The physical chemistry of organic coatings revisited-viewing coatings as a materials scientist

Journal of Coatings Technology and Research

Volumn 5, Issue 2, 2008, Pages 133-155

  Bierwagen, Gordon ^a  

^a NORTH DAKOTA STATE UNIVERSITY   (United States)

Author keywords

Chromate replacement; Corrosion protection; CPVC; Electrochemistry; Materials science; Physical chemistry; Room temperature ionic liquids

Indexed keywords

CONCENTRATION (PROCESS); CORROSION PROTECTION; ELECTROCHEMISTRY; IONIC LIQUIDS; MATERIALS SCIENCE; PIGMENTS;

CHROMATE REPLACEMENT; PIGMENT VOLUME CONCENTRATIONS (PVC); PIGMENTED ORGANIC COATINGS; ROOM TEMPERATURE IONIC LIQUIDS;

ORGANIC COATINGS;

EID: 42449156663     PISSN: 15470091     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11998-007-9066-4     Document Type: Article

References (135)

1. Stokes, RJ, Fennel Evans, D, Fundamentals of Interfacial Engineering. Wiley-VCH, New York (1997)
2. R Doherty (2007) Retrospective on R. W. Cahn and D. Turnbull. Science 317:56
3. Torquato, S, Random Heterogeneous Materials, Ch. 1. Springer, New York (2001)
4. Asbeck, WK, Van Loo, M, "Critical Pigment Volume Relationships," Ind. Eng. Chem., 41 1470-1475 (1949)
5. GP Bierwagen (1972) CPVC (Critical Pigment Volume Concentration) Calculations J. Paint Tech. 44(574): 46-55
6. Bierwagen GP, Hay TK (1975) The Reduced Pigment Volume Concentration as an Important Parameter in Interpreting & Predicting the Properties of Organic Coatings. Prog. Org. Coat. 3: 281-303
7. Bierwagen GP, Saunders TE (1974) Studies of the Effects of Particle Size Distribution on the Packing Efficiency of Particles. Powder Tech. 10: 111-119
8. Bierwagen GP, Mallinger RG (1982) Comparison of Prediction and Experiment for the Critical Pigment Volume Concentration in Thermoplastic Coatings. J. Coat. Technol. 54(690): 73
9. Bierwagen GP, Rich DC (1983) The Critical Pigment Volume Concentration in Latex Coatings. Prog. Org. Coat. 11:339-352
10. Bierwagen GP (1992) A Re-Examination of the CPVC as a Transition Point in Coatings Behavior. J. Coat. Technol. 64(806): 71-75
11. Fishman RS, Kurtze DA, Bierwagen GP (1992) The Effects of Density Fluctuations in Organic Coatings. J. Appl. Phys. 72: 3116-3124
12. Fishman RS, Kurtze DA, Bierwagen GP (1993) Pigment Inhomogeneity and Void Formation in Organic Coatings. Prog. Org. Coat. 21: 387-403
13. Frith, WJ, Buscall, R, "Percolation and Dritical Exponents on Randomly Close-Packed Mixtures of Hard Spheres," J. Chem. Phys., 95 5983-5989 (1991)
14. Fishman RS, Hill ES, Storsved TK, Bierwagen GP (1996) Density Fluctuations in Hard Sphere Packings. J. Appl. Phys. 79: 729-735
15. Dill, K, Bromberg, S, Stitger, D, Molecular Driving Forces, Ch. 23, 24, 27 and 33. Taylor & Francis Group, New York (2003)
16. Jones, RAL, Richards, RW, Polymers at Surfaces and Interfaces. Cambridge University Press, Cambridge (1999)
17. R Tothon (1995) Particulate-Filled Polymer Composites. Longman Scientific & Technical Publishers with J. Wiley, NY
18. Nanna ME, Bierwagen GP (2004) Mg-Rich Coatings: A new Paradigm for Cr-Free Corrosion Protection of Al Aerospace Alloys. JCT Res. 1: 69-81
19. Bideau, D, Dodds, J (eds) (1991) The Physics of Granular Media, Nova Science Publishers. Commack, NY
20. Battocchi D, Simões AM, Tallman DE, Bierwagen GP (2006) Electrochemical Behaviour of a Mg-Rich Primer in the Protection of Al Alloys. Corros. Sci. 48: 1292-1306
