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42149085424
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In (SPANphos)Rh(CO)Cl the corresponding angle is 108.65°.
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In (SPANphos)Rh(CO)Cl the corresponding angle is 108.65°.
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2Rh(CO)Cl complexes with MeI see also: Angharad Baber, R.; Haddow, M. F.; Middelton, A. J.; Orpen, A. G.; Pringle, P. G.; Haynes, A.; Williams, G. L.; Papp, R. Organometallics 2007, 26, 713.
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42
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42149124710
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For a Rh(CO)Cl complex containing a trans-coordinating monodentate phosphinine, see ref 16
-
For a Rh(CO)Cl complex containing a trans-coordinating monodentate phosphinine, see ref 16.
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43
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42149160458
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For compound 7 a composition was found which is consistent with the empirical formula C59H44BF4P2Rh · CH2Cl2 · Et2O. Substitution of the second norbomadiene ligand by an additional bidentate phosphinine to form a species of the composition Rh(4)2BF4 would lead to a much higher carbon content (76.8, Furthermore, the presence of a potential bis-chelate to form Rh(4)2BF4 is rather unlikely, since free ligand is observed in the 31P NMR spectrum upon reaction of Rh(nbd)2BF4 with excess bis-phosphinine 4
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4 with excess bis-phosphinine 4.
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44
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42149183335
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Molecular mechanics calculations were performed using CAChe Worksystem Pro, version 6.1.1, from Fujitsu, using augmented MM2 force field parameters
-
Molecular mechanics calculations were performed using CAChe Worksystem Pro, version 6.1.1, from Fujitsu, using augmented MM2 force field parameters.
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45
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For phosphinines as ligands in homogeneous catalysis, see also: (a) Reetz, M. T.; Li, X. Angew. Chem., Int. Ed. 2005, 44, 2962.
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