Role of solvent nucleophilicity in excess-acidity plots for equilibria in sulfuric acid - water mixtures

Canadian Journal of Chemistry

Volumn 86, Issue 4, 2008, Pages 277-280

  Bentley, T William ^a  

^a SWANSEA UNIVERSITY   (United Kingdom)

Author keywords

Excess acidity; Kinetics; Solvent nucleophilicity; Solvolysis; Sulfuric acid

Indexed keywords

KINETICS; SULFURIC ACID;

EXCESS ACIDITY; SOLVENT NUCLEOPHILICITY; SOLVOLYSIS;

BINARY MIXTURES;

EID: 42149174317     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/V08-003     Document Type: Article

References (28)

1. K. Yates and R.A. McClelland, J. Am. Chem., Soc. 89, 2686 (1967).
2. R.A. Cox and K. Yates. Can. J. Chem. 61, 2225 (1983).
3. N.C. Marziano, G.M. Cimino, and R.C. Passerini, J. Chem., Soc., Perkin Trans. 2, 1915 (1973).
4. R.A. Cox, Adv. Phys. Org. Chem. 35, 1 (2000).
5. T.W. Bentley and K. Roberts. J. Chem. Soc., Perkin Trans. 2, 293 (1987).
6. A. Bagno, G. Scorrano, and R.A. More O'Ferrall. Rev. Chem. Intermed. 7, 313 (1987).
7. E. Grunwald and S. Winstein, J. Am. Chem. Soc. 70, 846 (1948).
8. F.L. Schadt, T.W. Bentley and P.v.R. Schleyer. J. Am. Chem. Soc 98, 7667 (1976).
9. T.W. Bentley and M.S. Garley, J. Phys. Org. Chem. 19, 341 (2006).
10. R.A. Stairs and E. Buncel, Can. J. Chem. 84, 1580 (2006).
11. N. Miathivanan, R.A. McClelland, and S. Steenken, J. Am. Chem. Soc. 112, 8454 (1990).
12. R.A. McClelland, Tetrahedron, 52, 6823 (1996).
13. S. Minegishi, S. Kobayashi, and H. Mayr. J. Am. Chem. Soc. 126, 5174 (2004).
14. D.N. Kevill and S.W. Anderson. J. Am. Chem., Soc. 108, 1579 (1986).
15. J. Kaspi and Z. Rappoport. Tetrahedron Lett. 2035 (1977).
16. T.W. Bentley, I.S. Koo, G. Llewellyn, and S.J. Norman. Croat. Chem. Acta, 65, 575 (1992).
17. D.N. Kevill, and S.W. Anderson. J. Chem. Res. 356 (1991).
18. T.W. Bentley and P.v.R. Schleyer. J. Am. Chem. Soc. 98, 7658 (1976).
19. D.N. Kevill. In Advances in quantitative structure - property relationships. No. 1. Edited by M. Charton. Jai press, Greenwich, CT. 1996. pp. 81-115.
20. (a) M. Eigen. Angew. Chem. Int. Ed. Engl. 3, 1 (1964);
21. (b) A.J. Kresge. Acc Chem. Res. 8, 354 (1975).
22. J.E. Szulejko and T.B. McMahon. J. Am. Chem. Soc. 115, 7839 (1993).
23. T.W. Bentley and G.Llewellyn. Prog. Phys. Org. Chem. 17, 121 (1990).
24. D.N. Kevill and G.M.L. Lin. J. Am. Chem., Soc. 101, 3916 (1979).
25. D.N. Kevill and S.W. Anderson. J. Org. Chem. 56, 1845 (1991).
26. E. Grunwald, A. Heller, and F. S. Klein. J. Chem. Soc. 2604 (1957).
27. M.V. Merritt, D.B. Anderson, K.A. Basu, I.W. Chang, H.J. Cheon, N.E. Mukundan, C.A. Flannery, A.Y. Kim, A. Vaishampayan, and D.A. Yens. J. Am. Chem. Soc 116, 5551 (1994).
28. J.M. Headrick, E.G. Diken, R.S. Walters, N.I. Hammer, R.A. Christie, J. Cui, E.M. Myshakin, M.A. Duncan, M.A. Johnson, and K.D. Jordan. Science (Washington, DC), 308, 1765 (2005).