21. Simões, AM, Battocchi, D, Tallman, DE, Bierwagen, GP, "SVET and SECM Examination of Cathodic Protection of Aluminum Using a Mg-rich Coating," Corros. Sci., 49 3838-3849 (2007)
22. G Bierwagen, D Battocchi, A Simões, A Stamness, D Tallman (2007) The Use of Multiple Electrochemical Techniques to Characterize Mg-rich Primers for Al Alloys. Prog. Org. Coat. 59: 172-178
23. B Skerry, D Eden (1991) Characterization of Coating Performance by Electrochemical Noise Analysis Prog. Org. Coat. 19: 379
24. Mills, DJ, Bierwagen, GP, Tallman, DE, Skerry, BS, "Characterization of Corrosion Under Marine Coatings by Electrochemical Noise Methods." Proc. 12th International Corrosion Congress, Vol. 1, pp. 182-193 (paper 486). Houston, TX, Sept. 1993
25. Mills DJ, Bierwagen GP, Tallman DE, Skerry BS (1995) Investigation of Anticorrosive Coatings by the Electrochemical Noise Method. Mater. Performance 34: 33-38
26. Mills, DJ, Berg, S, Bierwagen, GP, "Characterization of the Corrosion Control Properties of Organic Electrodeposition Coatings." In: Scantlebury, D, Kendig, M (eds.) Proc. of the Symposium on Advances in Corrosion Protection by Organic Coatings II, Vol. 95-13, pp. 82-97. Special Publication of The Electrochemical Society, Proceedings, (1995)
27. Bierwagen, GP, Balbyshev, V, Mills, D, Tallman, D, "Fundamental Considerations on Electrochemical Noise Methods to Examine Corrosion under Organic Coatings." In: Scantlebury, D, Kendig, M (eds.) Proc. of the Symposium on Advances in Corrosion Protection by Organic Coatings II, Vol. 95-13, pp. 69-81. Special Publication of The Electrochemical Society, Proceedings, (1995)
28. Scantlebury, D, Kendig, M (eds.), Proc. of the Symposium on Advances in Corrosion Protection by Organic Coatings II, Vol. 95-13, p. iii. Special Publication of The Electrochemical Society, Proceedings, (1995)
29. Bierwagen GP (1994) Calculation of Noise Resistance from Simultaneous Electrochemical Voltage & Current Noise Data. J. Electrochem. Soc. 141: L155-L1957
30. Kelly, RG, Scully, JR, Shoesmith, DW, Buchheit, RG "Electrochemical Techniques is Corrosion Science and Engineering," Ch. 4 and Ch. 8. Marcel Dekker, New York (2003)
31. Bierwagen GP, Wang X, Tallman DE (2003) The In-Situ Study of Coatings Using Embedded Electrodes for ENM Measurements Prog. Org. Coat. 46: 163-175
32. Bierwagen GP, Jeffcoate C, Mills DJ, Li J, Balbyshev S, Tallman DE (1996) The Use of Electrochemical Noise Methods to Study Thick, High Impedance Coatings. Prog. Org. Coat. 29: 21-30
33. Jeffcoate, C, Li, J, Bierwagen, G, "Problems encountered in Electrochemical Corrosion Testing of Flame Sprayed Powder Coatings." In: Taylor, SR, Isaacs, H, Brooman, E (eds.) Electrochemical Soc. Symposium Proceedings 95-16, p. 60. (1995)
34. Jeffcoate CS, Wocken TL, Bierwagen GP (1997) Electrochemical Assessment of Spray-Applied Thermoplastic Coating Barrier Properties. J. Mater. Eng. Performance 6: 417-420
35. Li J, Jeffcoate CS, Biewagen GP, Mills DJ, Tallman DE (1998) Thermal Transition Effects and Electrochemical Properties in Organic Coatings: I. Initial Studies on Corrosion Protective Organic Coatings. Corrosion 54: 763-771
36. GP Bierwagen, J Li, L He, L Ellingson, DE Tallman (2000) Consideration of a New Accelerated Evaluation Method for Coating Corrosion Resistance-Thermal Cycling Testing. Prog. Org. Coat. 39: 67-78
