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Choy, J.H.1
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9
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41749086998
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Lattice parameters for BTT (a, 5.421 Å, b, 4.945 Å,c, 23.974 Å, Ar-BTT (a, 5.444 Å, b, 4.978 Å, c, 24.121 Å, Li-BTT (a, 5.431 Å, b, 4.971 Å, c, 24.000 Å, SBT (a, 3.897 Å, b, 3.902 Å, c, 24.986 Å, Ar-SBT (a, 3.900 A, b, 3.904 Å, c, 24.967 Å, Li-SBT (a, 3.912 ̊, b, 3.906 Å, c, 25.005 Å, BTO (a, 5.407 Å, b, 5.437 Å, c, 32.826 Å, Ar-BTO (a, 5.411 Å, b, 5.444 Å, c, 32.849 Å, and Li-BTO a, 5.414 Å, b, 5.449 Å, c, 32.790 Å
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Lattice parameters for BTT (a = 5.421 Å, b = 4.945 Å,c = 23.974 Å), Ar-BTT (a = 5.444 Å, b = 4.978 Å, c = 24.121 Å), Li-BTT (a = 5.431 Å, b = 4.971 Å, c = 24.000 Å), SBT (a = 3.897 Å, b = 3.902 Å, c = 24.986 Å), Ar-SBT (a = 3.900 A, b = 3.904 Å, c = 24.967 Å), Li-SBT (a = 3.912 ̊, b = 3.906 Å, c = 25.005 Å), BTO (a = 5.407 Å, b = 5.437 Å, c = 32.826 Å), Ar-BTO (a = 5.411 Å, b = 5.444 Å, c = 32.849 Å), and Li-BTO (a = 5.414 Å, b = 5.449 Å, c = 32.790 Å).
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10
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0000726658
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Hess, N. J.; Balmer, M. L.; Bunker, B. C.; Conradson, S. D. J. Solid State Chem. 1997, 129, 206.
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14
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41749084501
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On the basis of the higher oxidation state of the Tav ion than the TiIV ion, the former is reasonably expected to be more electronegative than the latter because the electronegativity becomes higher with the increase of the oxidation state. This expectation is further supported by the fact that a neutral tantalum element has nearly the same electronegativity as the divalent titanium ion (χPauling(Ta 0, 1.5, χPauling(O-II, 1.54; χPauling(O-II, 3.4, ref 12, Using the Pauling's formula for (a-b) bond ionicity (I) calculation, I=1- exp[-1/4(χa, χb)2, the bond ionicity is expected to be smaller for (Tav-O) bonds than for (TiIV-O) bonds, implying the greater covalency for the former bonds
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IV-O) bonds, implying the greater covalency for the former bonds.
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Choy, J. H.; Hwang, S. J.; Park, N. G. J. Am Chem. Soc. 1997, 119, 1624.
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Choy, J.H.1
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16
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41749106313
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Peaks positions for BTT (A, 9881.2 eV; B, 9886.0 eV; ΔE = 4.8 eV), Ar-BTT (A, 9881.0 eV; B, 9885.7 eV; ΔE = 4.7 eV), Li-BTT (A, 9881.0 eV; B, 9885.7 eV; ΔE = 4.7 eV), SBT (A, 9881.8 eV; B, 9886.3 eV; ΔE = 4.5 eV), Ar-SBT (A, 9881.7 eV; B, 9886.2 eV; ΔE = 4.5 eV), and Li-SBT (A, 9881.6 eV; B, 9885.8 eV; ΔE = 4.2 eV). The standard deviation of the peak positions is ±0.1 eV
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Peaks positions for BTT (A, 9881.2 eV; B, 9886.0 eV; ΔE = 4.8 eV), Ar-BTT (A, 9881.0 eV; B, 9885.7 eV; ΔE = 4.7 eV), Li-BTT (A, 9881.0 eV; B, 9885.7 eV; ΔE = 4.7 eV), SBT (A, 9881.8 eV; B, 9886.3 eV; ΔE = 4.5 eV), Ar-SBT (A, 9881.7 eV; B, 9886.2 eV; ΔE = 4.5 eV), and Li-SBT (A, 9881.6 eV; B, 9885.8 eV; ΔE = 4.2 eV). The standard deviation of the peak positions is ±0.1 eV
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17
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0024701785
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Studer, F.; Bourgault, D.; Martin. C.; Retoux, R.; Michael, C.; Raveau, B.; Dartyge, E.; Fontaine, A. Physica C 1989, 159, 609.
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