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We have calculated the 1:1 complex between BH and methanol, where the hydrogen atom of BH is solvated by OH of methanol. According to the optimized structure using the basis set of 6-31+Gd, the vibrational mode at 1059 cm -1 for bare BH is shifted to 1070 cm-1, and the mode at 1045 cm-1 is shifted to 1051 cm-1. The latter band of the complex does not have the contribution of C-O stretching in contrast to that of the bare BH molecule
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A wider slit width was used to collect time-resolved resonance Raman spectra to increase the signal intensity. Therefore, the apparent bandwidth of the signal is broadened by the effect of the slit function; for example, the Raman signal at 1347 cm-1 of cyclohexane has the bandwidth of 18.6 cm-1 for the time-resolved system, while it has the bandwidth of 17.2 cm-1 for the static measurement system. For other bands, the bandwidths measured by the time-resolved system are generally at most 2 cm -1 larger than the bandwidths of the system for the static measurement. Therefore, the effect of the difference of the slit function is small and does not exceed 2 cm-1 for the results presented here
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-1 for the results presented here.
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