37. Bierwagen, G, He, L, Tallman, D, "Time-Temperature Effects in Polymer Coatings for Corrosion Protection as Analyzed by EIS." In: Macromolecular Symposia, Vol. 187, pp. 909-918. Wiley-VCH, Weinheim, Germany, September 2002 (Presented at FATIPEC XXVI, Dresden, Germany, Sept. 9-11, 2002)
38. G Bierwagen, D Tallman, J Li, L He (2003) EIS Studies of Coated Metals in Accelerated Exposure. Prog. Org. Coat. 46: 148-157
39. Private communication, Sebastien Duval, Institut Petrol France, Lyon, France (June 2001)
40. Deflorian F, Rossi S, Fedrizzi L, Zanella C (2007) Comparison of organic coating accelerated tests and natural weathering considering meteorological data. Prog. Org. Coat. 59: 244-250
41. L He, GP Bierwagen, DE Tallman (2003) Use of a Scanning Thermal Microscope to Examine Corrosion Protective Coatings in Exposure. Prog. Org. Coat. 47: 233-248
42. Hinderliter, B, Allahar, KN, Bierwagen, GP, Tallman, DE, Croll, SG, "Thermal Cycling of Epoxy Coatings Using Room Temperature Ionic Liquids." Electrochem. Soc., 155 (2008) (in press)
43. Twite RL, Bierwagen GP (1998) Review of Alternatives to Chromate for Corrosion Protection of Aluminum Aerospace Alloys. Prog. Org. Coat. 33: 91-100
44. Janata, J, Baer, D, Bierwagen, GP, Birnbaum, H, Buchheit, R, Davenport, O, Isaacs, H, Hedberg, F, Kendig, M, Mansfeld, F, Miller, B, Wieckowski, A, Wilkes, J, "Issues Related to Chromium Replacement." Presented at 187th Meeting of The Electrochemical Society, May 21-26. Reno, Nevada (1995)
45. Bierwagen GP, Twite R, ChenG, Tallman DE (1997) AFM, SEM and Electrochemical Characterization of Al Alloys Conversion Coatings, and Primers Used for Aircraft. Prog. Org. Coat. 32: 25-30
46. Reynolds LB, Twite R, Donley MS, Bierwagen GP, Khobaib M (1997) Preliminary Evaluation of the Anticorrosive Properties of Aircraft Coatings by Electrochemical Methods. Prog. Org. Coat. 32: 31-34
47. J Sinko (2001) Challenges of Chromate Inhibitor Pigments Replacement in Organic Coatings. Prog. Org. Coat. 42: 267-282
48. Kendig, MW, Buchheit, RG, "Corrosion Inhibition of Aluminum andcAluminum Alloys by Soluble Chromates, Chromate Coatings, and Chromate-Free Coatings." Corrosion, 59 379-400 (2003)
49. Buchheit, RG, Grant, RP, Hlava, PF, McKenzie, B, Zender, GL, "Local Dissolution Phenomena Associated with S Phase (Al2CuMg) Particles in Aluminum Alloy 2024-T3, " J. Electrochem. Soc., 144 2621-2628 (1997)
50. Ilevbare, GO, Scully, JR, Yuan, J, Kelly, RG, "Inhibition of Pitting Corrosion on Aluminum Alloy 2024-T3: Effect of Soluble Chromate Additions vs Chromate Conversion Coating," Corrosion, 56 227-242 (2000)
51. Buchheit, RG, "Inhibition of Pitting Corrosion on Aluminum Alloy 2024-T3: Effect of Soluble Chromate Additions vs Chromate Conversion Coating," J. Electrochem. Soc., 142 3994 (1995)
52. Clark, WJ, Ramsey, JD, McCreery, RL, Frankel, GS, "A Galvanic Corrosion Approach to Investigating Chromate Effects on Aluminum Alloy 2024-T3." J. Electrochem. Soc., 149 B179-B185 (2002), and other work by this group at Ohio State University
53. P Gordon (2001) Bierwagen and Dennis E. Tallman, Choice and Measurement of Crucial Aerospace Coating System Properties. Prog. Org. Coat., 41 201-217
54. Chattopadhyay AK, Zentner MR 1990 Aerospace and Aircraft Coatings. Federation Series on Coatings Technology, Federation of Societiesfor Paint Technology, Philadelphia, PA
