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13344264310
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3OH in 0.1% HTFA; flow rate = 1 mL/min.
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13344272563
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note
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Comparison of these data with those reported earlier for III (ref 10) shows that the present binuclear metallopeptide has somewhat greater β-sheet character.
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20
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0021764813
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26
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13344252639
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-
note
-
Emission lifetimes are taken from transients collected as an average of five laser shots acquired from two separate samples of material obtained from two separate syntheses. Excitation was achieved using the 532 nm output from a Q-switched Nd:YAG laser (10 ns pulse). In all cases, the decay profiles remained single exponential for at least 8 half-lives.
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-
-
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27
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13344258159
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note
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2O to enhance the emission lifetimes (see ref 12b).
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28
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13344253452
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private communication
-
Electron-transfer rates in the oligoproline series in ref 3a were originally reported on the basis of transient emission data. In all cases, these results have been subsequently confirmed by transient absorption experiments (Isied, S., private communication).
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Isied, S.1
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