 0.013 5, R1, 0.0509, wR2, 0.0630. Crystal data for 2: C14H28CoN8O 4P2S2, MW, 278.72, pink-orange needles, 0.38 x 0.08 x 0.08 mm, Mo Kα radiation, λ, 0.710 73 Å, monoclinic, space group P21/cc, a
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int = 0.043), R1 = 0.0498, wR2 = 0.1242.
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32
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33845551572
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