55. Hegedus, CR, Spadafora, SJ, Pulley, DF, Eng, AT, Hirst, DJ, "Aerospace and Aircraft Coatings." In: Koeleske, JV (ed.), Paint and Coating Testing Manual, 14th edn., pp. 683-695. ASTM Manual Series MNL17, 1995, ASTM Publication Code No. 28-017095-14, ASTM, Philadelphia, PA (Chapter 58)
56. G Bierwagen, D Tallman, J Li, L He (2003) EIS Studies of Coated Metals in Accelerated Exposure. Prog. Org. Coat. 46: 148-157
57. Bierwagen, GP, Tallman, DE, Touzain, S, Smith, A, Twite, R, Balbyshev, V, Pae, Y, "Electrochemical Noise Methods Applied to the Study of Organic Coatings and Pretreatment." Paper 380, Corrosion 98, Reviewed paper for the 1998 Annual Meeting of the Nat. Assoc. Corrosion Eng. (NACE), NACE Int., San Diego, CA, March 1998
58. De Rosa RL, Grant JT, Kasten L, Donley M, Bierwagen GP (2000) Surface Analysis of Various Methods of Preparing Al 2024 T-3 Surface for Painting. Corrosion 56: 395-400
59. Yang XF, Tallman DE, Gelling VJ, Bierwagen GP, Kasten LS, Berg J (2001) Use of a Sol-Gel Conversion Coating for Aluminum Corrosion Protection. Surf. Coat. Tech. 140: 44-50
60. Yang XF, Vang C, Tallman DE, Bierwagen GP, Croll SG Rohlik S (2001) Weathering Degradation of a Polyurethane Coating. Polym. Degrad. Stabil. 74: 341-351
61. L He, GP Bierwagen, DE Tallman (2003) Use of a Scanning Thermal Microscope to Examine Corrosion Protective Coatings in Exposure. Prog. Org. Coat. 47: 233-248
62. D Battocchi, G Bierwagen, D Tallman (2005) Emulation and Study of the Corrosion Behavior of Al Alloy 2024 T3 Using a Wire Beam Electrode (WBE) in Conjunction with Scanning Vibrating Electrode Technique (SVET). Corros. Sci. 47: 1165-1176
63. Bierwagen GP (1987) The Science of Durability of Organic Coatings-A Foreword. Prog. Org. Coat. 15: 179-185
64. Bierwagen, GP, Tallman, DE, Jeffcoate, CS, Zlotnick, J, "Defects & Heterogeneities in Corrosion Protective Organic Coatings Films and Their Effects on Performance." In: Bierwagen, GP (ed.) Ch. 10 in American Chemical Society, ACS Symposium Series, Vol. 689, p. 123. Organic Coatings for Corrosion Control (1998)
65. Bierwagen GP (1996) Reflections on Corrosion Control by Coatings. Prog. Org. Coat. 28: 43-48
66. J He, VJ Gelling, DE Tallman, GP Bierwagen (2000) A Scanning Vibrating Electrode Study of Chromated-Epoxy Primer on Steel and Aluminum. J. Electrochem. Soc. 147: 3661-3666
67. Bierwagen, G, Li, J, He, L, Tallman, D, "Fundamentals of the Measurement of Corrosion Protection and the Prediction of Its Lifetime in Coatings." In: Martin, J, Bauer, D (ed.) Service Life Prediction Methodology and Metrologies, Chapter 14, pp. 316-350. Monterey, CA, Nov. 14-17, 1999, ACS Symposium Series # 805, ACS Books, Washington, DC (2001)
68. Hinderleiter BR, Croll SG, Tallman DE, Su Q, Bierwagen GP (2006) Interpretation of EIS Results from Accelerated Exposure of Coated Metals based on Modeling of Coating Physical Properties Electrochim. Acta 51: 4505-4515
69. Martin, JW, "Service Life Prediction from Accelerated Aging Test Results Using Reliability Theory and Life Testing Analysis." In: Masters, L (ed.) Problems i Service Life Prediction of Building and Construction Materials, NATO ASI Series, Series E: No. 95 Applied Sciences, pp. 191-211. Nijhoff Publishers, Boston (1985)
70. McKnight, ME, Martin, JW, "Advanced Methods and Models for Describing Coating Appearance." Prog. Org. Coat., 34 152-159 (1998)
