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Volumn 20, Issue 6, 2008, Pages 2151-2159

Structure and properties of a new family of nearly equiatomic rare-earth metal-tin-germanides RESn1+xGe1-x (RE = Y, Gd-Tm): An unusual example of site preferences between elements from the same group

Author keywords

[No Author keywords available]

Indexed keywords

GERMANIDES; HIGH-TEMPERATURE REACTIONS; POLYANIONIC MOIETIES; STOICHIOMETRIC COMPOUNDS;

EID: 41749087123     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm7033799     Document Type: Article
Times cited : (35)

References (76)
  • 45
    • 41749120837 scopus 로고    scopus 로고
    • 2).
    • 2).
  • 58
    • 41749088113 scopus 로고    scopus 로고
    • Although these layers are dubbed square nets throughout the text, it must not be forgotten that this description is just an approximation. The puckering of the nets increases as the size of the rare-earth metal cation increases, i.e, from Tm to Gd. This also coincides with the increase of the Sn-content, i.e, enlarging the unit cell, thereby making the separation of the two effects impossible
    • Although these layers are dubbed "square nets" throughout the text, it must not be forgotten that this description is just an approximation. The puckering of the nets increases as the size of the rare-earth metal cation increases, i.e., from Tm to Gd. This also coincides with the increase of the Sn-content, i.e., enlarging the unit cell, thereby making the separation of the two effects impossible.
  • 61
    • 33748242427 scopus 로고
    • and references therein
    • Nesper, R Angew. Chem., Int. Ed. 1991, 30, 789, and references therein.
    • (1991) Angew. Chem., Int. Ed , vol.30 , pp. 789
    • Nesper, R.1
  • 73
    • 41749088971 scopus 로고    scopus 로고
    • 15 The transition metal is shown to have significant interactions with the square sheets.
    • 15 The transition metal is shown to have significant interactions with the square sheets.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.