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Volumn 27, Issue 5, 2008, Pages 834-838

Wide-bite-angle diphosphinines: Design, synthesis, and coordination properties

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; LIGANDS; LOW TEMPERATURE EFFECTS; MOLECULAR ORIENTATION; PHOSPHATES;

EID: 42149102655     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om7003546     Document Type: Article
Times cited : (43)

References (52)
  • 14
    • 0037239636 scopus 로고    scopus 로고
    • 2] isomers, see also: Harvey, J. N.; Heslop, K. M.; Orpen, A. G.; Pringle, P. G. Chem. Commun. 2003, 278.
    • 2] isomers, see also: Harvey, J. N.; Heslop, K. M.; Orpen, A. G.; Pringle, P. G. Chem. Commun. 2003, 278.
  • 20
    • 42149085424 scopus 로고    scopus 로고
    • In (SPANphos)Rh(CO)Cl the corresponding angle is 108.65°.
    • In (SPANphos)Rh(CO)Cl the corresponding angle is 108.65°.
  • 30
    • 42149084242 scopus 로고    scopus 로고
    • Paciello, R.; Zeller, E.; Breit, B.; Röper, M. (BASF AG) DE 19.743.197, 1999.
    • (b) Paciello, R.; Zeller, E.; Breit, B.; Röper, M. (BASF AG) DE 19.743.197, 1999.
  • 41
    • 33847198693 scopus 로고    scopus 로고
    • 2Rh(CO)Cl complexes with MeI see also: Angharad Baber, R.; Haddow, M. F.; Middelton, A. J.; Orpen, A. G.; Pringle, P. G.; Haynes, A.; Williams, G. L.; Papp, R. Organometallics 2007, 26, 713.
    • 2Rh(CO)Cl complexes with MeI see also: Angharad Baber, R.; Haddow, M. F.; Middelton, A. J.; Orpen, A. G.; Pringle, P. G.; Haynes, A.; Williams, G. L.; Papp, R. Organometallics 2007, 26, 713.
  • 42
    • 42149124710 scopus 로고    scopus 로고
    • For a Rh(CO)Cl complex containing a trans-coordinating monodentate phosphinine, see ref 16
    • For a Rh(CO)Cl complex containing a trans-coordinating monodentate phosphinine, see ref 16.
  • 43
    • 42149160458 scopus 로고    scopus 로고
    • For compound 7 a composition was found which is consistent with the empirical formula C59H44BF4P2Rh · CH2Cl2 · Et2O. Substitution of the second norbomadiene ligand by an additional bidentate phosphinine to form a species of the composition Rh(4)2BF4 would lead to a much higher carbon content (76.8, Furthermore, the presence of a potential bis-chelate to form Rh(4)2BF4 is rather unlikely, since free ligand is observed in the 31P NMR spectrum upon reaction of Rh(nbd)2BF4 with excess bis-phosphinine 4
    • 4 with excess bis-phosphinine 4.
  • 44
    • 42149183335 scopus 로고    scopus 로고
    • Molecular mechanics calculations were performed using CAChe Worksystem Pro, version 6.1.1, from Fujitsu, using augmented MM2 force field parameters
    • Molecular mechanics calculations were performed using CAChe Worksystem Pro, version 6.1.1, from Fujitsu, using augmented MM2 force field parameters.
  • 45
    • 18844431131 scopus 로고    scopus 로고
    • For phosphinines as ligands in homogeneous catalysis, see also: (a) Reetz, M. T.; Li, X. Angew. Chem., Int. Ed. 2005, 44, 2962.
    • For phosphinines as ligands in homogeneous catalysis, see also: (a) Reetz, M. T.; Li, X. Angew. Chem., Int. Ed. 2005, 44, 2962.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.