71. Martin, JW, "Repeatability and Reproducibility of Field Exposure Results." In: Martin, J, Bauer, D (eds.) Service Life Prediction Methodology and Metrologies, Ch. 1, Monterey, CA, Nov. 14-17, 1999, ACS Symposium Series # 805, pp. 2-22. ACS Books, Washington, DC (2001)
72. Staehle, RW, "Relationship Among Statistical Distributions, Accelerated Testing and Future Environments." Application of Accelerated Corrosion Tests to Service Life Prediction of Materials, ASTM Special Technical Publication STP 1194, pp. 3-26 (1994)
73. Bierwagen, GP, Mills, DJ, Tallman, DE, "Electrochemical Noise Methods as a Possible In Situ Corrosion Sensing Technique." Proc. 12th International Corrosion Congress, Vol. 6, pp. 4208-4218 (paper 576). Houston, TX (Sept. 3, 1993)
74. Wang, X, Bierwagen, GP, Mabbutt, SJ, Tallman, D, "Some Non-conventional Measurement Electrode Configurations for Electrochemical Impedance Spectroscopy and Electrochemical Noise Measurements of Coated Metals and Their Possible Uses." EuroCorr 2001, Lake Garda, Italy, Sept., 2001, CD-ROM Conf. Proc., Paper No. 61
75. Bierwagen, GP, Wang, X, Tallman, DE, "The In-Situ Study of Coatings Using Embedded Electrodes for ENM Measurements." Prog. Organic Coatings, Vol. 46, pp. 163-175 (2003), from International Workshop: "Application of Electrochemical Techniques to Organic Coatings," Jurata, Poland May 2001
76. Allahar, K, Su, Q, Bierwagen, G, Battocchi, D, Johnson Gelling, V, Tallman, D, "Further Studies of Embedded Electrodes for In-Situ Measurement of Corrosion Protective Properties of Organic Coatings." Refereed Paper 06675 NACE Corrosion 2006 Conference, San Diego CA
77. Allahar, K, Su, Q, Bierwagen, G, Battocchi, D, Johnson Gelling, V, Tallman, D, "Examination of the Feasibility of the Use of In-Situ Corrosion Sensors in Army Vehicles." To be published in Proc.Tri-Services Corrosion Conference 2005, Orlando, FL
78. Hinderliter, B, Allahar, K, Stafford, O, Bierwagen, G, Tallman, D, Croll, S, "Using Ionic Liquids to Measure Coating Properties Via Electrochemical Impedance Spectroscopy (EIS)," In review, J. Coat. Technol. Res.
79. Su, Q, Allahar, K, Bierwagen, G, "Embedded Electrode Electrochemical Noise Monitoring of the Corrosion beneath Organic Coatings Induced by ac-dc-ac Conditions," submitted to Electrochim. Acta, (2007) (in press)
80. Fernández JE (2007) Materials for Aesthetic, Energy-Efficient, and Self-Diagnostic Buildings. Science 315: 1807-1810
81. Hollaender, J, Ludwig, E, Hillebrand, S, Proc. of the Fifth International Tinplate Conference, p. 300. London (1992)
82. Bethencourt M, Botana, FJ, Cano, MJ, Osuna, RM, Marcos, M, "Lifetime Prediction of Water-Borne Acrylic Paints by the AD-DC_AC Method," Prog. Org. Coat., 49 275-281 (2004)
83. Poelman, M, Olivier, MG, Gayarre, N, Petitjean, JP, "Electrochemical Study of Different Ageing Tests for the Evaluation of a Cataphoretic Epoxy Primer on Aluminium," Prog. Org. Coat., 54 55-62 (2005)
84. Rodriguez, MT, Gracenea, JJ, Garcia, SJ, Saura, JJ, Suay, JJ, "Testing the Influence of the Plasticizers Addition on the Anticorrosive Properties of an Epoxy Primer by Means of Electrochemical Techniques," Prog. Org. Coat., 50 123-131 (2005)
85. Cottis RA (2006) Sources of Electrochemical Noise in Corroding Systems. Russian J. Electrochem. 42: 497-505
86. Sanchez-Amaya JM, Cottis RA, Botana FJ (2005) Shot Noise and Statistical Parameters for the Estimation of Corrosion Mechanisms. Corr. Sci. 47: 3280-3299
87. See www.Nobel.org for details of 2000 Nobel Prize in Chemistry shared by these three scientists
88. Tallman DE, Pae Y, Bierwagen GP (1999) Conducting Polymers and Corrosion: Poly(aniline) on Steel. Corrosion 55: 779-786
89. Tallman DE, Pae Y, Bierwagen GP (2000) Conducting Polymers and Corrosion 2: Polyaniline on Aluminum Alloys. Corrosion 56: 401-410
90. J He, VJ Gelling, DE Tallman, GP Bierwagen, GG Wallace (2000) Conducting Polymers and Corrosion III: A Scanning Vibrating Electrode Study of Poly(3-Octyl Pyrrole) on Steel and Aluminum. J. Electrochem. Soc. 147: 3667-3672
91. Tallman, DE, He, J, Gelling, VJ, Bierwagen, GP, Wallace, GG, "Scanning Vibrating Electrode Studies of Electroactive Conducting Polymers on Active Metals," In: Zarras, P et al. (eds.) American Chemical Society Symposium Series, Ch. 15, Vol. 843, pp. 228-253. Conductive/Electroactive Polymers for Corrosion Prevention (2003)
92. He, J, Battocchi, D, Simoes, AM, Tallman, DE, Bierwagen, GP, "Scanning Probe Studies of Active Coatings for Corrosion Control of Al Alloys." ACS Symposium on Smart Coatings, Book Chapter (2007) (in press)
93. Tallman, DE, Jensen, M, Bierwagen, G, "Studies of Electron Transfer at Aluminum Alloy Surfaces by Scanning Electrochemical Microscopy," accepted for publication in "ECS Transactions-Cancun" Volume 3, "Critical Factors in Localized Corrosion 5: A Symposium in Honor of Hugh Isaacs," from the Cancun meeting to be available in early 2007
94. Gelling VJ, Wiest MM, Tallman DE, Bierwagen GP, Wallace GG (2001) Electroactive-conducting Polymers for Corrosion Control. 4. Studies of Poly(3-octyl pyrrole) and Poly(3-octadecyl pyrrole) on Aluminum 2024 T-3 Alloy. Prog. Org. Coat. 43: 149-157
95. Tallman DE, Dewald MP, Vang CK, Wallace GG, Bierwagen GP (2004) Electrodeposition of Conducting Polymers on Active Metals by Electron Transfer Mediation. Curr. Appl. Phys. 4: 137-140
96. Tallman, DE, Bierwagen, GP, "Corrosion Protection Using Conducting Polymers." In: Chapter 15 in Handbook of Conducting Polymers, 3rd edn., pp. 15-1 to 15-53. Conjugated Polymers-Processing and Applications. CRC Press (2006)
97. Nanna, ME, Bierwagen, GP, "Mg-Rich Coatings: A new Paradigm for Cr-Free Corrosion Protection of Al Aerospace Alloys." J. Coat. Technol. Res., 1 69-81 (2004); awarded 1st place 2003 FSCT Roon Award Competition, ICE 2003, Philadelphia, PA, Nov. 14, 2003
98. Hare, C, "Corrosion Control of Steel by Organic Coatings," In: Review, RW (ed.) Uhlig's Corrosion Handbook, 2nd edn., Ch. 55, pp.1023-1038. John Wiley & Sons, New York (2000)
99. Felix S, Barajas R, Bastidas JM, Morcillo M, Feliu S (1993) Study of Protections Mechanism of Zinc-Rich paints by Electrochemical Impedance Spectroscopy. In: Scully JR, Silverman DC, Kendig M (eds) Electrochemical Impedance Spectroscopy, ASTM STP 1188. Amer. Soc. Testing and Materials (ASTM), Philadelphia, PA, pp. 438-449
100. Battocchi, D, Bierwagen, G, Stamness, A, Simoes, A, Tallman, D, "The Use of Multiple Electrochemical Techniques to Characterize Mg-rich Primers for Al Alloys." Refereed Paper 06250 NACE Corrosion 2006 Conference, San Diego, CA
101. Bierwagen, G, Battocchi, D, Simões, A, Stamness, A, Tallman, D, "The Use of Multiple Electrochemical Techniques to Characterize Mg-rich Primers for Al Alloys." Prog. Org. Coat., 59 172-178 (2007) (from AEOTC 2005, Villard-de-Lans, France April 2005)
102. Battocchi D, Simões AM, Tallman DE, Bierwagen GP (2006) Electrochemical Behavior of a Mg-rich Primer in the Protection of Al Alloys. Corros. Sci. 48: 1292-1306
103. Hosking NC, Strom MA, Shipway PH, Rudd CD (2007) Corrosion Resistance of Zinc-Magnesium Coated Steel. Corros. Sci. 49: 3669-3695
104. Battocchi D, Simões AM, Tallman DE, Bierwagen GP (2006) Comparison of Testing Solutions on the Protection of Al-Alloys Using a Mg-Rich Primer. Corros. Sci. 48: 1292-1306
105. Simões, AM, Battocchi, D, Tallman, DE, Bierwagen, GP, "SVET and SECM Examination of Cathodic Protection of Aluminum Using a Mg-rich Coating," Corros. Sci., 49 3838-3849 (2007)
106. Battocchi, D, Bierwagen, G, Simões, A, Stamness, A, Tallman, D, "Mg-Rich Primer for Chromate Free Protective Systems on Al 2024 and Al 7075." Eurocorr 2005 Proceedings, Book Chapter (2007) (in press)
107. Hare, C, "Corrosion Control of Steel by Organic Coatings," In: Review, RW (ed.) Uhlig's Corrosion Handbook, 2nd edn., Ch. 55, pp. 1023-1038. John Wiley & Sons, New York (2000)
108. Pereira D, Scantlebury JD, Ferreira MGS, Almeida ME (1990) The Application of Electrochemical Measurements to the Study and Behavior of Zinc-Rich Coatings. Corros. Sci. 30: 1135-1147
109. Faidi SE, Scantlebury JD, Bullivant P, Whittle NT, Savin R, (1993) An Electrochemical Study of Zinc-Containing Epoxy Coatings on Mild Steel. Corros. Sci. 35: 1319-1328
110. Gervasi CA, Di Sarli AR, Cavalcanti E, Ferraz O, Bucharsky EC, Real SG, Vilche JR (1994) The Corrosion Protection of Steel in Sea Water Using Zinc-Rich Alkyd Paints. An Assessment of the Pigment-Content Effect by EIS Corros. Sci. 36: 1963-1972
111. He, J, Battocchi, D, Simoes, AM, Tallman, DE, Bierwagen, GP, "Scanning Probe Studies of Active Coatings for Corrosion Control of Al Alloys." ACS Symposium on Smart Coatings, Book Chapter (2007) (in press)
112. Battocchi, D, Bierwagen, G, Simões, A, Stamness, A, Tallman, D, "Mg-Rich Primer for Chromate Free Protective Systems on Al 2024 and Al 7075," Eurocorr 2005, Book Chapter (2007) (in press)
113. PCT/US04/033089 Filed 10/07/04: Magnesium Rich Coatings and Coating Systems, Inventors: Gordon Bierwagen, Dante Battocchi and Michael Nanna
114. Bierwagen, G, Crawford, KK, Boudjouk, P, Battocchi, D, Brown, R, Griffin, J, "Buyer Beware and Seller Prepare: Improving the Likelihood of Forming an Academic-Industrial License Partnership." Paper II.1, Invited presentation May 2997 at Nurnberg Coatings Congress, Nurnberg, Germany, May 7, 2007
115. Battocchi, D, Bierwagen, G, Zentner, M, Brown, R, "Mg-rich Primer for Totally Chromate-Free Protective Systems on Al Alloys." Paper IX.5, Invited presentation May 2997 at Nurnberg Coatings Congress, Nurnberg, Germany, May 8, 2007
116. Hosking NC, Ström MA, Shipway PH, Rudd CD (2007) Corrosion Resistance of Zinc-Magnesium Coated Steel. Corros. Sci. 49: 3669-3695
117. Haycock, DE, Nicholls, CJ, Urch, DS, Webber, MJ, Wiech, G, "The Electronic Structure of Magnesium Dialuminium Tetraoxide (Spinel) Using X-Ray Emission and X-Ray Photoelectron Spectroscopies." J. Chem. Soc., Dalton Trans. 12 1785-1790 (1978)
118. Henry Moore's bronze work "Knife Edge Mirror: Two Pieces"
119. Scott, DA, Copper and Bronze in Art. Getty Publications, Getty Center, Los Angeles, CA (2002)
120. Römich, R (ed.), New Conservation Methods for Outdoor Bronze Sculptures, European Commission, Directorate General XII-Science, Research & Development, B1049 Brussells, Belgium (1996) Final Report EUR 16637 EN
121. Bierwagen, G, Shedlosky, TJ, Ellingson, L, "Electrochemical Studies of the Protection Bronzes from Corrosion by Organic Coatings." Metal 2001: Proceedings of the ICOM Committee for Conservation Metals Working Group, 1-00, ICC-COM-UNESCO Metal 2001, Congress Mundial de Conservacion de Metales, Metals Working Group International Congress, Santiago, Chile, April 2-6, 2001 (published in 2003)
122. Ellingson LA, Shedlosky TJ, Bierwagen GP, de la Rie ER, Brostoff LB (2004) The Use of Electrochemical Impedance Spectroscopy in the Evaluation of Coatings for Outdoor Bronze. Stud. Conserv. 49: 53-62
123. Webster, DC, Bennett, J, Kuebler, D, Kossuth, MB, Jonasdottir, S, "High Throughput Workflow for the Development of Coatings," JCT CoatingsTech, 1(6) 34-39 (2004)
124. Chisholm B, Potyrailo R, Cawse J, Shaffer R, Brennan M, Molaison C, Whisenhunt D, Flanagan B, Olson D, Akhave J (2002) The Development of Combinatorial Chemistry Methods for Coating Development: I. Overview of the Experimental Factory. Prog. Org. Coat. 45: 313-321
125. G Bierwagen, TJ Shedlosky, K Stanek (2003) Developing and Testing a New Generation of Protective Coatings for Outdoor Bronze Sculpture. Prog. Org. Coat. 48: 289-296
126. Shedlosky, TJ, Huovinen, A, Webster, D, Bierwagen, G, "Development and Evaluation of Removable Protective Coatings on Bronze," Metal 04: Proc. Int. Conference on Metals Conservation, p. 400. Canberra, Australia (Oct. 4-8, 2004)
127. Huovinen, AM, Shedlosky, TJ, Bierwagen, GP, Webster, DC, "Combinatorial Formulation and Evaluation of Removable Protective Coatings on Bronze." FSCT Advancements in Coatings Series: Research Methods in the 21st Century: A Toolkit for Competitive Advantage, New Orleans Marriott, New Orleans, LA, May 18-20 (2005)
128. Shedlosky, T, Bierwagen, G, Webster, D, Huovinen, A, Protective Coating for Metals, US Patent Application 60/674, 220 filed April 20, 2005, Eur. Patent Offic 05760218.7 (2005)
129. P Trulove, RA Mantz 2003 Electrochemical Properties of Ionic Liquids. In: Wassercheid P, Welton T (eds) Ionic Liquids in Synthesis, Wyley-VCH Verlag GmbH & Co., Weinheim, Germany, pp. 103-126
130. Ohno, H (ed.), Electrochemical Aspects of Ionic Liquids. Hoboken, New Jersey, Wiley Interscience (2005)
131. Simões AM, Tallman DE, Bierwagen GP (2005) The Use of Ionic Liquids for the Electrochemical Characterization of Water Transport in Organic Coatings. Electrochem. Solid-State Lett. 8: B60-B63
132. Hinderliter, B, Allahar, KN, Bierwagen, GP, Tallman, DE, Croll, SG, "Thermal Cycling of Epoxy Coatings Using Room Temperature Ionic Liquids." J. Electrochem. Soc., 155 (3) (2008) (in press)
133. AA Kornyshev (2007) Double-Layer in Ionic Liquids: Paradigm Change? J. Phys. Chem. B 111: 5545-5557
134. Allahar, K, Hinderliter, B, Simoes, A, Tallman, D, Bierwagen, G, Croll, S, "Simulation of Wet-Dry Cycling of Organic Coatings using Ionic Liquids." J. Electrochem. Soc., 154 177-185 (2007)
135. Hinderliter, B, Allahar, K, Stafford, O, Bierwagen, G, Tallman, D, Croll, S, "Using Ionic Liquids to Measure Coating Properties Via Electrochemical Impedance Spectroscopy (EIS)," In review, J. Coat. Technol. Res.